Highly Oxidized States of Phthalocyaninato Terbium(III) Multiple‐Decker Complexes Showing Structural Deformations, Biradical Properties and Decreases in Magnetic Anisotropy

Presented here is a comprehensive study of highly oxidized multiple‐decker complexes composed of TbIII and CdII ions and two to five phthalocyaninato ligands, which are stabilized by electron‐donating n‐butoxy groups. From X‐ray structural analyses, all the complexes become axially compressed upon l...

Celý popis

Uloženo v:
Podrobná bibliografie
Vydáno v:Chemistry : a European journal Ročník 26; číslo 39; s. 8621 - 8630
Hlavní autoři: Horii, Yoji, Damjanović, Marko, Ajayakumar, M. R., Katoh, Keiichi, Kitagawa, Yasutaka, Chibotaru, Liviu, Ungur, Liviu, Mas‐Torrent, Marta, Wernsdorfer, Wolfgang, Breedlove, Brian K., Enders, Markus, Veciana, Jaume, Yamashita, Masahiro
Médium: Journal Article
Jazyk:angličtina
Vydáno: Germany Wiley Subscription Services, Inc 14.07.2020
John Wiley and Sons Inc
Témata:
Anisotropy
biradical
Chemistry
Coexistence
Coordination compounds
crystal engineering
Ligands
Magnetic anisotropy
Magnetic measurement
Magnetic properties
Metal ions
NMR
Nuclear magnetic resonance
Oxidation
redox
Terbium
Redox, Biradical, Magnetic anisotropy, NMR, Crystal engineering
ISSN:0947-6539, 1521-3765, 1521-3765
On-line přístup:Získat plný text
Tagy: Přidat tag
Žádné tagy, Buďte první, kdo vytvoří štítek k tomuto záznamu!
Abstract Presented here is a comprehensive study of highly oxidized multiple‐decker complexes composed of TbIII and CdII ions and two to five phthalocyaninato ligands, which are stabilized by electron‐donating n‐butoxy groups. From X‐ray structural analyses, all the complexes become axially compressed upon ligand oxidation, resulting in bowl‐shaped distortions of the ligands. In addition, unusual coexistence of square antiprism and square prism geometries around metal ions was observed in +4e charged species. From paramagnetic 1H NMR studies on the resulting series of triple, quadruple and quintuple‐decker complexes, ligand oxidation leads to a decrease in the magnetic anisotropy, as predicted from theoretical calculations. Unusual paramagnetic shifts were observed in the spectra of the +2e charged quadruple and quintuple‐decker complexes, indicating that those two species are actually unexpected triplet biradicals. Magnetic measurements revealed that the series of complexes show single‐molecule magnet properties, which are controlled by the multi‐step redox induced structural changes. Stacking up: From extensive studies on highly oxidized species of phthalocyaninato‐lanthanoid‐cadmium multiple‐decker complexes, the complexes had staggered and eclipsed conformations and showed complicated changes in their magnetic anisotropies and biradical properties.
AbstractList Presented here is a comprehensive study of highly oxidized multiple‐decker complexes composed of Tb III and Cd II ions and two to five phthalocyaninato ligands, which are stabilized by electron‐donating n ‐butoxy groups. From X‐ray structural analyses, all the complexes become axially compressed upon ligand oxidation, resulting in bowl‐shaped distortions of the ligands. In addition, unusual coexistence of square antiprism and square prism geometries around metal ions was observed in +4 e charged species. From paramagnetic 1 H NMR studies on the resulting series of triple, quadruple and quintuple‐decker complexes, ligand oxidation leads to a decrease in the magnetic anisotropy, as predicted from theoretical calculations. Unusual paramagnetic shifts were observed in the spectra of the +2 e charged quadruple and quintuple‐decker complexes, indicating that those two species are actually unexpected triplet biradicals. Magnetic measurements revealed that the series of complexes show single‐molecule magnet properties, which are controlled by the multi‐step redox induced structural changes.
Herein we present a comprehensive study of highly oxidized multiple-decker complexes composed of Tb(III) and Cd(II) ions and two to five phthalocyaninato ligands, which are stabilized by electron-donating n -butoxy groups. From X-ray structural analyses, all the complexes become axially compressed upon ligand oxidation, resulting in bowl-shaped distortions of the ligands. In addition, unusual coexistence of square antiprism and square prism geometries around metal ions was observed in +4 e charged species. From paramagnetic 1 H NMR studies on the resulting series of triple, quadruple and quintuple-decker complexes, ligand oxidation leads to a decrease in the magnetic anisotropy, as predicted from theoretical calculations. Unusual paramagnetic shifts were observed in the spectra of the +2 e charged quadruple and quintuple-decker complexes, indicating that those two species are actually unexpected triplet biradicals. Magnetic measurements revealed that the series of complexes show single-molecule magnet properties, which are controlled by the multi-step redox induced structural changes.
Presented here is a comprehensive study of highly oxidized multiple‐decker complexes composed of TbIII and CdII ions and two to five phthalocyaninato ligands, which are stabilized by electron‐donating n‐butoxy groups. From X‐ray structural analyses, all the complexes become axially compressed upon ligand oxidation, resulting in bowl‐shaped distortions of the ligands. In addition, unusual coexistence of square antiprism and square prism geometries around metal ions was observed in +4e charged species. From paramagnetic 1H NMR studies on the resulting series of triple, quadruple and quintuple‐decker complexes, ligand oxidation leads to a decrease in the magnetic anisotropy, as predicted from theoretical calculations. Unusual paramagnetic shifts were observed in the spectra of the +2e charged quadruple and quintuple‐decker complexes, indicating that those two species are actually unexpected triplet biradicals. Magnetic measurements revealed that the series of complexes show single‐molecule magnet properties, which are controlled by the multi‐step redox induced structural changes.
Presented here is a comprehensive study of highly oxidized multiple‐decker complexes composed of TbIII and CdII ions and two to five phthalocyaninato ligands, which are stabilized by electron‐donating n‐butoxy groups. From X‐ray structural analyses, all the complexes become axially compressed upon ligand oxidation, resulting in bowl‐shaped distortions of the ligands. In addition, unusual coexistence of square antiprism and square prism geometries around metal ions was observed in +4e charged species. From paramagnetic 1H NMR studies on the resulting series of triple, quadruple and quintuple‐decker complexes, ligand oxidation leads to a decrease in the magnetic anisotropy, as predicted from theoretical calculations. Unusual paramagnetic shifts were observed in the spectra of the +2e charged quadruple and quintuple‐decker complexes, indicating that those two species are actually unexpected triplet biradicals. Magnetic measurements revealed that the series of complexes show single‐molecule magnet properties, which are controlled by the multi‐step redox induced structural changes. Stacking up: From extensive studies on highly oxidized species of phthalocyaninato‐lanthanoid‐cadmium multiple‐decker complexes, the complexes had staggered and eclipsed conformations and showed complicated changes in their magnetic anisotropies and biradical properties.
Presented here is a comprehensive study of highly oxidized multiple-decker complexes composed of TbIII and CdII ions and two to five phthalocyaninato ligands, which are stabilized by electron-donating n-butoxy groups. From X-ray structural analyses, all the complexes become axially compressed upon ligand oxidation, resulting in bowl-shaped distortions of the ligands. In addition, unusual coexistence of square antiprism and square prism geometries around metal ions was observed in +4e charged species. From paramagnetic 1 H NMR studies on the resulting series of triple, quadruple and quintuple-decker complexes, ligand oxidation leads to a decrease in the magnetic anisotropy, as predicted from theoretical calculations. Unusual paramagnetic shifts were observed in the spectra of the +2e charged quadruple and quintuple-decker complexes, indicating that those two species are actually unexpected triplet biradicals. Magnetic measurements revealed that the series of complexes show single-molecule magnet properties, which are controlled by the multi-step redox induced structural changes.Presented here is a comprehensive study of highly oxidized multiple-decker complexes composed of TbIII and CdII ions and two to five phthalocyaninato ligands, which are stabilized by electron-donating n-butoxy groups. From X-ray structural analyses, all the complexes become axially compressed upon ligand oxidation, resulting in bowl-shaped distortions of the ligands. In addition, unusual coexistence of square antiprism and square prism geometries around metal ions was observed in +4e charged species. From paramagnetic 1 H NMR studies on the resulting series of triple, quadruple and quintuple-decker complexes, ligand oxidation leads to a decrease in the magnetic anisotropy, as predicted from theoretical calculations. Unusual paramagnetic shifts were observed in the spectra of the +2e charged quadruple and quintuple-decker complexes, indicating that those two species are actually unexpected triplet biradicals. Magnetic measurements revealed that the series of complexes show single-molecule magnet properties, which are controlled by the multi-step redox induced structural changes.
Author Damjanović, Marko
Ungur, Liviu
Kitagawa, Yasutaka
Breedlove, Brian K.
Yamashita, Masahiro
Chibotaru, Liviu
Veciana, Jaume
Ajayakumar, M. R.
Katoh, Keiichi
Mas‐Torrent, Marta
Wernsdorfer, Wolfgang
Enders, Markus
Horii, Yoji
AuthorAffiliation 2 Institute of Inorganic Chemistry Heidelberg University Im Neuenheimer Feld 270 69120 Heidelberg Germany
5 Theory of Nanomaterials Group Katholieke Universiteit Leuven 3001 Leuven Belgium
9 WPI-Advanced Institute for Materials Research Tohoku University 2-1-1 Katahira Sendai 980-8577 Japan
7 Institute of Nanotechnology (INT) Karlsruhe Institute of Technology (KIT) Hermann-von-Helmholtz-Platz 1 76344 Eggenstein-Leopoldshafen Germany
8 School of Materials Science and Engineering Nankai University Tianjin 300350 P. R. China
1 Department of Chemistry Graduate School of Science Tohoku University 6-3 Aramaki-Aza-Aoba Aoba-ku Sendai, Miyagi 980-8578 Japan
6 Department of Chemistry National University of Singapore 3 Science Drive 3 117543 Singapore Singapore
4 Department of Materials Engineering Science Graduate School of Engineering Science Osaka University 1-1 Machikaneyama-cho Toyonaka, Osaka 560-8531 Japan
3 Department of Molecular Nanoscience and Organic Materials Institut de Ciencia de Material
AuthorAffiliation_xml – name: 1 Department of Chemistry Graduate School of Science Tohoku University 6-3 Aramaki-Aza-Aoba Aoba-ku Sendai, Miyagi 980-8578 Japan
– name: 2 Institute of Inorganic Chemistry Heidelberg University Im Neuenheimer Feld 270 69120 Heidelberg Germany
– name: 5 Theory of Nanomaterials Group Katholieke Universiteit Leuven 3001 Leuven Belgium
– name: 9 WPI-Advanced Institute for Materials Research Tohoku University 2-1-1 Katahira Sendai 980-8577 Japan
– name: 8 School of Materials Science and Engineering Nankai University Tianjin 300350 P. R. China
– name: 4 Department of Materials Engineering Science Graduate School of Engineering Science Osaka University 1-1 Machikaneyama-cho Toyonaka, Osaka 560-8531 Japan
– name: 6 Department of Chemistry National University of Singapore 3 Science Drive 3 117543 Singapore Singapore
– name: 7 Institute of Nanotechnology (INT) Karlsruhe Institute of Technology (KIT) Hermann-von-Helmholtz-Platz 1 76344 Eggenstein-Leopoldshafen Germany
– name: 3 Department of Molecular Nanoscience and Organic Materials Institut de Ciencia de Materials de Barcelona (ICMAB-CSIC)/CIBER-BBN 08193 Bellaterra Spain
Author_xml – sequence: 1
  givenname: Yoji
  orcidid: 0000-0002-4789-6858
  surname: Horii
  fullname: Horii, Yoji
  email: yoji.horii.c5@tohoku.ac.jp
  organization: Tohoku University
– sequence: 2
  givenname: Marko
  surname: Damjanović
  fullname: Damjanović, Marko
  email: marko.damjanovic@kit.edu
  organization: Karlsruhe Institute of Technology (KIT)
– sequence: 3
  givenname: M. R.
  orcidid: 0000-0002-7041-7456
  surname: Ajayakumar
  fullname: Ajayakumar, M. R.
  organization: Institut de Ciencia de Materials de Barcelona (ICMAB-CSIC)/CIBER-BBN
– sequence: 4
  givenname: Keiichi
  orcidid: 0000-0002-0140-8222
  surname: Katoh
  fullname: Katoh, Keiichi
  email: keiichi.katoh.b3@tohoku.ac.jp
  organization: Tohoku University
– sequence: 5
  givenname: Yasutaka
  orcidid: 0000-0002-6583-7026
  surname: Kitagawa
  fullname: Kitagawa, Yasutaka
  organization: Osaka University
– sequence: 6
  givenname: Liviu
  surname: Chibotaru
  fullname: Chibotaru, Liviu
  organization: Katholieke Universiteit Leuven
– sequence: 7
  givenname: Liviu
  surname: Ungur
  fullname: Ungur, Liviu
  organization: National University of Singapore
– sequence: 8
  givenname: Marta
  orcidid: 0000-0002-1586-005X
  surname: Mas‐Torrent
  fullname: Mas‐Torrent, Marta
  organization: Institut de Ciencia de Materials de Barcelona (ICMAB-CSIC)/CIBER-BBN
– sequence: 9
  givenname: Wolfgang
  orcidid: 0000-0003-4602-5257
  surname: Wernsdorfer
  fullname: Wernsdorfer, Wolfgang
  organization: Karlsruhe Institute of Technology (KIT)
– sequence: 10
  givenname: Brian K.
  surname: Breedlove
  fullname: Breedlove, Brian K.
  organization: Tohoku University
– sequence: 11
  givenname: Markus
  orcidid: 0000-0003-0415-1992
  surname: Enders
  fullname: Enders, Markus
  email: markus.enders@uni-heidelberg.de
  organization: Heidelberg University
– sequence: 12
  givenname: Jaume
  surname: Veciana
  fullname: Veciana, Jaume
  email: vecianaj@icmab.es
  organization: Institut de Ciencia de Materials de Barcelona (ICMAB-CSIC)/CIBER-BBN
– sequence: 13
  givenname: Masahiro
  surname: Yamashita
  fullname: Yamashita, Masahiro
  email: masahiro.yamashita.c5@tohoku.ac.jp
  organization: Tohoku University
BackLink https://www.ncbi.nlm.nih.gov/pubmed/32428358$$D View this record in MEDLINE/PubMed
BookMark eNqFksFu1DAQhiNURLeFK0dkiUuR2MWJ42xyQSrbwq7UVSu1nC3HHm9cEnuxHdpw4hF4Eh6KJ8HLlgUqIU7WeL7_nxnNHCR7xhpIkqcpnqQYZ69EA90kwxnGKSnog2SU0iwdk2lB95IRrvLpuKCk2k8OvL_GGFcFIY-SfZLlWUloOUq-zfWqaQd0fqul_gwSXQYewCOr0EUTGt5aMXCjDQ8WXYGrdd8dLRaLF2jZt0GvW_j-5esJiA_g0Mx2Mb6N4svG3mizil6uF6F3vEUnoKzreNDW-JfojXZcahH_L5xdgws6qriRERMOuI-RNmjJVwaCFujYaG9DJIfHyUPFWw9P7t7D5P3b06vZfHx2_m4xOz4bC4opHVOqgNSY1qKsSqlyImpc1TlNC6lIVatKyBorSQgBmeagQJZUUVypghZEFBk5TF5vfdd93YEUYEKcgq2d7rgbmOWa_Z0xumEr-4lNSZnHVUSDozsDZz_24APrtBfQttyA7T3LckwJnuLpptbze-i17Z2J40UqI9EuozhSz_7saNfKr1VGYLIFhLPeO1A7JMVscytscytsdytRkN8TCB1-bihOpNt_y6qt7Ea3MPynCJvNT5e_tT8A0WnZIQ
CitedBy_id crossref_primary_10_1002_chem_202003761
crossref_primary_10_1142_S1088424623500104
crossref_primary_10_3390_magnetochemistry9020036
crossref_primary_10_1038_s41467_021_24693_6
crossref_primary_10_3390_molecules29020510
crossref_primary_10_1016_j_poly_2022_115792
crossref_primary_10_1002_ange_202102666
crossref_primary_10_1002_anie_202102666
crossref_primary_10_1246_bcsj_20200257
crossref_primary_10_3390_molecules27196498
crossref_primary_10_1021_acs_cgd_5c00111
crossref_primary_10_3390_molecules28114474
Cites_doi 10.1002/chem.201000276
10.1021/jacs.7b12667
10.1002/chem.201805368
10.1002/anie.201403091
10.1063/1.464913
10.1021/ja01047a004
10.1021/ic700954t
10.1039/c2dt31400b
10.1107/S0108767307043930
10.1021/cr030656l
10.1021/ja00784a066
10.1039/C2CS35418G
10.1016/j.poly.2006.09.020
10.1002/chem.201103037
10.1002/chem.201501944
10.1002/ange.201403091
10.1021/ja029629n
10.1021/jacs.5b00336
10.1021/ma60061a033
10.1039/c1cc14657b
10.1016/0010-8545(96)01242-8
10.1002/asia.201800324
10.1021/cr900182s
10.1016/j.jmr.2010.11.008
10.1021/ic8014892
10.1002/chem.201002026
10.1038/nnano.2012.258
10.1016/0009-2614(93)85294-X
10.1021/ja3064606
10.1002/ange.201205584
10.1021/acs.inorgchem.6b01870
10.1039/a904890a
10.1021/ja907077e
10.1021/jp002109z
10.1021/ja00287a034
10.1021/ja00273a018
10.1016/0010-8545(91)80024-8
10.1038/ncomms1210
10.1021/ja4069485
10.1002/chem.201805927
10.1021/ja00170a016
10.1038/nmat3142
10.1021/ja100125e
10.1016/0022-2364(72)90027-3
10.1038/nchem.2812
10.1038/s41586-019-1331-z
10.1002/anie.201205584
10.1002/9783527636402.ch4
10.1039/C5CS00183H
10.1103/PhysRevB.37.785
10.1021/ja000356a
10.1002/anie.199014671
10.1002/ange.19901021240
10.1021/cr000013v
10.1063/1.1674902
10.1021/j100124a012
10.1039/c1cp22689d
10.1126/science.1059552
10.1039/C2CC38088A
10.1002/chem.201301101
10.1021/ja00443a070
10.1021/ic502951t
10.1038/nmat3050
10.1039/c2dt31411h
ContentType Journal Article
Copyright 2020 The Authors. Published by Wiley-VCH Verlag GmbH & Co. KGaA.
2020 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
2020. This article is published under http://creativecommons.org/licenses/by-nc/4.0/ (the “License”). Notwithstanding the ProQuest Terms and Conditions, you may use this content in accordance with the terms of the License.
Copyright_xml – notice: 2020 The Authors. Published by Wiley-VCH Verlag GmbH & Co. KGaA.
– notice: 2020 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
– notice: 2020. This article is published under http://creativecommons.org/licenses/by-nc/4.0/ (the “License”). Notwithstanding the ProQuest Terms and Conditions, you may use this content in accordance with the terms of the License.
DBID 24P
AAYXX
CITATION
NPM
7SR
8BQ
8FD
JG9
K9.
7X8
5PM
DOI 10.1002/chem.202001365
DatabaseName Wiley Online Library Open Access
CrossRef
PubMed
Engineered Materials Abstracts
METADEX
Technology Research Database
Materials Research Database
ProQuest Health & Medical Complete (Alumni)
MEDLINE - Academic
PubMed Central (Full Participant titles)
DatabaseTitle CrossRef
PubMed
Materials Research Database
ProQuest Health & Medical Complete (Alumni)
Engineered Materials Abstracts
Technology Research Database
METADEX
MEDLINE - Academic
DatabaseTitleList CrossRef
PubMed
Materials Research Database


MEDLINE - Academic
Database_xml – sequence: 1
  dbid: 24P
  name: Wiley Online Library Open Access
  url: https://authorservices.wiley.com/open-science/open-access/browse-journals.html
  sourceTypes: Publisher
– sequence: 2
  dbid: NPM
  name: PubMed
  url: http://www.ncbi.nlm.nih.gov/entrez/query.fcgi?db=PubMed
  sourceTypes: Index Database
– sequence: 3
  dbid: 7X8
  name: MEDLINE - Academic
  url: https://search.proquest.com/medline
  sourceTypes: Aggregation Database
DeliveryMethod fulltext_linktorsrc
Discipline Chemistry
EISSN 1521-3765
EndPage 8630
ExternalDocumentID PMC7384013
32428358
10_1002_chem_202001365
CHEM202001365
Genre article
Journal Article
GrantInformation_xml – fundername: Deutsche Forschungsgemeinschaft
  funderid: INST 40/467-1 FUGG
– fundername: German-Japanese University Consortium
– fundername: Baden-Württemberg
  funderid: bwHPC
– fundername: Tohoku University Molecule & Material Synthesis Platform in Nanotechnology Platform Project
– fundername: Beilstein-Institut zur Förderung der Chemischen Wissenschaften
– fundername: Centro de Investigación Biomédica en Red en Bioingeniería, Biomateriales y Nanomedicina
– fundername: National University of Singapore
  funderid: R-143-000-A80-114; R-143-000-A65-133
– fundername: Ministerio de Economía y Competitividad
  funderid: FANCY CTQ2016-80030-R; MAT2016-80826-R; SEV-2015-0496
– fundername: Japan Society for the Promotion of Science
  funderid: JP14J02656; JP20225003; JP15K05467; JP24750119; 18K14242; 19K05401; JP17K19102
– fundername: European Commission
  funderid: ERC StG 2012-306826
– fundername: ;
– fundername: ;
  grantid: INST 40/467-1 FUGG
– fundername: ;
  grantid: ERC StG 2012-306826
– fundername: ;
  grantid: FANCY CTQ2016-80030-R; MAT2016-80826-R; SEV-2015-0496
– fundername: ;
  grantid: JPMJCR12L3
– fundername: ;
  grantid: B18030
– fundername: ;
  grantid: 2017SGR918
– fundername: ;
  grantid: JP14J02656; JP20225003; JP15K05467; JP24750119; 18K14242; 19K05401; JP17K19102
GroupedDBID ---
-DZ
-~X
.3N
.GA
05W
0R~
10A
1L6
1OB
1OC
1ZS
24P
29B
33P
3SF
3WU
4.4
4ZD
50Y
50Z
51W
51X
52M
52N
52O
52P
52S
52T
52U
52W
52X
53G
5GY
5VS
66C
6J9
702
77Q
7PT
8-0
8-1
8-3
8-4
8-5
8UM
930
A03
AAESR
AAEVG
AAHHS
AAHQN
AAMNL
AANLZ
AAONW
AASGY
AAXRX
AAYCA
AAZKR
ABCQN
ABCUV
ABDBF
ABIJN
ABJNI
ABLJU
ABPVW
ACAHQ
ACCFJ
ACCZN
ACGFS
ACIWK
ACNCT
ACPOU
ACUHS
ACXBN
ACXQS
ADBBV
ADEOM
ADIZJ
ADKYN
ADMGS
ADOZA
ADXAS
ADZMN
ADZOD
AEEZP
AEGXH
AEIGN
AEIMD
AEQDE
AEUQT
AEUYR
AFBPY
AFFPM
AFGKR
AFPWT
AFRAH
AFWVQ
AFZJQ
AHBTC
AHMBA
AITYG
AIURR
AIWBW
AJBDE
AJXKR
ALAGY
ALMA_UNASSIGNED_HOLDINGS
ALVPJ
AMBMR
AMYDB
ATUGU
AUFTA
AZBYB
AZVAB
BAFTC
BDRZF
BFHJK
BHBCM
BMNLL
BMXJE
BNHUX
BROTX
BRXPI
BY8
CS3
D-E
D-F
DCZOG
DPXWK
DR2
DRFUL
DRSTM
EBD
EBS
F00
F01
F04
F5P
G-S
G.N
GNP
GODZA
H.T
H.X
HBH
HGLYW
HHY
HHZ
HZ~
IX1
J0M
JPC
KQQ
LATKE
LAW
LC2
LC3
LEEKS
LH4
LITHE
LOXES
LP6
LP7
LUTES
LYRES
MEWTI
MK4
MRFUL
MRSTM
MSFUL
MSSTM
MXFUL
MXSTM
N04
N05
N9A
NF~
NNB
O66
O9-
OIG
P2W
P2X
P4D
PQQKQ
Q.N
Q11
QB0
QRW
R.K
RGC
RNS
ROL
RWI
RX1
RYL
SUPJJ
TN5
TWZ
UB1
UPT
V2E
V8K
W8V
W99
WBFHL
WBKPD
WH7
WIB
WIH
WIK
WJL
WOHZO
WQJ
WRC
WXSBR
WYISQ
XG1
XPP
XV2
YZZ
ZZTAW
~IA
~WT
AAYXX
AEYWJ
AGHNM
AGYGG
CITATION
O8X
NPM
7SR
8BQ
8FD
JG9
K9.
7X8
5PM
ID FETCH-LOGICAL-c5055-55fe3b05bc898df43cb09b4516df39bf9cdb0fd333ed14efed85f509f6563c623
IEDL.DBID 24P
ISICitedReferencesCount 19
ISICitedReferencesURI http://www.webofscience.com/api/gateway?GWVersion=2&SrcApp=Summon&SrcAuth=ProQuest&DestLinkType=CitingArticles&DestApp=WOS_CPL&KeyUT=000540746500001&url=https%3A%2F%2Fcvtisr.summon.serialssolutions.com%2F%23%21%2Fsearch%3Fho%3Df%26include.ft.matches%3Dt%26l%3Dnull%26q%3D
ISSN 0947-6539
1521-3765
IngestDate Tue Sep 30 16:40:53 EDT 2025
Wed Oct 01 14:28:25 EDT 2025
Tue Oct 07 06:49:30 EDT 2025
Wed Feb 19 02:30:59 EST 2025
Sat Nov 29 07:09:13 EST 2025
Tue Nov 18 21:16:20 EST 2025
Wed Jan 22 16:33:01 EST 2025
IsDoiOpenAccess true
IsOpenAccess true
IsPeerReviewed true
IsScholarly true
Issue 39
Keywords Redox, Biradical, Magnetic anisotropy, NMR, Crystal engineering
Language English
License Attribution-NonCommercial
2020 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
This is an open access article under the terms of the http://creativecommons.org/licenses/by-nc/4.0/ License, which permits use, distribution and reproduction in any medium, provided the original work is properly cited and is not used for commercial purposes.
LinkModel DirectLink
MergedId FETCHMERGED-LOGICAL-c5055-55fe3b05bc898df43cb09b4516df39bf9cdb0fd333ed14efed85f509f6563c623
Notes Dedicated to Prof. Dr. Walter Siebert
These authors contributed equally to this work.
ObjectType-Article-1
SourceType-Scholarly Journals-1
ObjectType-Feature-2
content type line 14
content type line 23
ORCID 0000-0002-0140-8222
0000-0002-4789-6858
0000-0002-7041-7456
0000-0003-4602-5257
0000-0002-6583-7026
0000-0003-0415-1992
0000-0002-1586-005X
OpenAccessLink https://onlinelibrary.wiley.com/doi/abs/10.1002%2Fchem.202001365
PMID 32428358
PQID 2423401250
PQPubID 986340
PageCount 10
ParticipantIDs pubmedcentral_primary_oai_pubmedcentral_nih_gov_7384013
proquest_miscellaneous_2405307072
proquest_journals_2423401250
pubmed_primary_32428358
crossref_primary_10_1002_chem_202001365
crossref_citationtrail_10_1002_chem_202001365
wiley_primary_10_1002_chem_202001365_CHEM202001365
PublicationCentury 2000
PublicationDate July 14, 2020
PublicationDateYYYYMMDD 2020-07-14
PublicationDate_xml – month: 07
  year: 2020
  text: July 14, 2020
  day: 14
PublicationDecade 2020
PublicationPlace Germany
PublicationPlace_xml – name: Germany
– name: Weinheim
– name: Hoboken
PublicationSubtitle A European Journal
PublicationTitle Chemistry : a European journal
PublicationTitleAlternate Chemistry
PublicationYear 2020
Publisher Wiley Subscription Services, Inc
John Wiley and Sons Inc
Publisher_xml – name: Wiley Subscription Services, Inc
– name: John Wiley and Sons Inc
References 1991; 110
2014 2014; 53 126
1990 1990; 29 102
1965; 10
1973; 95
2010; 16
1988; 37
2011; 10
1973
2012; 18
2011; 13
2011; 17
2013; 8
1993; 203
2017; 9
2013 2013; 52 125
2013; 19
1986; 108
1971; 54
2011; 208
2001; 293
2012; 134
2015; 137
1967; 12
2015; 44
2019; 25
2000; 122
2008; 64
2003; 125
2007; 26
1972; 8
2004; 104
2011; 2
2018; 140
2013; 49
1978; 11
1969; 91
2011
2013; 42
2015; 54
1985; 107
1999
2016; 55
2000; 104
1993; 98
1993; 97
2015; 21
2010; 132
2008; 47
1996; 150
2013; 135
1977; 99
2011; 47
1990; 112
2009; 109
2007; 46
2019; 571
2012; 41
2018; 13
e_1_2_6_53_1
e_1_2_6_32_1
e_1_2_6_30_2
e_1_2_6_30_1
e_1_2_6_19_1
e_1_2_6_13_1
e_1_2_6_36_1
e_1_2_6_59_1
e_1_2_6_34_2
e_1_2_6_11_1
e_1_2_6_34_1
e_1_2_6_17_1
e_1_2_6_55_1
e_1_2_6_15_1
e_1_2_6_38_1
e_1_2_6_57_1
e_1_2_6_15_2
e_1_2_6_62_1
e_1_2_6_64_1
e_1_2_6_43_1
e_1_2_6_20_1
e_1_2_6_41_1
e_1_2_6_60_1
e_1_2_6_9_1
e_1_2_6_5_1
e_1_2_6_7_1
e_1_2_6_1_1
e_1_2_6_49_1
e_1_2_6_3_1
Kirin I. S. (e_1_2_6_22_1) 1965; 10
e_1_2_6_28_1
e_1_2_6_45_1
e_1_2_6_26_1
e_1_2_6_47_1
e_1_2_6_52_1
e_1_2_6_54_1
e_1_2_6_10_1
e_1_2_6_31_1
e_1_2_6_50_1
Kirin I. S. (e_1_2_6_24_1) 1967; 12
e_1_2_6_14_1
e_1_2_6_35_1
e_1_2_6_12_1
Kirin I. S. (e_1_2_6_23_1) 1967; 12
e_1_2_6_33_1
La Mar G. N. (e_1_2_6_51_1) 1973
e_1_2_6_18_1
e_1_2_6_39_1
e_1_2_6_56_1
e_1_2_6_16_1
e_1_2_6_37_1
e_1_2_6_58_1
e_1_2_6_63_1
e_1_2_6_42_1
e_1_2_6_65_1
e_1_2_6_21_1
e_1_2_6_40_1
e_1_2_6_61_1
e_1_2_6_8_1
e_1_2_6_4_1
e_1_2_6_6_1
e_1_2_6_25_1
e_1_2_6_48_1
e_1_2_6_2_1
e_1_2_6_29_1
e_1_2_6_44_1
e_1_2_6_27_1
e_1_2_6_46_1
References_xml – year: 2011
– volume: 132
  start-page: 6870
  year: 2010
  end-page: 6871
  publication-title: J. Am. Chem. Soc.
– volume: 54
  start-page: 724
  year: 1971
  end-page: 728
  publication-title: J. Chem. Phys.
– volume: 19
  start-page: 11162
  year: 2013
  end-page: 11166
  publication-title: Chem. Eur. J.
– volume: 203
  start-page: 472
  year: 1993
  end-page: 476
  publication-title: Chem. Phys. Lett.
– volume: 13
  start-page: 1692
  year: 2018
  end-page: 1698
  publication-title: Chem. Asian J.
– volume: 17
  start-page: 117
  year: 2011
  end-page: 122
  publication-title: Chem. Eur. J.
– volume: 11
  start-page: 186
  year: 1978
  end-page: 191
  publication-title: Macromolecules
– volume: 18
  start-page: 1047
  year: 2012
  end-page: 1049
  publication-title: Chem. Eur. J.
– volume: 26
  start-page: 1859
  year: 2007
  end-page: 1862
  publication-title: Polyhedron
– volume: 47
  start-page: 11686
  year: 2011
  end-page: 11688
  publication-title: Chem. Commun.
– volume: 134
  start-page: 14698
  year: 2012
  end-page: 14701
  publication-title: J. Am. Chem. Soc.
– volume: 2
  start-page: 217
  year: 2011
  publication-title: Nat. Commun.
– volume: 140
  start-page: 2995
  year: 2018
  end-page: 3007
  publication-title: J. Am. Chem. Soc.
– volume: 110
  start-page: 115
  year: 1991
  end-page: 160
  publication-title: Coord. Chem. Rev.
– volume: 10
  start-page: 947
  year: 2011
  publication-title: Nat. Mater.
– volume: 109
  start-page: 5868
  year: 2009
  end-page: 5923
  publication-title: Chem. Rev.
– volume: 112
  start-page: 5525
  year: 1990
  end-page: 5534
  publication-title: J. Am. Chem. Soc.
– volume: 25
  start-page: 3240
  year: 2019
  end-page: 3243
  publication-title: Chem. Eur. J.
– volume: 95
  start-page: 948
  year: 1973
  end-page: 949
  publication-title: J. Am. Chem. Soc.
– volume: 9
  start-page: 1133
  year: 2017
  end-page: 1139
  publication-title: Nat. Chem.
– volume: 41
  start-page: 13705
  year: 2012
  end-page: 13710
  publication-title: Dalton Trans.
– volume: 55
  start-page: 11782
  year: 2016
  end-page: 11790
  publication-title: Inorg. Chem.
– volume: 52 125
  start-page: 397 415
  year: 2013 2013
  end-page: 400 418
  publication-title: Angew. Chem. Int. Ed. Angew. Chem.
– volume: 98
  start-page: 5648
  year: 1993
  end-page: 5652
  publication-title: J. Chem. Phys.
– volume: 208
  start-page: 179
  year: 2011
  end-page: 194
  publication-title: J. Magn. Reson.
– volume: 107
  start-page: 192
  year: 1985
  end-page: 195
  publication-title: J. Am. Chem. Soc.
– volume: 64
  start-page: 112
  year: 2008
  end-page: 122
  publication-title: Acta Crystallogr. Sect. A
– volume: 41
  start-page: 13582
  year: 2012
  end-page: 13600
  publication-title: Dalton Trans.
– volume: 8
  start-page: 165
  year: 2013
  end-page: 169
  publication-title: Nat. Nanotechnol.
– volume: 37
  start-page: 785
  year: 1988
  end-page: 789
  publication-title: Phys. Rev. B
– volume: 13
  start-page: 20086
  year: 2011
  end-page: 20090
  publication-title: Phys. Chem. Chem. Phys.
– volume: 293
  start-page: 79
  year: 2001
  end-page: 82
  publication-title: Science
– volume: 12
  start-page: 369
  year: 1967
  end-page: 372
  publication-title: Russ. J. Inorg. Chem.
– start-page: 3259
  year: 1999
  end-page: 3264
  publication-title: J. Chem. Soc. Perkin 1
– volume: 44
  start-page: 6616
  year: 2015
  end-page: 6643
  publication-title: Chem. Soc. Rev.
– volume: 25
  start-page: 3098
  year: 2019
  end-page: 3104
  publication-title: Chem. Eur. J.
– volume: 12
  start-page: 497
  year: 1967
  end-page: 498
  publication-title: Russ. J. Inorg. Chem.
– volume: 109
  start-page: 897
  year: 2009
  end-page: 1091
  publication-title: Chem. Rev.
– volume: 99
  start-page: 286
  year: 1977
  end-page: 288
  publication-title: J. Am. Chem. Soc.
– volume: 108
  start-page: 3652
  year: 1986
  end-page: 3659
  publication-title: J. Am. Chem. Soc.
– volume: 53 126
  start-page: 10082 10246
  year: 2014 2014
  end-page: 10085 10249
  publication-title: Angew. Chem. Int. Ed. Angew. Chem.
– volume: 10
  start-page: 1065
  year: 1965
  end-page: 1066
  publication-title: Russ. J. Inorg. Chem.
– volume: 104
  start-page: 5243
  year: 2004
  end-page: 5264
  publication-title: Chem. Rev.
– volume: 47
  start-page: 10217
  year: 2008
  end-page: 10219
  publication-title: Inorg. Chem.
– year: 1973
– volume: 49
  start-page: 889
  year: 2013
  end-page: 891
  publication-title: Chem. Commun.
– volume: 8
  start-page: 91
  year: 1972
  end-page: 100
  publication-title: J. Magn. Reson.
– volume: 132
  start-page: 6278
  year: 2010
  end-page: 6279
  publication-title: J. Am. Chem. Soc.
– volume: 46
  start-page: 7250
  year: 2007
  end-page: 7252
  publication-title: Inorg. Chem.
– volume: 125
  start-page: 8694
  year: 2003
  end-page: 8695
  publication-title: J. Am. Chem. Soc.
– volume: 97
  start-page: 5852
  year: 1993
  end-page: 5859
  publication-title: J. Phys. Chem. C
– volume: 42
  start-page: 1921
  year: 2013
  end-page: 1933
  publication-title: Chem. Soc. Rev.
– volume: 150
  start-page: 29
  year: 1996
  end-page: 75
  publication-title: Coord. Chem. Rev.
– volume: 135
  start-page: 14349
  year: 2013
  end-page: 14358
  publication-title: J. Am. Chem. Soc.
– volume: 16
  start-page: 8285
  year: 2010
  end-page: 8290
  publication-title: Chem. Eur. J.
– volume: 10
  start-page: 502
  year: 2011
  end-page: 506
  publication-title: Nat. Mater.
– volume: 122
  start-page: 7921
  year: 2000
  end-page: 7926
  publication-title: J. Am. Chem. Soc.
– volume: 137
  start-page: 3124
  year: 2015
  end-page: 3130
  publication-title: J. Am. Chem. Soc.
– volume: 29 102
  start-page: 1467 1499
  year: 1990 1990
  end-page: 1468 1501
  publication-title: Angew. Chem. Int. Ed. Engl. Angew. Chem.
– volume: 21
  start-page: 14421
  year: 2015
  end-page: 14432
  publication-title: Chem. Eur. J.
– volume: 571
  start-page: 387
  year: 2019
  end-page: 392
  publication-title: Nature
– volume: 104
  start-page: 10009
  year: 2000
  end-page: 10016
  publication-title: J. Phys. Chem. A
– volume: 91
  start-page: 5210
  year: 1969
  end-page: 5214
  publication-title: J. Am. Chem. Soc.
– volume: 54
  start-page: 3297
  year: 2015
  end-page: 3305
  publication-title: Inorg. Chem.
– ident: e_1_2_6_29_1
  doi: 10.1002/chem.201000276
– ident: e_1_2_6_54_1
  doi: 10.1021/jacs.7b12667
– ident: e_1_2_6_45_1
  doi: 10.1002/chem.201805368
– ident: e_1_2_6_34_1
  doi: 10.1002/anie.201403091
– ident: e_1_2_6_56_1
  doi: 10.1063/1.464913
– ident: e_1_2_6_17_1
  doi: 10.1021/ja01047a004
– ident: e_1_2_6_40_1
  doi: 10.1021/ic700954t
– ident: e_1_2_6_43_1
  doi: 10.1039/c2dt31400b
– ident: e_1_2_6_48_1
  doi: 10.1107/S0108767307043930
– ident: e_1_2_6_13_1
  doi: 10.1021/cr030656l
– ident: e_1_2_6_10_1
  doi: 10.1021/ja00784a066
– ident: e_1_2_6_1_1
  doi: 10.1039/C2CS35418G
– ident: e_1_2_6_39_1
  doi: 10.1016/j.poly.2006.09.020
– ident: e_1_2_6_20_1
  doi: 10.1002/chem.201103037
– ident: e_1_2_6_32_1
  doi: 10.1002/chem.201501944
– ident: e_1_2_6_34_2
  doi: 10.1002/ange.201403091
– ident: e_1_2_6_36_1
  doi: 10.1021/ja029629n
– ident: e_1_2_6_5_1
  doi: 10.1021/jacs.5b00336
– ident: e_1_2_6_14_1
  doi: 10.1021/ma60061a033
– ident: e_1_2_6_26_1
  doi: 10.1039/c1cc14657b
– ident: e_1_2_6_49_1
  doi: 10.1016/0010-8545(96)01242-8
– ident: e_1_2_6_31_1
  doi: 10.1002/asia.201800324
– volume: 10
  start-page: 1065
  year: 1965
  ident: e_1_2_6_22_1
  publication-title: Russ. J. Inorg. Chem.
– ident: e_1_2_6_2_1
  doi: 10.1021/cr900182s
– ident: e_1_2_6_55_1
  doi: 10.1016/j.jmr.2010.11.008
– ident: e_1_2_6_41_1
  doi: 10.1021/ic8014892
– ident: e_1_2_6_47_1
  doi: 10.1002/chem.201002026
– ident: e_1_2_6_38_1
  doi: 10.1038/nnano.2012.258
– ident: e_1_2_6_60_1
  doi: 10.1016/0009-2614(93)85294-X
– ident: e_1_2_6_42_1
  doi: 10.1021/ja3064606
– ident: e_1_2_6_30_2
  doi: 10.1002/ange.201205584
– ident: e_1_2_6_46_1
  doi: 10.1021/acs.inorgchem.6b01870
– ident: e_1_2_6_28_1
  doi: 10.1039/a904890a
– ident: e_1_2_6_33_1
  doi: 10.1021/ja907077e
– ident: e_1_2_6_61_1
  doi: 10.1021/jp002109z
– ident: e_1_2_6_18_1
  doi: 10.1021/ja00287a034
– ident: e_1_2_6_25_1
  doi: 10.1021/ja00273a018
– ident: e_1_2_6_12_1
  doi: 10.1016/0010-8545(91)80024-8
– ident: e_1_2_6_35_1
  doi: 10.1038/ncomms1210
– ident: e_1_2_6_53_1
  doi: 10.1021/ja4069485
– ident: e_1_2_6_63_1
  doi: 10.1002/chem.201805927
– ident: e_1_2_6_6_1
  doi: 10.1021/ja00170a016
– ident: e_1_2_6_4_1
  doi: 10.1038/nmat3142
– ident: e_1_2_6_19_1
  doi: 10.1021/ja100125e
– ident: e_1_2_6_52_1
  doi: 10.1016/0022-2364(72)90027-3
– ident: e_1_2_6_16_1
  doi: 10.1038/nchem.2812
– volume: 12
  start-page: 497
  year: 1967
  ident: e_1_2_6_23_1
  publication-title: Russ. J. Inorg. Chem.
– ident: e_1_2_6_8_1
  doi: 10.1038/s41586-019-1331-z
– ident: e_1_2_6_30_1
  doi: 10.1002/anie.201205584
– ident: e_1_2_6_50_1
  doi: 10.1002/9783527636402.ch4
– ident: e_1_2_6_7_1
  doi: 10.1039/C5CS00183H
– ident: e_1_2_6_57_1
  doi: 10.1103/PhysRevB.37.785
– ident: e_1_2_6_27_1
  doi: 10.1021/ja000356a
– ident: e_1_2_6_15_1
  doi: 10.1002/anie.199014671
– ident: e_1_2_6_15_2
  doi: 10.1002/ange.19901021240
– volume: 12
  start-page: 369
  year: 1967
  ident: e_1_2_6_24_1
  publication-title: Russ. J. Inorg. Chem.
– ident: e_1_2_6_3_1
  doi: 10.1021/cr000013v
– ident: e_1_2_6_58_1
  doi: 10.1063/1.1674902
– ident: e_1_2_6_59_1
  doi: 10.1021/j100124a012
– ident: e_1_2_6_64_1
  doi: 10.1039/c1cp22689d
– ident: e_1_2_6_9_1
  doi: 10.1126/science.1059552
– volume-title: NMR of Paramagnetic Molecules—Principles and Applications
  year: 1973
  ident: e_1_2_6_51_1
– ident: e_1_2_6_21_1
  doi: 10.1039/C2CC38088A
– ident: e_1_2_6_62_1
  doi: 10.1002/chem.201301101
– ident: e_1_2_6_11_1
  doi: 10.1021/ja00443a070
– ident: e_1_2_6_44_1
  doi: 10.1021/ic502951t
– ident: e_1_2_6_37_1
  doi: 10.1038/nmat3050
– ident: e_1_2_6_65_1
  doi: 10.1039/c2dt31411h
SSID ssj0009633
Score 2.429794
Snippet Presented here is a comprehensive study of highly oxidized multiple‐decker complexes composed of TbIII and CdII ions and two to five phthalocyaninato ligands,...
Presented here is a comprehensive study of highly oxidized multiple‐decker complexes composed of Tb III and Cd II ions and two to five phthalocyaninato...
Herein we present a comprehensive study of highly oxidized multiple-decker complexes composed of Tb(III) and Cd(II) ions and two to five phthalocyaninato...
Presented here is a comprehensive study of highly oxidized multiple-decker complexes composed of TbIII and CdII ions and two to five phthalocyaninato ligands,...
SourceID pubmedcentral
proquest
pubmed
crossref
wiley
SourceType Open Access Repository
Aggregation Database
Index Database
Enrichment Source
Publisher
StartPage 8621
SubjectTerms Anisotropy
biradical
Chemistry
Coexistence
Coordination compounds
crystal engineering
Ligands
Magnetic anisotropy
Magnetic measurement
Magnetic properties
Metal ions
NMR
Nuclear magnetic resonance
Oxidation
redox
Terbium
Title Highly Oxidized States of Phthalocyaninato Terbium(III) Multiple‐Decker Complexes Showing Structural Deformations, Biradical Properties and Decreases in Magnetic Anisotropy
URI https://onlinelibrary.wiley.com/doi/abs/10.1002%2Fchem.202001365
https://www.ncbi.nlm.nih.gov/pubmed/32428358
https://www.proquest.com/docview/2423401250
https://www.proquest.com/docview/2405307072
https://pubmed.ncbi.nlm.nih.gov/PMC7384013
Volume 26
WOSCitedRecordID wos000540746500001&url=https%3A%2F%2Fcvtisr.summon.serialssolutions.com%2F%23%21%2Fsearch%3Fho%3Df%26include.ft.matches%3Dt%26l%3Dnull%26q%3D
hasFullText 1
inHoldings 1
isFullTextHit
isPrint
journalDatabaseRights – providerCode: PRVWIB
  databaseName: Wiley Online Library Full Collection 2020
  customDbUrl:
  eissn: 1521-3765
  dateEnd: 99991231
  omitProxy: false
  ssIdentifier: ssj0009633
  issn: 0947-6539
  databaseCode: DRFUL
  dateStart: 19980101
  isFulltext: true
  titleUrlDefault: https://onlinelibrary.wiley.com
  providerName: Wiley-Blackwell
link http://cvtisr.summon.serialssolutions.com/2.0.0/link/0/eLvHCXMwpV1fb9MwELfGhgQvMP4MAmMyEhIgES2xncZ5HCsVldio2Cb1LXJim0YqDmo6WPe0j8An4UPxSbhL0mzVhJDgJUrks2Lr7uyfffbvCHkhg15gpYn9gCkMMzLlq7An_UADOjci11KqOtlEfHgox-NkdOUWf8MP0W24oWfU4zU6uMqq3UvSUOgT3iRnNetYdINshCGXmLyBidEl7W6vTSYvYh9JWJe0jQHbXa2_Oi1dw5rXj0xehbL1XDS4-_-92CR3WhxK9xrDuUfWjLtPbu0v0789ID_xBMh0QT-eFbo4N5o2sJSWlo4m84mCSXChXOFg0U6PQTfF6ZdXw-HwNT1ojyj-uvjRN3hog-KYMzVnUPloUn6HuZIe1ay1yPhB-6a7P1m9oW-LmaojR3SEUYIZ0r1S5TSIIbyt4Ktw9EB9dnj5ku65oirnILl4SE4G74733_ttcgc_B9AV-VFkDc-CKMtlIrUVPM-CJMO0wdryJLNJrrPAas650aEw1mgZWUA3FgAozwG0bZF1VzrzmFAdmUTnTETCMMFFlmhjeybIAN1YGxvpEX-p2zRvmc8xAcc0bTibWYpaSDsteORlJ_-14fz4o-T20lTS1verFBEqrFoBW3rkeVcM2sNQjHKmPEUZGPyQaYl55FFjWd2vEOICLoZmxys21wkgI_hqiSsmNTN4zCWulz3Capv7S-tTZN3ovp78S6Wn5Da-42Z3KLbJOliPeUZu5t_mRTXbqX0RnvFY7pCN_qfByYffKDI8Gw
linkProvider Wiley-Blackwell
linkToHtml http://cvtisr.summon.serialssolutions.com/2.0.0/link/0/eLvHCXMwrV1fb9MwED_BQBov_P8TGGAkJEBatNRxGudxbEyrWEulFWlvkRPbNFJxUNPByhMfgU_Ch-KTcJekGdWEkBCPjs-KrTv7frbPvwN4LoN-YKWJ_YArumbkyle9vvQDjejciFxLqepkE_FoJE9OknEbTUhvYRp-iO7AjWZGvV7TBKcD6Z1z1lAcFD0l5zXtWHQZrgh0NWTqXIzPeXf7bTZ5EfvEwrribQz4znr7db90AWxejJn8HcvWzujgxn8Yxk243iJRttuYzi24ZNxt2NxbJYC7Az8oBmS2ZO_OCl18NZo1wJSVlo2ni6lCN7hUrnC4bWcT1E5x-vHlYDB4xYZtkOLPb9_3DYVtMFp1ZuYMGx9Pyy_oLdlxzVtLnB9s33QvKKtt9rqYq_ruiI3pnmBOhK9MOY1iBHArLBWODdUHR88v2a4rqnKBksu78P7gzWTv0G_TO_g5wq7IjyJrwiyIslwmUlsR5lmQZJQ4WNswyWyS6yywOgxDo3vCWKNlZBHfWISgYY6w7R5suNKZB8B0ZBKdcxEJw0UoskQb2zdBhvjG2thID_yVctO85T6nFByztGFt5ilpIe204MGLTv5Tw_rxR8mtla2k7eyvUsKouG9FdOnBs64atUeXMcqZ8pRkcPkjriXuwf3GtLpfEchFZIzdjteMrhMgTvD1GldMa27wOJS0Y_aA10b3l96nxLvRlR7-S6OnsHk4GR6lR4PR20dwjb7T0XdPbMEGWpJ5DFfzz4uimj-pJ-Yvjb49fg
linkToPdf http://cvtisr.summon.serialssolutions.com/2.0.0/link/0/eLvHCXMwrV1tb9MwED5Bh4AvvL8EBhgJCZCIlualcT6OlYqKrVRsk_YtcuIzjVScqe1g5RM_gV_Cj-KXcJekGdWEkBAfnZwTW3e2H_vOzwE8k17PMxJj1_MVuxl95apuT7qeJnSOYa6lVFWyiXg0kkdHybiJJuS7MDU_RHvgxiOjmq95gOOxNltnrKHUKb5K7le0Y9FF2Ag5k0wHNvofBoe7Z8y7vSaffBi7zMO6Ym70_K31L6yvTOfg5vmoyd_RbLUcDa7_h47cgGsNFhXbtfHchAtob8GVnVUKuNvwg6NApkvx_rTQxVfUooamojRiPFlMFC2ES2ULSxt3cUD6KU4-vRgOhy_FXhOm-PPb9z5y4IbgeWeKp1R5f1J-ofVS7FfMtcz6IfrY3qGcvxKvi5mqvEdizJ6CGVO-CmU1iTHEnVOpsGJPfbR8AVNs22JeLkhyeQcOB28Odt66TYIHNyfgFblRZDDIvCjLZSK1CYM885KMUwdrEySZSXKdeUYHQYC6G6JBLSNDCMcQCA1yAm53oWNLi_dB6AgTnfthFKIfBmGWaDQ99DJCOMbEKB1wV8pN84b9nJNwTNOat9lPWQtpqwUHnrfyxzXvxx8lN1e2kjbjf54ySqWdK-FLB562r0l77I5RFssTlqEJkNmWfAfu1abV_ophLmFjana8ZnStALOCr7-xxaRiB48DyXtmB_zK6P7S-pSZN9rSg3-p9AQuj_uDdHc4evcQrvJjPvvuhpvQIUPCR3Ap_7wo5rPHzcj8BXkmPpQ
openUrl ctx_ver=Z39.88-2004&ctx_enc=info%3Aofi%2Fenc%3AUTF-8&rfr_id=info%3Asid%2Fsummon.serialssolutions.com&rft_val_fmt=info%3Aofi%2Ffmt%3Akev%3Amtx%3Ajournal&rft.genre=article&rft.atitle=Highly+Oxidized+States+of+Phthalocyaninato+Terbium%28III%29+Multiple-Decker+Complexes+Showing+Structural+Deformations%2C+Biradical+Properties+and+Decreases+in+Magnetic+Anisotropy&rft.jtitle=Chemistry+%3A+a+European+journal&rft.au=Horii%2C+Yoji&rft.au=Damjanovi%C4%87%2C+Marko&rft.au=Ajayakumar%2C+M+R&rft.au=Katoh%2C+Keiichi&rft.date=2020-07-14&rft.issn=1521-3765&rft.eissn=1521-3765&rft.volume=26&rft.issue=39&rft.spage=8621&rft_id=info:doi/10.1002%2Fchem.202001365&rft.externalDBID=NO_FULL_TEXT
thumbnail_l http://covers-cdn.summon.serialssolutions.com/index.aspx?isbn=/lc.gif&issn=0947-6539&client=summon
thumbnail_m http://covers-cdn.summon.serialssolutions.com/index.aspx?isbn=/mc.gif&issn=0947-6539&client=summon
thumbnail_s http://covers-cdn.summon.serialssolutions.com/index.aspx?isbn=/sc.gif&issn=0947-6539&client=summon