Highly Oxidized States of Phthalocyaninato Terbium(III) Multiple‐Decker Complexes Showing Structural Deformations, Biradical Properties and Decreases in Magnetic Anisotropy

Presented here is a comprehensive study of highly oxidized multiple‐decker complexes composed of TbIII and CdII ions and two to five phthalocyaninato ligands, which are stabilized by electron‐donating n‐butoxy groups. From X‐ray structural analyses, all the complexes become axially compressed upon l...

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Veröffentlicht in:Chemistry : a European journal Jg. 26; H. 39; S. 8621 - 8630
Hauptverfasser: Horii, Yoji, Damjanović, Marko, Ajayakumar, M. R., Katoh, Keiichi, Kitagawa, Yasutaka, Chibotaru, Liviu, Ungur, Liviu, Mas‐Torrent, Marta, Wernsdorfer, Wolfgang, Breedlove, Brian K., Enders, Markus, Veciana, Jaume, Yamashita, Masahiro
Format: Journal Article
Sprache:Englisch
Veröffentlicht: Germany Wiley Subscription Services, Inc 14.07.2020
John Wiley and Sons Inc
Schlagworte:
Anisotropy
biradical
Chemistry
Coexistence
Coordination compounds
crystal engineering
Ligands
Magnetic anisotropy
Magnetic measurement
Magnetic properties
Metal ions
NMR
Nuclear magnetic resonance
Oxidation
redox
Terbium
Redox, Biradical, Magnetic anisotropy, NMR, Crystal engineering
ISSN:0947-6539, 1521-3765, 1521-3765
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Abstract Presented here is a comprehensive study of highly oxidized multiple‐decker complexes composed of TbIII and CdII ions and two to five phthalocyaninato ligands, which are stabilized by electron‐donating n‐butoxy groups. From X‐ray structural analyses, all the complexes become axially compressed upon ligand oxidation, resulting in bowl‐shaped distortions of the ligands. In addition, unusual coexistence of square antiprism and square prism geometries around metal ions was observed in +4e charged species. From paramagnetic 1H NMR studies on the resulting series of triple, quadruple and quintuple‐decker complexes, ligand oxidation leads to a decrease in the magnetic anisotropy, as predicted from theoretical calculations. Unusual paramagnetic shifts were observed in the spectra of the +2e charged quadruple and quintuple‐decker complexes, indicating that those two species are actually unexpected triplet biradicals. Magnetic measurements revealed that the series of complexes show single‐molecule magnet properties, which are controlled by the multi‐step redox induced structural changes. Stacking up: From extensive studies on highly oxidized species of phthalocyaninato‐lanthanoid‐cadmium multiple‐decker complexes, the complexes had staggered and eclipsed conformations and showed complicated changes in their magnetic anisotropies and biradical properties.
AbstractList Presented here is a comprehensive study of highly oxidized multiple‐decker complexes composed of Tb III and Cd II ions and two to five phthalocyaninato ligands, which are stabilized by electron‐donating n ‐butoxy groups. From X‐ray structural analyses, all the complexes become axially compressed upon ligand oxidation, resulting in bowl‐shaped distortions of the ligands. In addition, unusual coexistence of square antiprism and square prism geometries around metal ions was observed in +4 e charged species. From paramagnetic 1 H NMR studies on the resulting series of triple, quadruple and quintuple‐decker complexes, ligand oxidation leads to a decrease in the magnetic anisotropy, as predicted from theoretical calculations. Unusual paramagnetic shifts were observed in the spectra of the +2 e charged quadruple and quintuple‐decker complexes, indicating that those two species are actually unexpected triplet biradicals. Magnetic measurements revealed that the series of complexes show single‐molecule magnet properties, which are controlled by the multi‐step redox induced structural changes.
Herein we present a comprehensive study of highly oxidized multiple-decker complexes composed of Tb(III) and Cd(II) ions and two to five phthalocyaninato ligands, which are stabilized by electron-donating n -butoxy groups. From X-ray structural analyses, all the complexes become axially compressed upon ligand oxidation, resulting in bowl-shaped distortions of the ligands. In addition, unusual coexistence of square antiprism and square prism geometries around metal ions was observed in +4 e charged species. From paramagnetic 1 H NMR studies on the resulting series of triple, quadruple and quintuple-decker complexes, ligand oxidation leads to a decrease in the magnetic anisotropy, as predicted from theoretical calculations. Unusual paramagnetic shifts were observed in the spectra of the +2 e charged quadruple and quintuple-decker complexes, indicating that those two species are actually unexpected triplet biradicals. Magnetic measurements revealed that the series of complexes show single-molecule magnet properties, which are controlled by the multi-step redox induced structural changes.
Presented here is a comprehensive study of highly oxidized multiple‐decker complexes composed of TbIII and CdII ions and two to five phthalocyaninato ligands, which are stabilized by electron‐donating n‐butoxy groups. From X‐ray structural analyses, all the complexes become axially compressed upon ligand oxidation, resulting in bowl‐shaped distortions of the ligands. In addition, unusual coexistence of square antiprism and square prism geometries around metal ions was observed in +4e charged species. From paramagnetic 1H NMR studies on the resulting series of triple, quadruple and quintuple‐decker complexes, ligand oxidation leads to a decrease in the magnetic anisotropy, as predicted from theoretical calculations. Unusual paramagnetic shifts were observed in the spectra of the +2e charged quadruple and quintuple‐decker complexes, indicating that those two species are actually unexpected triplet biradicals. Magnetic measurements revealed that the series of complexes show single‐molecule magnet properties, which are controlled by the multi‐step redox induced structural changes.
Presented here is a comprehensive study of highly oxidized multiple‐decker complexes composed of TbIII and CdII ions and two to five phthalocyaninato ligands, which are stabilized by electron‐donating n‐butoxy groups. From X‐ray structural analyses, all the complexes become axially compressed upon ligand oxidation, resulting in bowl‐shaped distortions of the ligands. In addition, unusual coexistence of square antiprism and square prism geometries around metal ions was observed in +4e charged species. From paramagnetic 1H NMR studies on the resulting series of triple, quadruple and quintuple‐decker complexes, ligand oxidation leads to a decrease in the magnetic anisotropy, as predicted from theoretical calculations. Unusual paramagnetic shifts were observed in the spectra of the +2e charged quadruple and quintuple‐decker complexes, indicating that those two species are actually unexpected triplet biradicals. Magnetic measurements revealed that the series of complexes show single‐molecule magnet properties, which are controlled by the multi‐step redox induced structural changes. Stacking up: From extensive studies on highly oxidized species of phthalocyaninato‐lanthanoid‐cadmium multiple‐decker complexes, the complexes had staggered and eclipsed conformations and showed complicated changes in their magnetic anisotropies and biradical properties.
Presented here is a comprehensive study of highly oxidized multiple-decker complexes composed of TbIII and CdII ions and two to five phthalocyaninato ligands, which are stabilized by electron-donating n-butoxy groups. From X-ray structural analyses, all the complexes become axially compressed upon ligand oxidation, resulting in bowl-shaped distortions of the ligands. In addition, unusual coexistence of square antiprism and square prism geometries around metal ions was observed in +4e charged species. From paramagnetic 1 H NMR studies on the resulting series of triple, quadruple and quintuple-decker complexes, ligand oxidation leads to a decrease in the magnetic anisotropy, as predicted from theoretical calculations. Unusual paramagnetic shifts were observed in the spectra of the +2e charged quadruple and quintuple-decker complexes, indicating that those two species are actually unexpected triplet biradicals. Magnetic measurements revealed that the series of complexes show single-molecule magnet properties, which are controlled by the multi-step redox induced structural changes.Presented here is a comprehensive study of highly oxidized multiple-decker complexes composed of TbIII and CdII ions and two to five phthalocyaninato ligands, which are stabilized by electron-donating n-butoxy groups. From X-ray structural analyses, all the complexes become axially compressed upon ligand oxidation, resulting in bowl-shaped distortions of the ligands. In addition, unusual coexistence of square antiprism and square prism geometries around metal ions was observed in +4e charged species. From paramagnetic 1 H NMR studies on the resulting series of triple, quadruple and quintuple-decker complexes, ligand oxidation leads to a decrease in the magnetic anisotropy, as predicted from theoretical calculations. Unusual paramagnetic shifts were observed in the spectra of the +2e charged quadruple and quintuple-decker complexes, indicating that those two species are actually unexpected triplet biradicals. Magnetic measurements revealed that the series of complexes show single-molecule magnet properties, which are controlled by the multi-step redox induced structural changes.
Author Damjanović, Marko
Ungur, Liviu
Kitagawa, Yasutaka
Breedlove, Brian K.
Yamashita, Masahiro
Chibotaru, Liviu
Veciana, Jaume
Ajayakumar, M. R.
Katoh, Keiichi
Mas‐Torrent, Marta
Wernsdorfer, Wolfgang
Enders, Markus
Horii, Yoji
AuthorAffiliation 2 Institute of Inorganic Chemistry Heidelberg University Im Neuenheimer Feld 270 69120 Heidelberg Germany
5 Theory of Nanomaterials Group Katholieke Universiteit Leuven 3001 Leuven Belgium
9 WPI-Advanced Institute for Materials Research Tohoku University 2-1-1 Katahira Sendai 980-8577 Japan
7 Institute of Nanotechnology (INT) Karlsruhe Institute of Technology (KIT) Hermann-von-Helmholtz-Platz 1 76344 Eggenstein-Leopoldshafen Germany
8 School of Materials Science and Engineering Nankai University Tianjin 300350 P. R. China
1 Department of Chemistry Graduate School of Science Tohoku University 6-3 Aramaki-Aza-Aoba Aoba-ku Sendai, Miyagi 980-8578 Japan
6 Department of Chemistry National University of Singapore 3 Science Drive 3 117543 Singapore Singapore
4 Department of Materials Engineering Science Graduate School of Engineering Science Osaka University 1-1 Machikaneyama-cho Toyonaka, Osaka 560-8531 Japan
3 Department of Molecular Nanoscience and Organic Materials Institut de Ciencia de Material
AuthorAffiliation_xml – name: 1 Department of Chemistry Graduate School of Science Tohoku University 6-3 Aramaki-Aza-Aoba Aoba-ku Sendai, Miyagi 980-8578 Japan
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– name: 3 Department of Molecular Nanoscience and Organic Materials Institut de Ciencia de Materials de Barcelona (ICMAB-CSIC)/CIBER-BBN 08193 Bellaterra Spain
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  organization: Katholieke Universiteit Leuven
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  organization: National University of Singapore
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  givenname: Marta
  orcidid: 0000-0002-1586-005X
  surname: Mas‐Torrent
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  givenname: Wolfgang
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  surname: Wernsdorfer
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  surname: Yamashita
  fullname: Yamashita, Masahiro
  email: masahiro.yamashita.c5@tohoku.ac.jp
  organization: Tohoku University
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Issue 39
Keywords Redox, Biradical, Magnetic anisotropy, NMR, Crystal engineering
Language English
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2020 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
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Notes Dedicated to Prof. Dr. Walter Siebert
These authors contributed equally to this work.
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Snippet Presented here is a comprehensive study of highly oxidized multiple‐decker complexes composed of TbIII and CdII ions and two to five phthalocyaninato ligands,...
Presented here is a comprehensive study of highly oxidized multiple‐decker complexes composed of Tb III and Cd II ions and two to five phthalocyaninato...
Herein we present a comprehensive study of highly oxidized multiple-decker complexes composed of Tb(III) and Cd(II) ions and two to five phthalocyaninato...
Presented here is a comprehensive study of highly oxidized multiple-decker complexes composed of TbIII and CdII ions and two to five phthalocyaninato ligands,...
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StartPage 8621
SubjectTerms Anisotropy
biradical
Chemistry
Coexistence
Coordination compounds
crystal engineering
Ligands
Magnetic anisotropy
Magnetic measurement
Magnetic properties
Metal ions
NMR
Nuclear magnetic resonance
Oxidation
redox
Terbium
Title Highly Oxidized States of Phthalocyaninato Terbium(III) Multiple‐Decker Complexes Showing Structural Deformations, Biradical Properties and Decreases in Magnetic Anisotropy
URI https://onlinelibrary.wiley.com/doi/abs/10.1002%2Fchem.202001365
https://www.ncbi.nlm.nih.gov/pubmed/32428358
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https://pubmed.ncbi.nlm.nih.gov/PMC7384013
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