Double Single-Crystal-to-Single-Crystal Transformation and Small-Molecule Activation in Rhodium NHC Complexes

Three gases, one crystal: Rhodium NHC complexes undergo back‐to‐back single‐crystal‐to‐single‐crystal transformations by selective nonreversible ligand exchange reactions (see picture). Slow diffusion of O2 converts a dinitrogen complex into a dioxygen complex, and CO subsequently replaces O2....

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Veröffentlicht in:Angewandte Chemie International Edition Jg. 50; H. 35; S. 8100 - 8104
Hauptverfasser: Zenkina, Olena V., Keske, Eric C., Wang, Ruiyao, Crudden, Cathleen M.
Format: Journal Article
Sprache:Englisch
Veröffentlicht: Weinheim WILEY-VCH Verlag 22.08.2011
WILEY‐VCH Verlag
Wiley Subscription Services, Inc
Ausgabe:International ed. in English
Schlagworte:
hydrides
N-heterocyclic carbenes
Rhodium
single-crystal reactions
X-ray diffraction
ISSN:1433-7851, 1521-3773, 1521-3773
Online-Zugang:Volltext
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Zusammenfassung:Three gases, one crystal: Rhodium NHC complexes undergo back‐to‐back single‐crystal‐to‐single‐crystal transformations by selective nonreversible ligand exchange reactions (see picture). Slow diffusion of O2 converts a dinitrogen complex into a dioxygen complex, and CO subsequently replaces O2.
Bibliographie:ark:/67375/WNG-VJ69K53W-2
The National Sciences and Engineering Research Council of Canada (NSERC) is gratefully acknowledged for support of this research, and Johnson Matthey is acknowledged for a gift of [{Rh(C2H4)2Cl}2]. NHC=N-heterocyclic carbene.
National Sciences and Engineering Research Council of Canada (NSERC)
ArticleID:ANIE201103316
istex:226BB9029FC69C5566A8B32B450CFC4E9E69B428
2
4
NHC=N‐heterocyclic carbene.
H
The National Sciences and Engineering Research Council of Canada (NSERC) is gratefully acknowledged for support of this research, and Johnson Matthey is acknowledged for a gift of [{Rh(C
)
Cl
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ISSN:1433-7851
1521-3773
1521-3773
DOI:10.1002/anie.201103316