Cyclopentanone Derivatives from 5‐Hydroxymethylfurfural via 1‐Hydroxyhexane‐2,5‐dione as Intermediate

An efficient strategy for the conversion of biomass derived 5‐hydroxymethylfurfural (HMF) into 2‐hydroxy‐3‐methylcyclopent‐2‐enone (MCP) by an intramolecular aldol condensation of 1‐hydroxyhexane‐2,5‐dione (HHD) has been developed. Further transformations of MCP towards the diol, enol acetate, levul...

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Veröffentlicht in:ChemSusChem Jg. 11; H. 2; S. 356 - 359
Hauptverfasser: Wozniak, Bartosz, Spannenberg, Anke, Li, Yuehui, Hinze, Sandra, de Vries, Johannes G.
Format: Journal Article
Sprache:Englisch
Veröffentlicht: Germany Wiley Subscription Services, Inc 23.01.2018
Schlagworte:
Aldehydes
biomass
cycloketones
Heterocyclic compounds
homogeneous catalysis
Hydroxymethylfurfural
Levulinic acid
platform chemicals
renewable resources
cycloketones
biomass
renewable resources
homogeneous catalysis
platform chemicals
ISSN:1864-5631, 1864-564X, 1864-564X
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Zusammenfassung:An efficient strategy for the conversion of biomass derived 5‐hydroxymethylfurfural (HMF) into 2‐hydroxy‐3‐methylcyclopent‐2‐enone (MCP) by an intramolecular aldol condensation of 1‐hydroxyhexane‐2,5‐dione (HHD) has been developed. Further transformations of MCP towards the diol, enol acetate, levulinic acid and N‐heterocyclic compounds are also reported. Dione and dusted: An efficient strategy for the conversion of biomass‐derived 5‐hydroxymethylfurfural into 2‐hydroxy‐3‐methylcyclopent‐2‐enone (MCP) by an intramolecular aldol condensation of 1‐hydroxyhexane‐2,5‐dione has been developed. Further transformations of MCP into the diol, enol acetate, levulinic acid, and N‐heterocyclic compounds are also reported.
Bibliographie:ObjectType-Article-1
SourceType-Scholarly Journals-1
ObjectType-Feature-2
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ISSN:1864-5631
1864-564X
1864-564X
DOI:10.1002/cssc.201702100