Faceted polymersomes: a sphere-to-polyhedron shape transformation
The creation of “soft” deformable hollow polymeric nanoparticles with complex non-spherical shapes via block copolymer self-assembly remains a challenge. In this work, we show that a perylene-bearing block copolymer can self-assemble into polymeric membrane sacs (polymersomes) that not only possess...
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| Vydáno v: | Chemical science (Cambridge) Ročník 10; číslo 9; s. 2725 - 2731 |
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| Médium: | Journal Article |
| Jazyk: | angličtina |
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England
Royal Society of Chemistry
07.03.2019
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| ISSN: | 2041-6520, 2041-6539 |
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| Abstract | The creation of “soft” deformable hollow polymeric nanoparticles with complex non-spherical shapes
via
block copolymer self-assembly remains a challenge. In this work, we show that a perylene-bearing block copolymer can self-assemble into polymeric membrane sacs (polymersomes) that not only possess uncommonly faceted polyhedral shapes but are also intrinsically fluorescent. Here, we further reveal for the first time an experimental visualization of the entire polymersome faceting process. We uncover how our polymersomes facet through a sphere-to-polyhedron shape transformation pathway that is driven by perylene aggregation confined within a topologically spherical polymersome shell. Finally, we illustrate the importance in understanding this shape transformation process by demonstrating our ability to controllably isolate different intermediate polymersome morphologies. The findings presented herein should provide opportunities for those who utilize non-spherical polymersomes for drug delivery, nanoreactor or templating applications, and those who are interested in the fundamental aspects of polymersome self-assembly. |
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| AbstractList | The creation of "soft" deformable hollow polymeric nanoparticles with complex non-spherical shapes via block copolymer self-assembly remains a challenge. In this work, we show that a perylene-bearing block copolymer can self-assemble into polymeric membrane sacs (polymersomes) that not only possess uncommonly faceted polyhedral shapes but are also intrinsically fluorescent. Here, we further reveal for the first time an experimental visualization of the entire polymersome faceting process. We uncover how our polymersomes facet through a sphere-to-polyhedron shape transformation pathway that is driven by perylene aggregation confined within a topologically spherical polymersome shell. Finally, we illustrate the importance in understanding this shape transformation process by demonstrating our ability to controllably isolate different intermediate polymersome morphologies. The findings presented herein should provide opportunities for those who utilize non-spherical polymersomes for drug delivery, nanoreactor or templating applications, and those who are interested in the fundamental aspects of polymersome self-assembly.The creation of "soft" deformable hollow polymeric nanoparticles with complex non-spherical shapes via block copolymer self-assembly remains a challenge. In this work, we show that a perylene-bearing block copolymer can self-assemble into polymeric membrane sacs (polymersomes) that not only possess uncommonly faceted polyhedral shapes but are also intrinsically fluorescent. Here, we further reveal for the first time an experimental visualization of the entire polymersome faceting process. We uncover how our polymersomes facet through a sphere-to-polyhedron shape transformation pathway that is driven by perylene aggregation confined within a topologically spherical polymersome shell. Finally, we illustrate the importance in understanding this shape transformation process by demonstrating our ability to controllably isolate different intermediate polymersome morphologies. The findings presented herein should provide opportunities for those who utilize non-spherical polymersomes for drug delivery, nanoreactor or templating applications, and those who are interested in the fundamental aspects of polymersome self-assembly. The creation of "soft" deformable hollow polymeric nanoparticles with complex non-spherical shapes block copolymer self-assembly remains a challenge. In this work, we show that a perylene-bearing block copolymer can self-assemble into polymeric membrane sacs (polymersomes) that not only possess uncommonly faceted polyhedral shapes but are also intrinsically fluorescent. Here, we further reveal for the first time an experimental visualization of the entire polymersome faceting process. We uncover how our polymersomes facet through a sphere-to-polyhedron shape transformation pathway that is driven by perylene aggregation confined within a topologically spherical polymersome shell. Finally, we illustrate the importance in understanding this shape transformation process by demonstrating our ability to controllably isolate different intermediate polymersome morphologies. The findings presented herein should provide opportunities for those who utilize non-spherical polymersomes for drug delivery, nanoreactor or templating applications, and those who are interested in the fundamental aspects of polymersome self-assembly. The creation of “soft” deformable hollow polymeric nanoparticles with complex non-spherical shapes via block copolymer self-assembly remains a challenge. In this work, we show that a perylene-bearing block copolymer can self-assemble into polymeric membrane sacs (polymersomes) that not only possess uncommonly faceted polyhedral shapes but are also intrinsically fluorescent. Here, we further reveal for the first time an experimental visualization of the entire polymersome faceting process. We uncover how our polymersomes facet through a sphere-to-polyhedron shape transformation pathway that is driven by perylene aggregation confined within a topologically spherical polymersome shell. Finally, we illustrate the importance in understanding this shape transformation process by demonstrating our ability to controllably isolate different intermediate polymersome morphologies. The findings presented herein should provide opportunities for those who utilize non-spherical polymersomes for drug delivery, nanoreactor or templating applications, and those who are interested in the fundamental aspects of polymersome self-assembly. We uncover how our polymersomes facet through a sphere-to-polyhedron shape transformation pathway that is driven by perylene aggregation confined within a topologically spherical polymersome shell. The creation of “soft” deformable hollow polymeric nanoparticles with complex non-spherical shapes via block copolymer self-assembly remains a challenge. In this work, we show that a perylene-bearing block copolymer can self-assemble into polymeric membrane sacs (polymersomes) that not only possess uncommonly faceted polyhedral shapes but are also intrinsically fluorescent. Here, we further reveal for the first time an experimental visualization of the entire polymersome faceting process. We uncover how our polymersomes facet through a sphere-to-polyhedron shape transformation pathway that is driven by perylene aggregation confined within a topologically spherical polymersome shell. Finally, we illustrate the importance in understanding this shape transformation process by demonstrating our ability to controllably isolate different intermediate polymersome morphologies. The findings presented herein should provide opportunities for those who utilize non-spherical polymersomes for drug delivery, nanoreactor or templating applications, and those who are interested in the fundamental aspects of polymersome self-assembly. The creation of “soft” deformable hollow polymeric nanoparticles with complex non-spherical shapes via block copolymer self-assembly remains a challenge. In this work, we show that a perylene-bearing block copolymer can self-assemble into polymeric membrane sacs (polymersomes) that not only possess uncommonly faceted polyhedral shapes but are also intrinsically fluorescent. Here, we further reveal for the first time an experimental visualization of the entire polymersome faceting process. We uncover how our polymersomes facet through a sphere-to-polyhedron shape transformation pathway that is driven by perylene aggregation confined within a topologically spherical polymersome shell. Finally, we illustrate the importance in understanding this shape transformation process by demonstrating our ability to controllably isolate different intermediate polymersome morphologies. The findings presented herein should provide opportunities for those who utilize non-spherical polymersomes for drug delivery, nanoreactor or templating applications, and those who are interested in the fundamental aspects of polymersome self-assembly. |
| Author | Parton, Robert G. Martin, Adam D. Wong, Chin Ken Floetenmeyer, Matthias Stenzel, Martina H. Thordarson, Pall |
| AuthorAffiliation | e Institute of Molecular Bioscience , The University of Queensland , St. Lucia , Brisbane , QLD 4072 , Australia c Centre for Advanced Macromolecular Design (CAMD) , School of Chemistry , University of New South Wales , Sydney , NSW 2052 , Australia d Centre for Microscopy and Microanalysis , The University of Queensland , St. Lucia , Brisbane , QLD 4072 , Australia b ARC Centre of Excellence in Convergent Bio-Nano Science and Technology , Australia a School of Chemistry , University of New South Wales , NSW 2052 , Australia . Email: m.stenzel@unsw.edu.au ; Email: p.thordarson@unsw.edu.au |
| AuthorAffiliation_xml | – name: a School of Chemistry , University of New South Wales , NSW 2052 , Australia . Email: m.stenzel@unsw.edu.au ; Email: p.thordarson@unsw.edu.au – name: c Centre for Advanced Macromolecular Design (CAMD) , School of Chemistry , University of New South Wales , Sydney , NSW 2052 , Australia – name: d Centre for Microscopy and Microanalysis , The University of Queensland , St. Lucia , Brisbane , QLD 4072 , Australia – name: e Institute of Molecular Bioscience , The University of Queensland , St. Lucia , Brisbane , QLD 4072 , Australia – name: b ARC Centre of Excellence in Convergent Bio-Nano Science and Technology , Australia |
| Author_xml | – sequence: 1 givenname: Chin Ken orcidid: 0000-0003-3040-4412 surname: Wong fullname: Wong, Chin Ken organization: School of Chemistry, University of New South Wales, Australia, ARC Centre of Excellence in Convergent Bio-Nano Science and Technology, Australia – sequence: 2 givenname: Adam D. orcidid: 0000-0002-5445-0299 surname: Martin fullname: Martin, Adam D. organization: School of Chemistry, University of New South Wales, Australia, ARC Centre of Excellence in Convergent Bio-Nano Science and Technology, Australia – sequence: 3 givenname: Matthias surname: Floetenmeyer fullname: Floetenmeyer, Matthias organization: Centre for Microscopy and Microanalysis, The University of Queensland, Brisbane, Australia – sequence: 4 givenname: Robert G. orcidid: 0000-0002-7494-5248 surname: Parton fullname: Parton, Robert G. organization: ARC Centre of Excellence in Convergent Bio-Nano Science and Technology, Australia, Centre for Microscopy and Microanalysis, The University of Queensland, Brisbane – sequence: 5 givenname: Martina H. orcidid: 0000-0002-6433-4419 surname: Stenzel fullname: Stenzel, Martina H. organization: School of Chemistry, University of New South Wales, Australia, Centre for Advanced Macromolecular Design (CAMD), School of Chemistry – sequence: 6 givenname: Pall orcidid: 0000-0002-1200-8814 surname: Thordarson fullname: Thordarson, Pall organization: School of Chemistry, University of New South Wales, Australia, ARC Centre of Excellence in Convergent Bio-Nano Science and Technology, Australia |
| BackLink | https://www.ncbi.nlm.nih.gov/pubmed/30996990$$D View this record in MEDLINE/PubMed |
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| CitedBy_id | crossref_primary_10_1002_pi_6203 crossref_primary_10_1016_j_chempr_2019_12_028 crossref_primary_10_3390_ma14247690 crossref_primary_10_1007_s41664_024_00336_9 crossref_primary_10_1039_D4SC08283D crossref_primary_10_1039_D3SC01707A crossref_primary_10_1002_anie_202413627 crossref_primary_10_1016_j_polymer_2024_127940 crossref_primary_10_1002_smll_202501838 crossref_primary_10_1002_ange_202413627 crossref_primary_10_1002_anie_202109637 crossref_primary_10_1002_ange_202109637 crossref_primary_10_1002_mabi_202400540 crossref_primary_10_1021_jacs_9b12925 crossref_primary_10_1002_adhm_202000261 crossref_primary_10_1016_j_jcis_2023_01_097 crossref_primary_10_1039_D2NR03874A crossref_primary_10_1038_s41467_023_39305_8 crossref_primary_10_1038_s41467_024_47312_6 crossref_primary_10_1016_j_polymer_2020_122914 |
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| Snippet | The creation of “soft” deformable hollow polymeric nanoparticles with complex non-spherical shapes
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block copolymer self-assembly remains a challenge. In... The creation of "soft" deformable hollow polymeric nanoparticles with complex non-spherical shapes block copolymer self-assembly remains a challenge. In this... The creation of “soft” deformable hollow polymeric nanoparticles with complex non-spherical shapes via block copolymer self-assembly remains a challenge. In... The creation of "soft" deformable hollow polymeric nanoparticles with complex non-spherical shapes via block copolymer self-assembly remains a challenge. In... We uncover how our polymersomes facet through a sphere-to-polyhedron shape transformation pathway that is driven by perylene aggregation confined within a... |
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| SubjectTerms | Block copolymers Chemistry Deformation Drug delivery systems Fluorescence Formability Mathematical morphology Nanoparticles Polyhedra Self-assembly Spherical shells Transformations |
| Title | Faceted polymersomes: a sphere-to-polyhedron shape transformation |
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