New Family of Cyclopropanating Reagents: Synthesis, Reactivity, and Stability Studies of Iodomethylzinc Phenoxides

A valuable alternative to the traditional Simmons–Smith reagents is offered by the title compounds, as a result of their ease of preparation and high reactivities towards unfunctionalized olefins (see scheme).

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Bibliographic Details
Published in:Angewandte Chemie International Edition Vol. 39; no. 24; pp. 4539 - 4542
Main Authors: Charette, André B., Francoeur, Sébastien, Martel, Jonathan, Wilb, Nicole
Format: Journal Article
Language:English
Published: Weinheim WILEY-VCH Verlag GmbH 15.12.2000
WILEY‐VCH Verlag GmbH
Subjects:
carbenoids
cyclopropanations
synthetic methods
zinc
ISSN:1433-7851, 1521-3773
Online Access:Get full text
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Description
Summary:A valuable alternative to the traditional Simmons–Smith reagents is offered by the title compounds, as a result of their ease of preparation and high reactivities towards unfunctionalized olefins (see scheme).
Bibliography:ark:/67375/WNG-Q4C5BKDG-7
ArticleID:ANIE4539
istex:18E0800D3537CDB844A2B4D14C9B5408EA582241
This work was supported by the E.W.R. Steacie Fund, the National Science and Engineering Research Council (NSERC) of Canada, Merck Frosst Canada, Boehringer Ingelheim (Canada), F.C.A.R. (Québec), and the Université de Montréal. J.M. and S.F. are grateful to NSERC and F.C.A.R. respectively for postgraduate fellowships.
ISSN:1433-7851
1521-3773
DOI:10.1002/1521-3773(20001215)39:24<4539::AID-ANIE4539>3.0.CO;2-9