Multifunctional lignin-based nanocomposites and nanohybrids

Significant progress in lignins valorization and development of high-performance sustainable materials have been achieved in recent years. Reports related to lignin utilization indicate excellent prospects considering green chemistry, chemical engineering, energy, materials and polymer science, phys...

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Vydáno v:Green chemistry : an international journal and green chemistry resource : GC Ročník 23; číslo 18; s. 6698
Hlavní autoři: Lizundia, Erlantz, Sipponen, Mika H, Greca, Luiz G, Balakshin, Mikhail, Tardy, Blaise L, Rojas, Orlando J, Puglia, Debora
Médium: Journal Article
Jazyk:angličtina
Vydáno: England 20.09.2021
ISSN:1463-9262
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Abstract Significant progress in lignins valorization and development of high-performance sustainable materials have been achieved in recent years. Reports related to lignin utilization indicate excellent prospects considering green chemistry, chemical engineering, energy, materials and polymer science, physical chemistry, biochemistry, among others. To fully realize such potential, one of the most promising routes involves lignin uses in nanocomposites and nanohybrid assemblies, where synergistic interactions are highly beneficial. This review first discusses the interfacial assembly of lignins with polysaccharides, proteins and other biopolymers, for instance, in the synthesis of nanocomposites. To give a wide perspective, we consider the subject of hybridization with metal and metal oxide nanoparticles, as well as uses as precursor of carbon materials and the assembly with other biobased nanoparticles, for instance to form nanohybrids. We provide cues to understand the fundamental aspects related to lignins, their self-assembly and supramolecular organization, all of which are critical in nanocomposites and nanohybrids. We highlight the possibilities of lignin in the fields of flame retardancy, food packaging, plant protection, electroactive materials, energy storage and health sciences. The most recent outcomes are evaluated given the importance of lignin extraction, within established and emerging biorefineries. We consider the benefit of lignin compared to synthetic counterparts. Bridging the gap between fundamental and application-driven research, this account offers critical insights as far as the potential of lignin as one of the frontrunners in the uptake of bioeconomy concepts and its application in value-added products.
AbstractList Significant progress in lignins valorization and development of high-performance sustainable materials have been achieved in recent years. Reports related to lignin utilization indicate excellent prospects considering green chemistry, chemical engineering, energy, materials and polymer science, physical chemistry, biochemistry, among others. To fully realize such potential, one of the most promising routes involves lignin uses in nanocomposites and nanohybrid assemblies, where synergistic interactions are highly beneficial. This review first discusses the interfacial assembly of lignins with polysaccharides, proteins and other biopolymers, for instance, in the synthesis of nanocomposites. To give a wide perspective, we consider the subject of hybridization with metal and metal oxide nanoparticles, as well as uses as precursor of carbon materials and the assembly with other biobased nanoparticles, for instance to form nanohybrids. We provide cues to understand the fundamental aspects related to lignins, their self-assembly and supramolecular organization, all of which are critical in nanocomposites and nanohybrids. We highlight the possibilities of lignin in the fields of flame retardancy, food packaging, plant protection, electroactive materials, energy storage and health sciences. The most recent outcomes are evaluated given the importance of lignin extraction, within established and emerging biorefineries. We consider the benefit of lignin compared to synthetic counterparts. Bridging the gap between fundamental and application-driven research, this account offers critical insights as far as the potential of lignin as one of the frontrunners in the uptake of bioeconomy concepts and its application in value-added products.
Significant progress in lignins valorization and development of high-performance sustainable materials have been achieved in recent years. Reports related to lignin utilization indicate excellent prospects considering green chemistry, chemical engineering, energy, materials and polymer science, physical chemistry, biochemistry, among others. To fully realize such potential, one of the most promising routes involves lignin uses in nanocomposites and nanohybrid assemblies, where synergistic interactions are highly beneficial. This review first discusses the interfacial assembly of lignins with polysaccharides, proteins and other biopolymers, for instance, in the synthesis of nanocomposites. To give a wide perspective, we consider the subject of hybridization with metal and metal oxide nanoparticles, as well as uses as precursor of carbon materials and the assembly with other biobased nanoparticles, for instance to form nanohybrids. We provide cues to understand the fundamental aspects related to lignins, their self-assembly and supramolecular organization, all of which are critical in nanocomposites and nanohybrids. We highlight the possibilities of lignin in the fields of flame retardancy, food packaging, plant protection, electroactive materials, energy storage and health sciences. The most recent outcomes are evaluated given the importance of lignin extraction, within established and emerging biorefineries. We consider the benefit of lignin compared to synthetic counterparts. Bridging the gap between fundamental and application-driven research, this account offers critical insights as far as the potential of lignin as one of the frontrunners in the uptake of bioeconomy concepts and its application in value-added products.Significant progress in lignins valorization and development of high-performance sustainable materials have been achieved in recent years. Reports related to lignin utilization indicate excellent prospects considering green chemistry, chemical engineering, energy, materials and polymer science, physical chemistry, biochemistry, among others. To fully realize such potential, one of the most promising routes involves lignin uses in nanocomposites and nanohybrid assemblies, where synergistic interactions are highly beneficial. This review first discusses the interfacial assembly of lignins with polysaccharides, proteins and other biopolymers, for instance, in the synthesis of nanocomposites. To give a wide perspective, we consider the subject of hybridization with metal and metal oxide nanoparticles, as well as uses as precursor of carbon materials and the assembly with other biobased nanoparticles, for instance to form nanohybrids. We provide cues to understand the fundamental aspects related to lignins, their self-assembly and supramolecular organization, all of which are critical in nanocomposites and nanohybrids. We highlight the possibilities of lignin in the fields of flame retardancy, food packaging, plant protection, electroactive materials, energy storage and health sciences. The most recent outcomes are evaluated given the importance of lignin extraction, within established and emerging biorefineries. We consider the benefit of lignin compared to synthetic counterparts. Bridging the gap between fundamental and application-driven research, this account offers critical insights as far as the potential of lignin as one of the frontrunners in the uptake of bioeconomy concepts and its application in value-added products.
Author Balakshin, Mikhail
Rojas, Orlando J
Greca, Luiz G
Tardy, Blaise L
Puglia, Debora
Sipponen, Mika H
Lizundia, Erlantz
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  surname: Lizundia
  fullname: Lizundia, Erlantz
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  organization: BCMaterials, Basque Center Centre for Materials, Applications and Nanostructures UPV/EHU Science Park 48940 Leioa Spain
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  email: luiz.greca@aalto.fi, mikhail.balakshin@aalto.fi, blaise.tardy@aalto.fi, orlando.rojas@aalto.fi
  organization: Department of Bioproducts and Biosystems, School of Chemical Engineering, Aalto University P.O. Box 16300 FI-00076 Aalto Finland luiz.greca@aalto.fi mikhail.balakshin@aalto.fi blaise.tardy@aalto.fi orlando.rojas@aalto.fi
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  surname: Balakshin
  fullname: Balakshin, Mikhail
  email: luiz.greca@aalto.fi, mikhail.balakshin@aalto.fi, blaise.tardy@aalto.fi, orlando.rojas@aalto.fi
  organization: Department of Bioproducts and Biosystems, School of Chemical Engineering, Aalto University P.O. Box 16300 FI-00076 Aalto Finland luiz.greca@aalto.fi mikhail.balakshin@aalto.fi blaise.tardy@aalto.fi orlando.rojas@aalto.fi
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  orcidid: 0000-0002-7648-0376
  surname: Tardy
  fullname: Tardy, Blaise L
  email: luiz.greca@aalto.fi, mikhail.balakshin@aalto.fi, blaise.tardy@aalto.fi, orlando.rojas@aalto.fi
  organization: Department of Bioproducts and Biosystems, School of Chemical Engineering, Aalto University P.O. Box 16300 FI-00076 Aalto Finland luiz.greca@aalto.fi mikhail.balakshin@aalto.fi blaise.tardy@aalto.fi orlando.rojas@aalto.fi
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  givenname: Orlando J
  orcidid: 0000-0003-4036-4020
  surname: Rojas
  fullname: Rojas, Orlando J
  email: luiz.greca@aalto.fi, mikhail.balakshin@aalto.fi, blaise.tardy@aalto.fi, orlando.rojas@aalto.fi, orlando.rojas@ubc.ca
  organization: Bioproducts Institute, Department of Chemical and Biological Engineering, Department of Chemistry, and Department of Wood Science, University of British Columbia 2360 East Mall Vancouver BC V6T 1Z4 Canada orlando.rojas@ubc.ca
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  orcidid: 0000-0001-8515-7813
  surname: Puglia
  fullname: Puglia, Debora
  email: debora.puglia@unipg.it
  organization: Civil and Environmental Engineering Department, University of Perugia Strada di Pentima 4 05100 Terni Italy debora.puglia@unipg.it
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