Ethanol as a Hydrogenating Agent: Palladium‐Catalyzed Stereoselective Hydrogenation of Ynamides To Give Enamides

Ethanol is shown to act as a hydrogenating agent for ynamides under palladium catalysis. This behavior is different from the normally expected reaction of ethanol addition to alkynes. The reaction shows stereoselectivity for E enamides, which is in contrast to reports using other hydrogenating sourc...

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Veröffentlicht in:	Angewandte Chemie International Edition Jg. 56; H. 24; S. 6984 - 6988
Hauptverfasser:	Reddy, Alla Siva, Swamy, K. C. Kumara
Format:	Journal Article
Sprache:	Englisch
Veröffentlicht:	WEINHEIM Wiley 06.06.2017 Wiley Subscription Services, Inc
Ausgabe:	International ed. in English
Schlagworte:	Alkynes Ammonium Catalysis Chemistry Chemistry, Multidisciplinary Deuterium enamides Ethanol Hydrogenation Palladium Physical Sciences Science & Technology Stereoselectivity ynamides FUNCTIONALIZED YNAMIDES HYDROGENOLYSIS GOLD CATALYSIS enamides ACIDS REACTIVITY ethanol hydrogenation SELECTIVE SEMIHYDROGENATION REDUCTION palladium ynamides 2+2+2 CYCLOADDITIONS TANDEM-CYCLIZATION ALKYNE SEMIHYDROGENATION
ISSN:	1433-7851, 1521-3773, 1521-3773
Online-Zugang:	Volltext
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