Direct Base-Assisted C‒H Cyclonickelation of 6-Phenyl-2,2′-bipyridine

The organonickel complexes [Ni(Phbpy)X] (X = Br, OAc, CN) were obtained for the first time in a direct base-assisted arene C(sp2)–H cyclometalation reaction from the rather unreactive precursor materials NiX2 and HPhbpy (6-phenyl-2,2′-bipyridine) or from the versatile precursor [Ni(HPhbpy)Br2]2. Dif...

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Bibliographic Details
Published in:	Molecules (Basel, Switzerland) Vol. 25; no. 4; p. 997
Main Authors:	Vogt, Nicolas, Sivchik, Vasily, Sandleben, Aaron, Hörner, Gerald, Klein, Axel
Format:	Journal Article
Language:	English
Published:	Switzerland MDPI AG 24.02.2020 MDPI
Subjects:	base-assisted Catalysis Cations, Divalent Chemistry Techniques, Synthetic Coordination Complexes - chemical synthesis Cycloaddition Reaction cyclometalation cyclonickelation c–h activation Decomposition Experiments Humans Ligands Models, Chemical Nickel Nickel - chemistry organonickel Oxidation-Reduction Pyridines - chemistry Stereoisomerism organonickel cyclometalation C–H activation base-assisted cyclonickelation
ISSN:	1420-3049, 1420-3049
Online Access:	Get full text
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