Structural and Oxidation State Alternatives in Platinum and Palladium Complexes of a Redox‐Active Amidinato Ligand

Reaction of [Pt(DMSO)2Cl2] or [Pd(MeCN)2Cl2] with the electron‐rich LH=N,N’‐bis(4‐dimethylaminophenyl)ethanimidamide yielded mononuclear [PtL2] (1) but dinuclear [Pd2L4] (2), a paddle‐wheel complex. The neutral compounds were characterized through experiments (crystal structures, electrochemistry, U...

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Bibliographic Details
Published in:	Chemistry : a European journal Vol. 27; no. 10; pp. 3374 - 3381
Main Authors:	Ehret, Fabian, Filippou, Vasileios, Blickle, Svenja, Bubrin, Martina, Záliš, Stanislav, Kaim, Wolfgang
Format:	Journal Article
Language:	English
Published:	WEINHEIM Wiley 15.02.2021 Wiley Subscription Services, Inc John Wiley and Sons Inc
Subjects:	Cations Chemistry Chemistry, Multidisciplinary Computer applications Crystal structure Crystals Electrochemistry electron transfer Ligands Magnetic resonance Oxidation oxidation states Palladium Palladium compounds Physical Sciences Platinum radical ligands Science & Technology Single crystals spectroelectrochemistry Spectroscopy spin distribution Valence oxidation states ORDER ELECTRON MONONUCLEAR electron transfer APPROXIMATION spin distribution spectroelectrochemistry REACTIVITY radical ligands METAL
ISSN:	0947-6539, 1521-3765, 1521-3765
Online Access:	Get full text
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