Cellulose Amorphization by Swelling in Ionic Liquid/Water Mixtures: A Combined Macroscopic and Second-Harmonic Microscopy Study
Amorphization of cellulose by swelling in ionic liquid (IL)/water mixtures at room temperature is a suitable alternative to the dissolution–precipitation pretreatment known to facilitate enzymatic digestion. When soaking microcrystalline cellulose in the IL 1‐ethyl‐3‐methylimidazolium acetate contai...
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| Vydáno v: | ChemSusChem Ročník 8; číslo 1; s. 82 - 86 |
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| Jazyk: | angličtina |
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Weinheim
WILEY-VCH Verlag
01.01.2015
WILEY‐VCH Verlag Wiley Subscription Services, Inc |
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| ISSN: | 1864-5631, 1864-564X, 1864-564X |
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| Abstract | Amorphization of cellulose by swelling in ionic liquid (IL)/water mixtures at room temperature is a suitable alternative to the dissolution–precipitation pretreatment known to facilitate enzymatic digestion. When soaking microcrystalline cellulose in the IL 1‐ethyl‐3‐methylimidazolium acetate containing 20 wt % water, the crystallinity of the cellulose sample is strongly reduced. As less than 4 % of the cellulose dissolves in this mixture, this swelling method makes a precipitation step and subsequent energy‐intensive IL purification redundant. Second‐harmonic generation (SHG) microscopy is used as a structure‐sensitive technique for in situ monitoring of the changes in cellulose crystallinity. Combined optical and SHG observations confirm that in the pure IL complete dissolution takes place, while swelling without dissolution in the optimal IL/water mixture yields a solid cellulose with a significantly reduced crystallinity in a single step.
Soaking as the solution: Soaking of cellulose ionic liquid/water mixtures results in a reduced crystallinity (amorphization). The evolution of cellulose crystallinity is studied in situ by second‐harmonic generation (SHG) microscopy. These results show the potential of soaking in ionic liquid/water mixtures as an alternative cellulose pretreatment method, with the main advantage of avoiding energy‐intensive IL purification, as required in dissolution–precipitation. |
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| AbstractList | Amorphization of cellulose by swelling in ionic liquid (IL)/water mixtures at room temperature is a suitable alternative to the dissolution-precipitation pretreatment known to facilitate enzymatic digestion. When soaking microcrystalline cellulose in the IL 1-ethyl-3-methylimidazolium acetate containing 20wt% water, the crystallinity of the cellulose sample is strongly reduced. As less than 4% of the cellulose dissolves in this mixture, this swelling method makes a precipitation step and subsequent energy-intensive IL purification redundant. Second-harmonic generation (SHG) microscopy is used as a structure-sensitive technique for insitu monitoring of the changes in cellulose crystallinity. Combined optical and SHG observations confirm that in the pure IL complete dissolution takes place, while swelling without dissolution in the optimal IL/water mixture yields a solid cellulose with a significantly reduced crystallinity in a single step. Amorphization of cellulose by swelling in ionic liquid (IL)/water mixtures at room temperature is a suitable alternative to the dissolution-precipitation pretreatment known to facilitate enzymatic digestion. When soaking microcrystalline cellulose in the IL 1-ethyl-3-methylimidazolium acetate containing 20 wt % water, the crystallinity of the cellulose sample is strongly reduced. As less than 4 % of the cellulose dissolves in this mixture, this swelling method makes a precipitation step and subsequent energy-intensive IL purification redundant. Second-harmonic generation (SHG) microscopy is used as a structure-sensitive technique for in situ monitoring of the changes in cellulose crystallinity. Combined optical and SHG observations confirm that in the pure IL complete dissolution takes place, while swelling without dissolution in the optimal IL/water mixture yields a solid cellulose with a significantly reduced crystallinity in a single step. Amorphization of cellulose by swelling in ionic liquid (IL)/water mixtures at room temperature is a suitable alternative to the dissolution–precipitation pretreatment known to facilitate enzymatic digestion. When soaking microcrystalline cellulose in the IL 1‐ethyl‐3‐methylimidazolium acetate containing 20 wt % water, the crystallinity of the cellulose sample is strongly reduced. As less than 4 % of the cellulose dissolves in this mixture, this swelling method makes a precipitation step and subsequent energy‐intensive IL purification redundant. Second‐harmonic generation (SHG) microscopy is used as a structure‐sensitive technique for in situ monitoring of the changes in cellulose crystallinity. Combined optical and SHG observations confirm that in the pure IL complete dissolution takes place, while swelling without dissolution in the optimal IL/water mixture yields a solid cellulose with a significantly reduced crystallinity in a single step. Soaking as the solution: Soaking of cellulose ionic liquid/water mixtures results in a reduced crystallinity (amorphization). The evolution of cellulose crystallinity is studied in situ by second‐harmonic generation (SHG) microscopy. These results show the potential of soaking in ionic liquid/water mixtures as an alternative cellulose pretreatment method, with the main advantage of avoiding energy‐intensive IL purification, as required in dissolution–precipitation. Amorphization of cellulose by swelling in ionic liquid (IL)/water mixtures at room temperature is a suitable alternative to the dissolution-precipitation pretreatment known to facilitate enzymatic digestion. When soaking microcrystalline cellulose in the IL 1-ethyl-3-methylimidazolium acetate containing 20 wt % water, the crystallinity of the cellulose sample is strongly reduced. As less than 4 % of the cellulose dissolves in this mixture, this swelling method makes a precipitation step and subsequent energy-intensive IL purification redundant. Second-harmonic generation (SHG) microscopy is used as a structure-sensitive technique for in situ monitoring of the changes in cellulose crystallinity. Combined optical and SHG observations confirm that in the pure IL complete dissolution takes place, while swelling without dissolution in the optimal IL/water mixture yields a solid cellulose with a significantly reduced crystallinity in a single step.Amorphization of cellulose by swelling in ionic liquid (IL)/water mixtures at room temperature is a suitable alternative to the dissolution-precipitation pretreatment known to facilitate enzymatic digestion. When soaking microcrystalline cellulose in the IL 1-ethyl-3-methylimidazolium acetate containing 20 wt % water, the crystallinity of the cellulose sample is strongly reduced. As less than 4 % of the cellulose dissolves in this mixture, this swelling method makes a precipitation step and subsequent energy-intensive IL purification redundant. Second-harmonic generation (SHG) microscopy is used as a structure-sensitive technique for in situ monitoring of the changes in cellulose crystallinity. Combined optical and SHG observations confirm that in the pure IL complete dissolution takes place, while swelling without dissolution in the optimal IL/water mixture yields a solid cellulose with a significantly reduced crystallinity in a single step. Amorphization of cellulose by swelling in ionic liquid (IL)/water mixtures at room temperature is a suitable alternative to the dissolution-precipitation pretreatment known to facilitate enzymatic digestion. When soaking microcrystalline cellulose in the IL 1-ethyl-3-methylimidazolium acetate containing 20wt% water, the crystallinity of the cellulose sample is strongly reduced. As less than 4% of the cellulose dissolves in this mixture, this swelling method makes a precipitation step and subsequent energy-intensive IL purification redundant. Second-harmonic generation (SHG) microscopy is used as a structure-sensitive technique for insitu monitoring of the changes in cellulose crystallinity. Combined optical and SHG observations confirm that in the pure IL complete dissolution takes place, while swelling without dissolution in the optimal IL/water mixture yields a solid cellulose with a significantly reduced crystallinity in a single step. Soaking as the solution: Soaking of cellulose ionic liquid/water mixtures results in a reduced crystallinity (amorphization). The evolution of cellulose crystallinity is studied in situ by second-harmonic generation (SHG) microscopy. These results show the potential of soaking in ionic liquid/water mixtures as an alternative cellulose pretreatment method, with the main advantage of avoiding energy-intensive IL purification, as required in dissolution-precipitation. |
| Author | Paesen, Rik De Vos, Dirk E. Glas, Daan Depuydt, Daphne Ameloot, Rob Ameloot, Marcel Binnemans, Koen |
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| CitedBy_id | crossref_primary_10_1002_cctc_201500482 crossref_primary_10_1016_j_molliq_2019_111793 crossref_primary_10_1016_j_addr_2015_12_014 crossref_primary_10_1557_s43578_022_00797_7 crossref_primary_10_3390_polym13244313 crossref_primary_10_1080_15440478_2023_2286323 crossref_primary_10_1016_j_molliq_2024_126315 crossref_primary_10_1039_D0SE01802C crossref_primary_10_1007_s10570_016_0908_z crossref_primary_10_3390_foods12051100 |
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| Keywords | biomass sustainable chemistry ionic liquids cellulose spectroscopy |
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| SubjectTerms | biomass Cellulose Cellulose - chemistry Imidazoles - chemistry ionic liquids Ionic Liquids - chemistry Ions Microscopy spectroscopy sustainable chemistry Water - chemistry |
| Title | Cellulose Amorphization by Swelling in Ionic Liquid/Water Mixtures: A Combined Macroscopic and Second-Harmonic Microscopy Study |
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