Recent progress in carbon dioxide (CO2) as feedstock for sustainable materials development: Co-polymers and polymer blends

Combustion of fossil fuels and many other industrial activities inevitably produces carbon dioxide (CO2) that is released into the atmosphere and is currently deemed to be among the major contributors to global warming. One of the prominent solutions proposed to mitigate global warming concerns from...

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Vydáno v:Polymer (Guilford) Ročník 145; s. 348 - 373
Hlavní autoři: Muthuraj, Rajendran, Mekonnen, Tizazu
Médium: Journal Article
Jazyk:angličtina
Vydáno: Kidlington Elsevier Ltd 06.06.2018
Elsevier BV
Témata:
Aliphatic compounds
Biodegradability
Biodegradable materials
Biodegradable polymers
Biodegradation
Bioplastics
Biopolymers
Carbon dioxide
Carbon monoxide
Carbon sequestration
Carbonates
Chemical synthesis
Climate change
Copolymers
Food production
Fossil fuels
Global warming
Industrial areas
Material properties
Materials science
Packaging
Plastic debris
Plastic pollution
Poly (ethylene carbonate)
Poly (propylene carbonate)
Polycarbonate resins
Polymer blends
Polymers
Propylene
Raw materials
Sustainability
Sustainable development
Sustainable materials
Poly (propylene carbonate)
Polymer blends
Poly (ethylene carbonate)
Biodegradability
Carbon dioxide
Packaging
Biodegradable polymers
ISSN:0032-3861, 1873-2291
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Abstract Combustion of fossil fuels and many other industrial activities inevitably produces carbon dioxide (CO2) that is released into the atmosphere and is currently deemed to be among the major contributors to global warming. One of the prominent solutions proposed to mitigate global warming concerns from CO2, capture and storage (CCS), did not attract many CO2 emitting industries as expected, mainly because of economic reasons. On the contrary, environmental pollution concerns associated with plastic waste, and the demand for sustainable feedstock for their production constitute grand challenges facing our society with regard to the production and use of plastics. As a result, the materials science community is striving to generate sustainable and biodegradable plastics to substitute conventional synthetic plastics from resources that do not pose direct completion with food production. This manuscript aims to provide a general overview of the recent progress achieved in CO2 based polymers for sustainable biopolymers such as co-polymers, and polymer blends. The synthesis, material properties, processability, and performances of important CO2 based co-polymers are critically reviewed. Furthermore, a critical review of CO2 co-polymers as components of polymer blend with a focus on the most relevant CO2 based aliphatic polycarbonates, poly (propylene carbonates) (PPC), is conducted. [Display omitted] •CO2 can substitute or complement non-renewable feedstock for chemical or material production.•Utilization of CO2 in polymer development can reduce its atmospheric accumulation.•Important CO2 co-polymers can be synthesized by fixation of up to 50% of their mass with CO2.•CO2 co-polymers have desirable attributes as a neat or co-blend with other polymers.
AbstractList Combustion of fossil fuels and many other industrial activities inevitably produces carbon dioxide (CO2) that is released into the atmosphere and is currently deemed to be among the major contributors to global warming. One of the prominent solutions proposed to mitigate global warming concerns from CO2, capture and storage (CCS), did not attract many CO2 emitting industries as expected, mainly because of economic reasons. On the contrary, environmental pollution concerns associated with plastic waste, and the demand for sustainable feedstock for their production constitute grand challenges facing our society with regard to the production and use of plastics. As a result, the materials science community is striving to generate sustainable and biodegradable plastics to substitute conventional synthetic plastics from resources that do not pose direct completion with food production. This manuscript aims to provide a general overview of the recent progress achieved in CO2 based polymers for sustainable biopolymers such as co-polymers, and polymer blends. The synthesis, material properties, processability, and performances of important CO2 based co-polymers are critically reviewed. Furthermore, a critical review of CO2 co-polymers as components of polymer blend with a focus on the most relevant CO2 based aliphatic polycarbonates, poly (propylene carbonates) (PPC), is conducted.
Combustion of fossil fuels and many other industrial activities inevitably produces carbon dioxide (CO2) that is released into the atmosphere and is currently deemed to be among the major contributors to global warming. One of the prominent solutions proposed to mitigate global warming concerns from CO2, capture and storage (CCS), did not attract many CO2 emitting industries as expected, mainly because of economic reasons. On the contrary, environmental pollution concerns associated with plastic waste, and the demand for sustainable feedstock for their production constitute grand challenges facing our society with regard to the production and use of plastics. As a result, the materials science community is striving to generate sustainable and biodegradable plastics to substitute conventional synthetic plastics from resources that do not pose direct completion with food production. This manuscript aims to provide a general overview of the recent progress achieved in CO2 based polymers for sustainable biopolymers such as co-polymers, and polymer blends. The synthesis, material properties, processability, and performances of important CO2 based co-polymers are critically reviewed. Furthermore, a critical review of CO2 co-polymers as components of polymer blend with a focus on the most relevant CO2 based aliphatic polycarbonates, poly (propylene carbonates) (PPC), is conducted. [Display omitted] •CO2 can substitute or complement non-renewable feedstock for chemical or material production.•Utilization of CO2 in polymer development can reduce its atmospheric accumulation.•Important CO2 co-polymers can be synthesized by fixation of up to 50% of their mass with CO2.•CO2 co-polymers have desirable attributes as a neat or co-blend with other polymers.
Author Mekonnen, Tizazu
Muthuraj, Rajendran
Author_xml – sequence: 1
  givenname: Rajendran
  surname: Muthuraj
  fullname: Muthuraj, Rajendran
  organization: Institute for Materials Research and Innovation, University of Bolton, Bolton, BL3 5AB, UK
– sequence: 2
  givenname: Tizazu
  surname: Mekonnen
  fullname: Mekonnen, Tizazu
  email: tmekonnen@uwaterloo.ca
  organization: Department of Chemical Engineering, University of Waterloo, Waterloo, ON, N2L 3G1, Canada
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Keywords Poly (propylene carbonate)
Polymer blends
Poly (ethylene carbonate)
Biodegradability
Carbon dioxide
Packaging
Biodegradable polymers
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Snippet Combustion of fossil fuels and many other industrial activities inevitably produces carbon dioxide (CO2) that is released into the atmosphere and is currently...
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SubjectTerms Aliphatic compounds
Biodegradability
Biodegradable materials
Biodegradable polymers
Biodegradation
Bioplastics
Biopolymers
Carbon dioxide
Carbon monoxide
Carbon sequestration
Carbonates
Chemical synthesis
Climate change
Copolymers
Food production
Fossil fuels
Global warming
Industrial areas
Material properties
Materials science
Packaging
Plastic debris
Plastic pollution
Poly (ethylene carbonate)
Poly (propylene carbonate)
Polycarbonate resins
Polymer blends
Polymers
Propylene
Raw materials
Sustainability
Sustainable development
Sustainable materials
Title Recent progress in carbon dioxide (CO2) as feedstock for sustainable materials development: Co-polymers and polymer blends
URI https://dx.doi.org/10.1016/j.polymer.2018.04.078
https://www.proquest.com/docview/2082632298
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