Strong Exchange Couplings Drastically Slow Down Magnetization Relaxation in an Air‐Stable Cobalt(II)‐Radical Single‐Molecule Magnet (SMM)

The energy barrier leading to magnetic bistability in molecular clusters is determined by the magnetic anisotropy of the cluster constituents. By incorporating a highly anisotropic four‐coordinate cobalt(II) building block into a strongly coupled fully air‐ and moisture‐stable three‐spin system, it...

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Veröffentlicht in:	Angewandte Chemie International Edition Jg. 58; H. 29; S. 9802 - 9806
Hauptverfasser:	Albold, Uta, Bamberger, Heiko, Hallmen, Philipp P., van Slageren, Joris, Sarkar, Biprajit
Format:	Journal Article
Sprache:	Englisch
Veröffentlicht:	Germany Wiley Subscription Services, Inc 15.07.2019 John Wiley and Sons Inc
Ausgabe:	International ed. in English
Schlagworte:	Anisotropy Bistability Cobalt Communication Communications Coupling (molecular) Couplings hysteresis Low temperature Magnetic anisotropy Magnetization Molecular clusters molecular magnetism Raman process Relaxation time single-molecule magnet molecular magnetism cobalt single-molecule magnet Raman process hysteresis
ISSN:	1433-7851, 1521-3773, 1521-3773
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Abstract	The energy barrier leading to magnetic bistability in molecular clusters is determined by the magnetic anisotropy of the cluster constituents. By incorporating a highly anisotropic four‐coordinate cobalt(II) building block into a strongly coupled fully air‐ and moisture‐stable three‐spin system, it proved possible to suppress under‐barrier Raman processes leading to 350‐fold increase of magnetization relaxation time and pronounced hysteresis. Relaxation times of up to 9 hours at low temperatures were found. A Co production: The energy barrier leading to magnetic bistability in molecular clusters is determined by the magnetic anisotropy of the cluster constituents. By incorporating a highly anisotropic four‐coordinate cobalt(II) building block into a strongly coupled three‐spin system, it proved possible to increase the magnetization relaxation time by a factor of 350 to almost 9 hours at low temperatures.
AbstractList	The energy barrier leading to magnetic bistability in molecular clusters is determined by the magnetic anisotropy of the cluster constituents. By incorporating a highly anisotropic four-coordinate cobalt(II) building block into a strongly coupled fully air- and moisture-stable three-spin system, it proved possible to suppress under-barrier Raman processes leading to 350-fold increase of magnetization relaxation time and pronounced hysteresis. Relaxation times of up to 9 hours at low temperatures were found.The energy barrier leading to magnetic bistability in molecular clusters is determined by the magnetic anisotropy of the cluster constituents. By incorporating a highly anisotropic four-coordinate cobalt(II) building block into a strongly coupled fully air- and moisture-stable three-spin system, it proved possible to suppress under-barrier Raman processes leading to 350-fold increase of magnetization relaxation time and pronounced hysteresis. Relaxation times of up to 9 hours at low temperatures were found. The energy barrier leading to magnetic bistability in molecular clusters is determined by the magnetic anisotropy of the cluster constituents. By incorporating a highly anisotropic four-coordinate cobalt(II) building block into a strongly coupled fully air- and moisture-stable three-spin system, it proved possible to suppress under-barrier Raman processes leading to 350-fold increase of magnetization relaxation time and pronounced hysteresis. Relaxation times of up to 9 hours at low temperatures were found. The energy barrier leading to magnetic bistability in molecular clusters is determined by the magnetic anisotropy of the cluster constituents. By incorporating a highly anisotropic four‐coordinate cobalt(II) building block into a strongly coupled fully air‐ and moisture‐stable three‐spin system, it proved possible to suppress under‐barrier Raman processes leading to 350‐fold increase of magnetization relaxation time and pronounced hysteresis. Relaxation times of up to 9 hours at low temperatures were found. A Co production: The energy barrier leading to magnetic bistability in molecular clusters is determined by the magnetic anisotropy of the cluster constituents. By incorporating a highly anisotropic four‐coordinate cobalt(II) building block into a strongly coupled three‐spin system, it proved possible to increase the magnetization relaxation time by a factor of 350 to almost 9 hours at low temperatures.
Author	Bamberger, Heiko Sarkar, Biprajit Hallmen, Philipp P. Albold, Uta van Slageren, Joris
AuthorAffiliation	1 Institut für Chemie und Biochemie Freie Universität Berlin Fabeckstrasse 34–36 14195 Berlin Germany 2 Institut für Physikalische Chemie Universität Stuttgart Pfaffenwaldring 55 70569 Stuttgart Germany
AuthorAffiliation_xml	– name: 2 Institut für Physikalische Chemie Universität Stuttgart Pfaffenwaldring 55 70569 Stuttgart Germany – name: 1 Institut für Chemie und Biochemie Freie Universität Berlin Fabeckstrasse 34–36 14195 Berlin Germany
Author_xml	– sequence: 1 givenname: Uta surname: Albold fullname: Albold, Uta organization: Freie Universität Berlin – sequence: 2 givenname: Heiko surname: Bamberger fullname: Bamberger, Heiko organization: Universität Stuttgart – sequence: 3 givenname: Philipp P. surname: Hallmen fullname: Hallmen, Philipp P. organization: Universität Stuttgart – sequence: 4 givenname: Joris orcidid: 0000-0002-0855-8960 surname: van Slageren fullname: van Slageren, Joris email: slageren@ipc.uni-stuttgart.de organization: Universität Stuttgart – sequence: 5 givenname: Biprajit surname: Sarkar fullname: Sarkar, Biprajit email: Biprajit.Sarkar@fu-berlin.de organization: Freie Universität Berlin
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Snippet	The energy barrier leading to magnetic bistability in molecular clusters is determined by the magnetic anisotropy of the cluster constituents. By incorporating...
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SubjectTerms	Anisotropy Bistability Cobalt Communication Communications Coupling (molecular) Couplings hysteresis Low temperature Magnetic anisotropy Magnetization Molecular clusters molecular magnetism Raman process Relaxation time single-molecule magnet
Title	Strong Exchange Couplings Drastically Slow Down Magnetization Relaxation in an Air‐Stable Cobalt(II)‐Radical Single‐Molecule Magnet (SMM)
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