Green approaches in the synthesis of furan-based diepoxy monomers
Two eco-respectful, one-step synthetic routes for the preparation of a bio-based epoxy monomer derived from furan precursors are developed. The diglycidyl ester products are throughly characterized in terms of structure and thermal properties. Gathered results indicate that the two selected approach...
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| Published in: | RSC advances Vol. 8; no. 29; pp. 16330 - 16335 |
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| Main Authors: | , , , |
| Format: | Journal Article |
| Language: | English |
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England
Royal Society of Chemistry
01.01.2018
The Royal Society of Chemistry |
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| ISSN: | 2046-2069, 2046-2069 |
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| Abstract | Two eco-respectful, one-step synthetic routes for the preparation of a bio-based epoxy monomer derived from furan precursors are developed. The diglycidyl ester products are throughly characterized in terms of structure and thermal properties. Gathered results indicate that the two selected approaches allow the preparation of pure, furanic diglycidyl ester, which represents a viable bio-based alternative to its petrochemical aromatic counterpart. |
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| AbstractList | Two eco-respectful, one-step synthetic routes for the preparation of a bio-based epoxy monomer derived from furan precursors are developed. The diglycidyl ester products are throughly characterized in terms of structure and thermal properties. Gathered results indicate that the two selected approaches allow the preparation of pure, furanic diglycidyl ester, which represents a viable bio-based alternative to its petrochemical aromatic counterpart.Two eco-respectful, one-step synthetic routes for the preparation of a bio-based epoxy monomer derived from furan precursors are developed. The diglycidyl ester products are throughly characterized in terms of structure and thermal properties. Gathered results indicate that the two selected approaches allow the preparation of pure, furanic diglycidyl ester, which represents a viable bio-based alternative to its petrochemical aromatic counterpart. Two eco-respectful, one-step synthetic routes for the preparation of a bio-based epoxy monomer derived from furan precursors are developed. The diglycidyl ester products are throughly characterized in terms of structure and thermal properties. Gathered results indicate that the two selected approaches allow the preparation of pure, furanic diglycidyl ester, which represents a viable bio-based alternative to its petrochemical aromatic counterpart. Two eco-respectful, one-step synthetic routes for the preparation of a bio-based epoxy monomer derived from furan precursors are developed. The diglycidyl ester products are throughly characterized in terms of structure and thermal properties. Gathered results indicate that the two selected approaches allow the preparation of pure, furanic diglycidyl ester, which represents a viable bio-based alternative to its petrochemical aromatic counterpart. Two eco-respectful, one-step synthetic routes for the preparation of a bio-based epoxy monomer derived from furan precursors are developed. |
| Author | Ambrogi, Veronica Cerruti, Pierfrancesco Mija, Alice Marotta, Angela |
| Author_xml | – sequence: 1 givenname: Angela surname: Marotta fullname: Marotta, Angela organization: Department of Chemical, Materials and Production Engineering (DICMaPI), University of Naples “Federico II”, 80125 Napoli, Italy – sequence: 2 givenname: Veronica surname: Ambrogi fullname: Ambrogi, Veronica organization: Department of Chemical, Materials and Production Engineering (DICMaPI), University of Naples “Federico II”, 80125 Napoli, Italy – sequence: 3 givenname: Pierfrancesco surname: Cerruti fullname: Cerruti, Pierfrancesco organization: Institute for Polymers, Composites and Biomaterials (IPCB), CNR, 80078 Pozzuoli (NA), Italy – sequence: 4 givenname: Alice orcidid: 0000-0001-5208-5956 surname: Mija fullname: Mija, Alice organization: Université Côte d’Azur, Université Nice-Sophia Antipolis, Institut de Chimie de Nice, UMR CNRS 7272, 06108 Nice Cedex 02, France |
| BackLink | https://www.ncbi.nlm.nih.gov/pubmed/35542187$$D View this record in MEDLINE/PubMed |
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| Cites_doi | 10.1039/C3GC42613K 10.1021/ma5000199 10.1016/j.eurpolymj.2014.09.025 10.1016/j.biortech.2010.03.050 10.1055/s-0036-1589496 10.2172/926125 10.1021/acssuschemeng.7b01222 10.1016/j.eurpolymj.2016.08.004 10.1039/C7CS00149E 10.1021/acs.iecr.7b01624 10.1016/j.tet.2012.11.079 10.1080/03602559.2010.512338 10.1039/c0gc00789g 10.1002/cssc.201501259 10.1039/C4CP00518J 10.1021/ma500687t 10.1039/C5GC02114F 10.1080/01694243.2012.697700 10.1016/j.cherd.2009.06.010 10.1016/j.polymer.2014.06.025 10.1016/j.polymer.2016.09.030 10.1016/j.jsbmb.2011.05.002 10.1002/cssc.201403262 10.1016/j.polymer.2016.02.003 10.1021/acsenergylett.6b00214 10.1016/j.polymertesting.2005.09.003 10.1039/C5RA00242G 10.1021/cr3001274 10.1016/S0142-9418(02)00048-X 10.1023/A:1021013921916 10.1016/j.progpolymsci.2016.12.009 10.1016/j.indcrop.2016.05.025 10.1039/C7GC02610B 10.1016/j.biortech.2016.04.122 10.1039/C5GC00991J 10.1016/j.eurpolymj.2014.03.034 10.1016/j.eurpolymj.2014.10.011 10.1039/b922014c 10.1039/C5GC01584G |
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| SubjectTerms | Chemistry epoxides furans Monomers thermal properties Thermodynamic properties |
| Title | Green approaches in the synthesis of furan-based diepoxy monomers |
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