Two-dimensional conjugated metal-organic frameworks (2D c -MOFs): chemistry and function for MOFtronics

The 21st century has seen a reinvention of how modern electronics impact our daily lives; silicon-electronics and organic electronics are currently at the core of modern electronics. Recent advances have demonstrated that conductive metal-organic frameworks (MOFs), as another unique class of electro...

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Veröffentlicht in:Chemical Society reviews Jg. 50; H. 4; S. 2764
Hauptverfasser: Wang, Mingchao, Dong, Renhao, Feng, Xinliang
Format: Journal Article
Sprache:Englisch
Veröffentlicht: England 01.03.2021
ISSN:1460-4744, 1460-4744
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Abstract The 21st century has seen a reinvention of how modern electronics impact our daily lives; silicon-electronics and organic electronics are currently at the core of modern electronics. Recent advances have demonstrated that conductive metal-organic frameworks (MOFs), as another unique class of electronic materials, are emerging to provide additional possibility for multifunctional electronic devices that brings us "MOFtronics". Typically, two-dimensional conjugated MOFs (2D c-MOFs) are a novel class of layer-stacked MOFs with in-plane extended π-conjugation that exhibit unique properties such as intrinsic porosity, crystallinity, stability, and electrical conductivity as well as tailorable band gaps. Benefiting from their unique features and high conductivity, 2D c-MOFs have displayed great potential for multiple high-performance (opto)electronic, magnetic, and energy devices. In this review article, we introduce the chemical and synthetic methodologies of 2D c-MOFs, intrinsic influences on their electronic structures and charge transport properties, as well as multifunctional applications of this class of materials for MOFtronics and potential power sources for MOFtronics. We highlight the benefits and limitations of thus-far developed 2D c-MOFs from synthesis to function and offer our perspectives in regard to the challenges to be addressed.
AbstractList The 21st century has seen a reinvention of how modern electronics impact our daily lives; silicon-electronics and organic electronics are currently at the core of modern electronics. Recent advances have demonstrated that conductive metal-organic frameworks (MOFs), as another unique class of electronic materials, are emerging to provide additional possibility for multifunctional electronic devices that brings us "MOFtronics". Typically, two-dimensional conjugated MOFs (2D c-MOFs) are a novel class of layer-stacked MOFs with in-plane extended π-conjugation that exhibit unique properties such as intrinsic porosity, crystallinity, stability, and electrical conductivity as well as tailorable band gaps. Benefiting from their unique features and high conductivity, 2D c-MOFs have displayed great potential for multiple high-performance (opto)electronic, magnetic, and energy devices. In this review article, we introduce the chemical and synthetic methodologies of 2D c-MOFs, intrinsic influences on their electronic structures and charge transport properties, as well as multifunctional applications of this class of materials for MOFtronics and potential power sources for MOFtronics. We highlight the benefits and limitations of thus-far developed 2D c-MOFs from synthesis to function and offer our perspectives in regard to the challenges to be addressed.
The 21st century has seen a reinvention of how modern electronics impact our daily lives; silicon-electronics and organic electronics are currently at the core of modern electronics. Recent advances have demonstrated that conductive metal-organic frameworks (MOFs), as another unique class of electronic materials, are emerging to provide additional possibility for multifunctional electronic devices that brings us "MOFtronics". Typically, two-dimensional conjugated MOFs (2D c-MOFs) are a novel class of layer-stacked MOFs with in-plane extended π-conjugation that exhibit unique properties such as intrinsic porosity, crystallinity, stability, and electrical conductivity as well as tailorable band gaps. Benefiting from their unique features and high conductivity, 2D c-MOFs have displayed great potential for multiple high-performance (opto)electronic, magnetic, and energy devices. In this review article, we introduce the chemical and synthetic methodologies of 2D c-MOFs, intrinsic influences on their electronic structures and charge transport properties, as well as multifunctional applications of this class of materials for MOFtronics and potential power sources for MOFtronics. We highlight the benefits and limitations of thus-far developed 2D c-MOFs from synthesis to function and offer our perspectives in regard to the challenges to be addressed.The 21st century has seen a reinvention of how modern electronics impact our daily lives; silicon-electronics and organic electronics are currently at the core of modern electronics. Recent advances have demonstrated that conductive metal-organic frameworks (MOFs), as another unique class of electronic materials, are emerging to provide additional possibility for multifunctional electronic devices that brings us "MOFtronics". Typically, two-dimensional conjugated MOFs (2D c-MOFs) are a novel class of layer-stacked MOFs with in-plane extended π-conjugation that exhibit unique properties such as intrinsic porosity, crystallinity, stability, and electrical conductivity as well as tailorable band gaps. Benefiting from their unique features and high conductivity, 2D c-MOFs have displayed great potential for multiple high-performance (opto)electronic, magnetic, and energy devices. In this review article, we introduce the chemical and synthetic methodologies of 2D c-MOFs, intrinsic influences on their electronic structures and charge transport properties, as well as multifunctional applications of this class of materials for MOFtronics and potential power sources for MOFtronics. We highlight the benefits and limitations of thus-far developed 2D c-MOFs from synthesis to function and offer our perspectives in regard to the challenges to be addressed.
Author Wang, Mingchao
Feng, Xinliang
Dong, Renhao
Author_xml – sequence: 1
  givenname: Mingchao
  orcidid: 0000-0001-9979-3503
  surname: Wang
  fullname: Wang, Mingchao
  email: xinliang.feng@tu-dresden.de, renhao.dong@tu-dresden.de
  organization: Center for Advancing Electronics Dresden (cfaed) & Faculty of Chemistry and Food Chemistry, Technische Universität Dresden, 01062 Dresden, Germany. xinliang.feng@tu-dresden.de renhao.dong@tu-dresden.de
– sequence: 2
  givenname: Renhao
  surname: Dong
  fullname: Dong, Renhao
  email: xinliang.feng@tu-dresden.de, renhao.dong@tu-dresden.de
  organization: Center for Advancing Electronics Dresden (cfaed) & Faculty of Chemistry and Food Chemistry, Technische Universität Dresden, 01062 Dresden, Germany. xinliang.feng@tu-dresden.de renhao.dong@tu-dresden.de
– sequence: 3
  givenname: Xinliang
  orcidid: 0000-0003-3885-2703
  surname: Feng
  fullname: Feng, Xinliang
  email: xinliang.feng@tu-dresden.de, renhao.dong@tu-dresden.de
  organization: Center for Advancing Electronics Dresden (cfaed) & Faculty of Chemistry and Food Chemistry, Technische Universität Dresden, 01062 Dresden, Germany. xinliang.feng@tu-dresden.de renhao.dong@tu-dresden.de
BackLink https://www.ncbi.nlm.nih.gov/pubmed/33465213$$D View this record in MEDLINE/PubMed
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Snippet The 21st century has seen a reinvention of how modern electronics impact our daily lives; silicon-electronics and organic electronics are currently at the core...
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