Double Single-Crystal-to-Single-Crystal Transformation and Small-Molecule Activation in Rhodium NHC Complexes

Three gases, one crystal: Rhodium NHC complexes undergo back‐to‐back single‐crystal‐to‐single‐crystal transformations by selective nonreversible ligand exchange reactions (see picture). Slow diffusion of O2 converts a dinitrogen complex into a dioxygen complex, and CO subsequently replaces O2....

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Bibliographic Details

Published in:	Angewandte Chemie International Edition Vol. 50; no. 35; pp. 8100 - 8104
Main Authors:	Zenkina, Olena V., Keske, Eric C., Wang, Ruiyao, Crudden, Cathleen M.
Format:	Journal Article
Language:	English
Published:	Weinheim WILEY-VCH Verlag 22.08.2011 WILEY‐VCH Verlag Wiley Subscription Services, Inc
Edition:	International ed. in English
Subjects:	hydrides N-heterocyclic carbenes Rhodium single-crystal reactions X-ray diffraction
ISSN:	1433-7851, 1521-3773, 1521-3773
Online Access:	Get full text
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