Double Single-Crystal-to-Single-Crystal Transformation and Small-Molecule Activation in Rhodium NHC Complexes

Three gases, one crystal: Rhodium NHC complexes undergo back‐to‐back single‐crystal‐to‐single‐crystal transformations by selective nonreversible ligand exchange reactions (see picture). Slow diffusion of O2 converts a dinitrogen complex into a dioxygen complex, and CO subsequently replaces O2....

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Vydáno v:Angewandte Chemie International Edition Ročník 50; číslo 35; s. 8100 - 8104
Hlavní autoři: Zenkina, Olena V., Keske, Eric C., Wang, Ruiyao, Crudden, Cathleen M.
Médium: Journal Article
Jazyk:angličtina
Vydáno: Weinheim WILEY-VCH Verlag 22.08.2011
WILEY‐VCH Verlag
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Vydání:International ed. in English
Témata:
hydrides
N-heterocyclic carbenes
Rhodium
single-crystal reactions
X-ray diffraction
ISSN:1433-7851, 1521-3773, 1521-3773
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Shrnutí:Three gases, one crystal: Rhodium NHC complexes undergo back‐to‐back single‐crystal‐to‐single‐crystal transformations by selective nonreversible ligand exchange reactions (see picture). Slow diffusion of O2 converts a dinitrogen complex into a dioxygen complex, and CO subsequently replaces O2.
Bibliografie:ark:/67375/WNG-VJ69K53W-2
The National Sciences and Engineering Research Council of Canada (NSERC) is gratefully acknowledged for support of this research, and Johnson Matthey is acknowledged for a gift of [{Rh(C2H4)2Cl}2]. NHC=N-heterocyclic carbene.
National Sciences and Engineering Research Council of Canada (NSERC)
ArticleID:ANIE201103316
istex:226BB9029FC69C5566A8B32B450CFC4E9E69B428
2
4
NHC=N‐heterocyclic carbene.
H
The National Sciences and Engineering Research Council of Canada (NSERC) is gratefully acknowledged for support of this research, and Johnson Matthey is acknowledged for a gift of [{Rh(C
)
Cl
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ISSN:1433-7851
1521-3773
1521-3773
DOI:10.1002/anie.201103316