Compilation of Henry's law constants (version 5.0.0) for water as solvent

Many atmospheric chemicals occur in the gas phase as well as in liquid cloud droplets and aerosol particles. Therefore, it is necessary to understand their distribution between the phases. According to Henry’s law, the equilibrium ratio between the abundances in the gas phase and in the aqueous phas...

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Bibliographic Details
Published in:Atmospheric chemistry and physics Vol. 23; no. 19; pp. 10901 - 12440
Main Author: Sander, Rolf
Format: Journal Article
Language:English
Published: Katlenburg-Lindau Copernicus GmbH 06.10.2023
Copernicus Publications
Subjects:
Aerosol particles
Aerosols
Chemistry
Cloud droplets
Constants
Environmental chemistry
Gases
Geochemistry
Henrys law
Trace gases
Vapor phases
ISSN:1680-7324, 1680-7316, 1680-7324
Online Access:Get full text
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Summary:Many atmospheric chemicals occur in the gas phase as well as in liquid cloud droplets and aerosol particles. Therefore, it is necessary to understand their distribution between the phases. According to Henry’s law, the equilibrium ratio between the abundances in the gas phase and in the aqueous phase is constant for a dilute solution. Henry’s law constants of trace gases of potential importance in environmental chemistry have been collected and converted into a uniform format. The compilation contains 46 434 values of Henry’s law constants for 10 173 species, collected from 995 references. It is also available on the internet at https://www.henrys-law.org (last access: October 2023). This article is a living review that supersedes the now obsolete publication by Sander (2015).
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ISSN:1680-7324
1680-7316
1680-7324
DOI:10.5194/acp-23-10901-2023