Time‐Dependent ATR‐FTIR Spectroscopic Studies on Fatty Acid Diffusion and the Formation of Metal Soaps in Oil Paint Model Systems

The formation of metal soaps (metal complexes of saturated fatty acids) is a serious problem affecting the appearance and structural integrity of many oil paintings. Tailored model systems for aged oil paint and time‐dependent attenuated total reflection Fourier transform infrared (ATR‐FTIR) spectro...

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Vydané v:Angewandte Chemie International Edition Ročník 57; číslo 25; s. 7351 - 7354
Hlavní autori: Baij, Lambert, Hermans, Joen J., Keune, Katrien, Iedema, Piet
Médium: Journal Article
Jazyk:English
Vydavateľské údaje: Germany Wiley Subscription Services, Inc 18.06.2018
John Wiley and Sons Inc
Vydanie:International ed. in English
Predmet:
Carboxylates
Communication
Communications
Coordination compounds
Crystallization
Diffusion
Fatty acids
Fourier transforms
Infrared reflection
Infrared spectroscopy
IR spectroscopy
Metal complexes
metal soaps
Oil painting
oil paintings
Palmitic acid
Pigments
Polymer films
Polymers
Soap
Soaps
Spectroscopic analysis
Spectroscopy
Spectrum analysis
Structural integrity
Time dependence
Vegetable oils
oil paintings
IR spectroscopy
metal soaps
ISSN:1433-7851, 1521-3773, 1521-3773
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Abstract The formation of metal soaps (metal complexes of saturated fatty acids) is a serious problem affecting the appearance and structural integrity of many oil paintings. Tailored model systems for aged oil paint and time‐dependent attenuated total reflection Fourier transform infrared (ATR‐FTIR) spectroscopy were used to study the diffusion of palmitic acid and subsequent metal soap crystallization. The simultaneous presence of free saturated fatty acids and polymer‐bound metal carboxylates leads to rapid metal soap crystallization, following a complex mechanism that involves both acid and metal diffusion. Solvent flow, water, and pigments all enhance metal soap crystallization in the model systems. These results contribute to the development of paint cleaning strategies, a better understanding of oil paint degradation, and highlight the potential of time‐dependent ATR‐FTIR spectroscopy for studying dynamic processes in polymer films. The formation of metal soaps (metal complexes of saturated fatty acids) is a serious problem affecting the appearance and structural integrity of many oil paintings. Tailored model systems for aged oil paint and time‐dependent ATR‐FTIR spectroscopy were used to study the diffusion of palmitic acid and subsequent metal soap crystallization.
AbstractList The formation of metal soaps (metal complexes of saturated fatty acids) is a serious problem affecting the appearance and structural integrity of many oil paintings. Tailored model systems for aged oil paint and time-dependent attenuated total reflection Fourier transform infrared (ATR-FTIR) spectroscopy were used to study the diffusion of palmitic acid and subsequent metal soap crystallization. The simultaneous presence of free saturated fatty acids and polymer-bound metal carboxylates leads to rapid metal soap crystallization, following a complex mechanism that involves both acid and metal diffusion. Solvent flow, water, and pigments all enhance metal soap crystallization in the model systems. These results contribute to the development of paint cleaning strategies, a better understanding of oil paint degradation, and highlight the potential of time-dependent ATR-FTIR spectroscopy for studying dynamic processes in polymer films.
The formation of metal soaps (metal complexes of saturated fatty acids) is a serious problem affecting the appearance and structural integrity of many oil paintings. Tailored model systems for aged oil paint and time‐dependent attenuated total reflection Fourier transform infrared (ATR‐FTIR) spectroscopy were used to study the diffusion of palmitic acid and subsequent metal soap crystallization. The simultaneous presence of free saturated fatty acids and polymer‐bound metal carboxylates leads to rapid metal soap crystallization, following a complex mechanism that involves both acid and metal diffusion. Solvent flow, water, and pigments all enhance metal soap crystallization in the model systems. These results contribute to the development of paint cleaning strategies, a better understanding of oil paint degradation, and highlight the potential of time‐dependent ATR‐FTIR spectroscopy for studying dynamic processes in polymer films. The formation of metal soaps (metal complexes of saturated fatty acids) is a serious problem affecting the appearance and structural integrity of many oil paintings. Tailored model systems for aged oil paint and time‐dependent ATR‐FTIR spectroscopy were used to study the diffusion of palmitic acid and subsequent metal soap crystallization.
The formation of metal soaps (metal complexes of saturated fatty acids) is a serious problem affecting the appearance and structural integrity of many oil paintings. Tailored model systems for aged oil paint and time-dependent attenuated total reflection Fourier transform infrared (ATR-FTIR) spectroscopy were used to study the diffusion of palmitic acid and subsequent metal soap crystallization. The simultaneous presence of free saturated fatty acids and polymer-bound metal carboxylates leads to rapid metal soap crystallization, following a complex mechanism that involves both acid and metal diffusion. Solvent flow, water, and pigments all enhance metal soap crystallization in the model systems. These results contribute to the development of paint cleaning strategies, a better understanding of oil paint degradation, and highlight the potential of time-dependent ATR-FTIR spectroscopy for studying dynamic processes in polymer films.The formation of metal soaps (metal complexes of saturated fatty acids) is a serious problem affecting the appearance and structural integrity of many oil paintings. Tailored model systems for aged oil paint and time-dependent attenuated total reflection Fourier transform infrared (ATR-FTIR) spectroscopy were used to study the diffusion of palmitic acid and subsequent metal soap crystallization. The simultaneous presence of free saturated fatty acids and polymer-bound metal carboxylates leads to rapid metal soap crystallization, following a complex mechanism that involves both acid and metal diffusion. Solvent flow, water, and pigments all enhance metal soap crystallization in the model systems. These results contribute to the development of paint cleaning strategies, a better understanding of oil paint degradation, and highlight the potential of time-dependent ATR-FTIR spectroscopy for studying dynamic processes in polymer films.
Author Iedema, Piet
Baij, Lambert
Hermans, Joen J.
Keune, Katrien
AuthorAffiliation 1 Van't Hoff Institute for Molecular Sciences University of Amsterdam P.O. Box 94720 1090GD Amsterdam The Netherlands
2 Rijksmuseum Amsterdam, Conservation and Restoration P.O. Box 74888 1070DN Amsterdam The Netherlands
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  givenname: Joen J.
  orcidid: 0000-0002-9446-9904
  surname: Hermans
  fullname: Hermans, Joen J.
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  organization: Rijksmuseum Amsterdam, Conservation and Restoration
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Issue 25
Keywords oil paintings
IR spectroscopy
metal soaps
Language English
License Attribution-NonCommercial-NoDerivs
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2018 The Authors. Published by Wiley-VCH Verlag GmbH & Co. KGaA.
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  volume-title: Conservation of Easel Paintings
  ident: e_1_2_2_19_1
– ident: e_1_2_2_16_1
  doi: 10.1016/j.polymer.2006.04.059
– ident: e_1_2_2_9_1
– ident: e_1_2_2_1_1
  doi: 10.1023/A:1025133508109
– ident: e_1_2_2_10_1
  doi: 10.1021/acs.analchem.6b04065
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Snippet The formation of metal soaps (metal complexes of saturated fatty acids) is a serious problem affecting the appearance and structural integrity of many oil...
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StartPage 7351
SubjectTerms Carboxylates
Communication
Communications
Coordination compounds
Crystallization
Diffusion
Fatty acids
Fourier transforms
Infrared reflection
Infrared spectroscopy
IR spectroscopy
Metal complexes
metal soaps
Oil painting
oil paintings
Palmitic acid
Pigments
Polymer films
Polymers
Soap
Soaps
Spectroscopic analysis
Spectroscopy
Spectrum analysis
Structural integrity
Time dependence
Vegetable oils
Title Time‐Dependent ATR‐FTIR Spectroscopic Studies on Fatty Acid Diffusion and the Formation of Metal Soaps in Oil Paint Model Systems
URI https://onlinelibrary.wiley.com/doi/abs/10.1002%2Fanie.201712751
https://www.ncbi.nlm.nih.gov/pubmed/29411920
https://www.proquest.com/docview/2053264938
https://www.proquest.com/docview/1999200920
https://pubmed.ncbi.nlm.nih.gov/PMC6033171
Volume 57
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