Mechanistic Insights into the Cobalt-Mediated Radical Polymerization (CMRP) of Vinyl Acetate with Cobalt(III) Adducts as Initiators

Over the past few years, cobalt‐mediated radical polymerization (CMRP) has proved efficient in controlling the radical polymerization of very reactive monomers, such as vinyl acetate (VAc). However, the reason for this success and the intimate mechanism remained basically speculative. Herein, two me...

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Bibliographic Details
Published in:	Chemistry : a European journal Vol. 14; no. 13; pp. 4046 - 4059
Main Authors:	Debuigne, Antoine, Champouret, Yohan, Jérôme, Robert, Poli, Rinaldo, Detrembleur, Christophe
Format:	Journal Article
Language:	English
Published:	Weinheim WILEY-VCH Verlag 28.04.2008 WILEY‐VCH Verlag Wiley Wiley-VCH Verlag
Subjects:	Chemical Sciences Chemistry Chemistry, Multidisciplinary Chimie cobalt cobalt-mediated radical polymerization (CMRP) Coordination chemistry density functional calculations Engineering, computing & technology Ingénierie, informatique & technologie Materials science & engineering Physical Sciences Physical, chemical, mathematical & earth Sciences Physique, chimie, mathématiques & sciences de la terre polymerization radical polymerization radical reactions Science & Technology Science des matériaux & ingénierie vinyl acetate polymerization POLY(VINYL ACETATE) ACTIVATION BLOCK-COPOLYMERS FRAGMENTATION CHAIN TRANSFER radical reactions REACTIVITY cobalt ATOM VITAMIN-B12 density functional calculations DEGENERATIVE TRANSFER CHEMISTRY vinyl acetate ACRYLATES Polymerization Density functional calculations Radical reactions Vinyl acetate Cobalt
ISSN:	0947-6539, 1521-3765, 1521-3765
Online Access:	Get full text
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