Highly Oxidized States of Phthalocyaninato Terbium(III) Multiple‐Decker Complexes Showing Structural Deformations, Biradical Properties and Decreases in Magnetic Anisotropy

Presented here is a comprehensive study of highly oxidized multiple‐decker complexes composed of TbIII and CdII ions and two to five phthalocyaninato ligands, which are stabilized by electron‐donating n‐butoxy groups. From X‐ray structural analyses, all the complexes become axially compressed upon l...

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Bibliographic Details
Published in:	Chemistry : a European journal Vol. 26; no. 39; pp. 8621 - 8630
Main Authors:	Horii, Yoji, Damjanović, Marko, Ajayakumar, M. R., Katoh, Keiichi, Kitagawa, Yasutaka, Chibotaru, Liviu, Ungur, Liviu, Mas‐Torrent, Marta, Wernsdorfer, Wolfgang, Breedlove, Brian K., Enders, Markus, Veciana, Jaume, Yamashita, Masahiro
Format:	Journal Article
Language:	English
Published:	Germany Wiley Subscription Services, Inc 14.07.2020 John Wiley and Sons Inc
Subjects:	Anisotropy biradical Chemistry Coexistence Coordination compounds crystal engineering Ligands Magnetic anisotropy Magnetic measurement Magnetic properties Metal ions NMR Nuclear magnetic resonance Oxidation redox Terbium Redox, Biradical, Magnetic anisotropy, NMR, Crystal engineering
ISSN:	0947-6539, 1521-3765, 1521-3765
Online Access:	Get full text
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