Oligomers of poly(anhydride): Study of interaction in coating binder

Polyanhydrides are largely used in biomedical and pharmaceutical fields because of their biodegradability and controlled degradation. In this work, oligomers were investigated as film binders for environmental applications. To overcome the main disadvantages of polyanhydrides (low solubility in comm...

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Vydané v:	Journal of applied polymer science Ročník 125; číslo 2; s. 1592 - 1600
Hlavní autori:	Lasne-Deschamps, Anne-Cécile, Faÿ, Fabienne, Sire, Olivier, Linossier, Isabelle, Vallée-Réhel, Karine
Médium:	Journal Article
Jazyk:	English
Vydavateľské údaje:	Hoboken Wiley Subscription Services, Inc., A Wiley Company 15.07.2012 Wiley Wiley Subscription Services, Inc
Predmet:	Applied sciences Bacteriology Binders coating Degradation Diffraction Exact sciences and technology Ionization Life Sciences Materials science Melting points Microbiology and Parasitology Oligomers Organic polymers Physicochemistry of polymers Polyanhydrides Polymers Polymers with particular properties Preparation, kinetics, thermodynamics, mechanism and catalysts sebacic acid self-organization Solvents Solvent effect Viscosity Coating material coating self-organization Molecular structure oligomers polyanhydrides Condensation polymerization Crystallinity Experimental study Oligomer Anhydride polymer Deposition process Sebacic acid Structure processing relationship Solvent evaporation Aliphatic polymer Rheological properties
ISSN:	0021-8995, 1097-4628
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Abstract	Polyanhydrides are largely used in biomedical and pharmaceutical fields because of their biodegradability and controlled degradation. In this work, oligomers were investigated as film binders for environmental applications. To overcome the main disadvantages of polyanhydrides (low solubility in common solvents and high melting points), oligomers based on sebacic acid were prepared. Characterization was carried out by nuclear magnetic resonance and electrospray ionization to obtain chemical structures of the products. The formation of weak interactions, which confer cohesion between chains, allows film properties to be observed. The impact of the solvent polarity on the specific organization was investigated by a combination of focused methods: capillary viscosimetry, IR spectroscopy, polarized light microscopy, and X‐ray diffraction. © 2012 Wiley Periodicals, Inc. J Appl Polym Sci, 2012
AbstractList	Polyanhydrides are largely used in biomedical and pharmaceutical fields because of their biodegradability and controlled degradation. In this work, oligomers were investigated as film binders for environmental applications. To overcome the main disadvantages of polyanhydrides (low solubility in common solvents and high melting points), oligomers based on sebacic acid were prepared. Characterization was carried out by nuclear magnetic resonance and electrospray ionization to obtain chemical structures of the products. The formation of weak interactions, which confer cohesion between chains, allows film properties to be observed. The impact of the solvent polarity on the specific organization was investigated by a combination of focused methods: capillary viscosimetry, IR spectroscopy, polarized light microscopy, and X‐ray diffraction. © 2012 Wiley Periodicals, Inc. J Appl Polym Sci, 2012 Polyanhydrides are largely used in biomedical and pharmaceutical fields because of their biodegradability and controlled degradation. In this work, oligomers were investigated as film binders for environmental applications. To overcome the main disadvantages of polyanhydrides (low solubility in common solvents and high melting points), oligomers based on sebacic acid were prepared. Characterization was carried out by nuclear magnetic resonance and electrospray ionization to obtain chemical structures of the products. The formation of weak interactions, which confer cohesion between chains, allows film properties to be observed. The impact of the solvent polarity on the specific organization was investigated by a combination of focused methods: capillary viscosimetry, IR spectroscopy, polarized light microscopy, and X-ray diffraction. copyright 2012 Wiley Periodicals, Inc. J Appl Polym Sci, 2012 Polyanhydrides are largely used in biomedical and pharmaceutical fields because of their biodegradability and controlled degradation. In this work, oligomers were investigated as film binders for environmental applications. To overcome the main disadvantages of polyanhydrides (low solubility in common solvents and high melting points), oligomers based on sebacic acid were prepared. Characterization was carried out by nuclear magnetic resonance and electrospray ionization to obtain chemical structures of the products. The formation of weak interactions, which confer cohesion between chains, allows film properties to be observed. The impact of the solvent polarity on the specific organization was investigated by a combination of focused methods: capillary viscosimetry, IR spectroscopy, polarized light microscopy, and X-ray diffraction. © 2012 Wiley Periodicals, Inc. J Appl Polym Sci, 2012 [PUBLICATION ABSTRACT]
Author	Linossier, Isabelle Lasne-Deschamps, Anne-Cécile Faÿ, Fabienne Sire, Olivier Vallée-Réhel, Karine
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Cites_doi	10.1016/j.actbio.2009.11.023 10.1016/j.reactfunctpolym.2005.02.017 10.1021/ma00198a002 10.1002/pola.10651 10.1016/0032-3861(90)90401-J 10.1016/j.ijpharm.2006.06.009 10.1021/cr040002s 10.1002/pola.1993.080311004 10.1016/S0169-409X(02)00050-9 10.1002/marc.200900059 10.1007/BF00665987 10.1016/j.polymdegradstab.2006.08.022 10.1021/ma00077a009 10.1016/j.tet.2009.02.083 10.1016/0142-9612(83)90054-6 10.1021/ma00195a018 10.1002/pola.10958 10.1021/ma062080i 10.1016/S0032-3861(01)00379-2 10.1016/0014-3057(95)00002-X 10.1016/S0169-409X(02)00051-0 10.1016/0014-3057(94)00187-1 10.1021/ma000291w 10.1016/j.progpolymsci.2005.06.002 10.1021/ma00009a024 10.1021/cr940351u 10.1021/j100291a046 10.1007/s10856-007-3166-7 10.1002/pola.1987.080251217 10.1016/S0168-3659(02)00125-6 10.1007/978-3-540-68588-3
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Keywords	Solvent effect Viscosity Coating material coating self-organization Molecular structure oligomers polyanhydrides Condensation polymerization Crystallinity Experimental study Oligomer Anhydride polymer Deposition process Sebacic acid Structure processing relationship Solvent evaporation Aliphatic polymer Rheological properties
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References_xml	– reference: Mathiowitz, E.; Amato, C.; Dor, P.; Langer, R. Polymer 1990, 31, 547. – reference: Griffin, J.; Carbone, A.; Delgado-Rivera, R.; Meiners, S.; Uhrich, K. E. Acta Biomater 2010, 6, 1917. – reference: Shimon Ben-Shabat, E. A.; Raziel, A.; Domb, A. J. J Polym Sci Part A: Polym Chem 2003, 41, 3781. – reference: Göpferich, A.; Tessmar, J. Adv Drug Deliv Rev 2002, 54, 911. – reference: Mathiowitz, E.; Kreitz, M.; Pekarek, K. Macromolecules 1993, 26, 6749. – reference: Nagata, M.; Ioka, E. React Funct Polym 2005, 63, 163. – reference: Rosen, H. B.; Chang, J.; Wnek, G. E.; Linhardt, R. J.; Langer, R. Biomaterials 1983, 4, 131. – reference: Huang, F.; Nagvekar, D. S.; Zhou, X.; Gibson, H. W. Macromolecules 2007, 40, 3561. – reference: Tantishaiyakul, V.; Worakul, N.; Wongpoowarak, W. Int J Pharm 2006, 325, 8. – reference: Wen-Chuan, L.; Chu, I.-M. J Biomed Mater Res Part B: Appl Biomater 2008, 84, 138. – reference: Dong, A.-J.; Zhang, J.-W.; Jiang, K.; Deng, L.-D. 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Snippet	Polyanhydrides are largely used in biomedical and pharmaceutical fields because of their biodegradability and controlled degradation. In this work, oligomers...
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SubjectTerms	Applied sciences Bacteriology Binders coating Degradation Diffraction Exact sciences and technology Ionization Life Sciences Materials science Melting points Microbiology and Parasitology Oligomers Organic polymers Physicochemistry of polymers Polyanhydrides Polymers Polymers with particular properties Preparation, kinetics, thermodynamics, mechanism and catalysts sebacic acid self-organization Solvents
Title	Oligomers of poly(anhydride): Study of interaction in coating binder
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