Catalysis seen in action

Synchrotron radiation techniques are widely applied in materials research and heterogeneous catalysis. In homogeneous catalysis, its use so far is rather limited despite its high potential. Here, insights in the strengths and limitations of X-ray spectroscopy technique in the field of homogeneous ca...

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Veröffentlicht in:Philosophical transactions of the Royal Society of London. Series A: Mathematical, physical, and engineering sciences Jg. 373; H. 2036
1. Verfasser: Tromp, Moniek
Format: Journal Article
Sprache:Englisch
Veröffentlicht: England 06.03.2015
Schlagworte:
homogeneous
catalysis
operando
time-resolved
X-ray spectroscopy techniques
high-energy resolution
ISSN:1471-2962, 1471-2962
Online-Zugang:Weitere Angaben
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Beschreibung
Zusammenfassung:Synchrotron radiation techniques are widely applied in materials research and heterogeneous catalysis. In homogeneous catalysis, its use so far is rather limited despite its high potential. Here, insights in the strengths and limitations of X-ray spectroscopy technique in the field of homogeneous catalysis are given, including new technique developments. A relevant homogeneous catalyst, used in the industrially important selective oligomerization of ethene, is taken as a worked-out example. Emphasis is placed on time-resolved operando X-ray absorption spectroscopy with outlooks to novel high energy resolution and emission techniques. All experiments described have been or can be done at the Diamond Light Source Ltd (Didcot, UK).
Bibliographie:ObjectType-Article-1
SourceType-Scholarly Journals-1
ObjectType-Feature-2
content type line 23
ISSN:1471-2962
1471-2962
DOI:10.1098/rsta.2013.0152