Heavy metal pollution caused by small-scale metal ore mining activities: A case study from a polymetallic mine in South China
Although metal ore mining activities are well known as an important source of heavy metals, soil pollution caused by small-scale mining activities has long been overlooked. This study investigated the pollution of surface soils in an area surrounding a recently abandoned small-scale polymetallic min...
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| Veröffentlicht in: | The Science of the total environment Jg. 639; S. 217 - 227 |
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| Hauptverfasser: | , , , , |
| Format: | Journal Article |
| Sprache: | Englisch |
| Veröffentlicht: |
Netherlands
Elsevier B.V
15.10.2018
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| ISSN: | 0048-9697, 1879-1026, 1879-1026 |
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| Abstract | Although metal ore mining activities are well known as an important source of heavy metals, soil pollution caused by small-scale mining activities has long been overlooked. This study investigated the pollution of surface soils in an area surrounding a recently abandoned small-scale polymetallic mining district in Guangdong province of south China. A total of 13 tailing samples, 145 surface soil samples, and 29 water samples were collected, and the concentrations of major heavy metals, including Cr, Mn, Co, Ni, Cu, Zn, As, Cd, Pb, and Se, were determined. The results show that the tailings contained high levels of heavy metals, with Cu, Zn, As, Cd, and Pb occurring in the ranges of 739–4.15 × 103, 1.81 × 103–5.00 × 103, 118–1.26 × 103, 8.14–57.7, and 1.23 × 103–6.99 × 103 mg/kg, respectively. Heavy metals also occurred at high concentrations in the mine drainages (15.4–17.9 mg/L for Cu, 21.1–29.3 mg/L for Zn, 0.553–0.770 mg/L for Cd, and 1.17–2.57 mg/L for Pb), particularly those with pH below 3. The mean contents of Cu, Zn, As, Cd, and Pb in the surface soils of local farmlands were up to 7 times higher than the corresponding background values, and results of multivariate statistical analysis clearly indicate that Cu, Zn, Cd, and Pb were largely contributed by the mining activities. The surface soils from farmlands surrounding the mining district were moderately to seriously polluted, while the potential ecological risk of heavy metal pollution was extremely high. It was estimated that the input fluxes from the mining district to the surrounding farmlands were approximately 17.1, 59.2, 0.311, and 93.8 kg/ha/yr for Cu, Zn, Cd, and Pb, respectively, which probably occurred through transport of fine tailings by wind and runoff, and mine drainage as well. These findings indicate the significant need for proper containment of the mine tailings at small-scale metal ore mines.
[Display omitted]
•Heavy metal pollution in a small-scale metal ore mining area was investigated.•Pollution generally decreased with increasing distance from the mining district.•Cu, Zn, Cd, and Pb in local farmland soils came primarily from the mining activities.•Heavy metal pollution of local farmland soils posed high potential ecological risk.•Significant attention needs to be paid to the dumped tailings of small-scale mines. |
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| AbstractList | Although metal ore mining activities are well known as an important source of heavy metals, soil pollution caused by small-scale mining activities has long been overlooked. This study investigated the pollution of surface soils in an area surrounding a recently abandoned small-scale polymetallic mining district in Guangdong province of south China. A total of 13 tailing samples, 145 surface soil samples, and 29 water samples were collected, and the concentrations of major heavy metals, including Cr, Mn, Co, Ni, Cu, Zn, As, Cd, Pb, and Se, were determined. The results show that the tailings contained high levels of heavy metals, with Cu, Zn, As, Cd, and Pb occurring in the ranges of 739-4.15 × 10
, 1.81 × 10
-5.00 × 10
, 118-1.26 × 10
, 8.14-57.7, and 1.23 × 10
-6.99 × 10
mg/kg, respectively. Heavy metals also occurred at high concentrations in the mine drainages (15.4-17.9 mg/L for Cu, 21.1-29.3 mg/L for Zn, 0.553-0.770 mg/L for Cd, and 1.17-2.57 mg/L for Pb), particularly those with pH below 3. The mean contents of Cu, Zn, As, Cd, and Pb in the surface soils of local farmlands were up to 7 times higher than the corresponding background values, and results of multivariate statistical analysis clearly indicate that Cu, Zn, Cd, and Pb were largely contributed by the mining activities. The surface soils from farmlands surrounding the mining district were moderately to seriously polluted, while the potential ecological risk of heavy metal pollution was extremely high. It was estimated that the input fluxes from the mining district to the surrounding farmlands were approximately 17.1, 59.2, 0.311, and 93.8 kg/ha/yr for Cu, Zn, Cd, and Pb, respectively, which probably occurred through transport of fine tailings by wind and runoff, and mine drainage as well. These findings indicate the significant need for proper containment of the mine tailings at small-scale metal ore mines. Although metal ore mining activities are well known as an important source of heavy metals, soil pollution caused by small-scale mining activities has long been overlooked. This study investigated the pollution of surface soils in an area surrounding a recently abandoned small-scale polymetallic mining district in Guangdong province of south China. A total of 13 tailing samples, 145 surface soil samples, and 29 water samples were collected, and the concentrations of major heavy metals, including Cr, Mn, Co, Ni, Cu, Zn, As, Cd, Pb, and Se, were determined. The results show that the tailings contained high levels of heavy metals, with Cu, Zn, As, Cd, and Pb occurring in the ranges of 739-4.15 × 103, 1.81 × 103-5.00 × 103, 118-1.26 × 103, 8.14-57.7, and 1.23 × 103-6.99 × 103 mg/kg, respectively. Heavy metals also occurred at high concentrations in the mine drainages (15.4-17.9 mg/L for Cu, 21.1-29.3 mg/L for Zn, 0.553-0.770 mg/L for Cd, and 1.17-2.57 mg/L for Pb), particularly those with pH below 3. The mean contents of Cu, Zn, As, Cd, and Pb in the surface soils of local farmlands were up to 7 times higher than the corresponding background values, and results of multivariate statistical analysis clearly indicate that Cu, Zn, Cd, and Pb were largely contributed by the mining activities. The surface soils from farmlands surrounding the mining district were moderately to seriously polluted, while the potential ecological risk of heavy metal pollution was extremely high. It was estimated that the input fluxes from the mining district to the surrounding farmlands were approximately 17.1, 59.2, 0.311, and 93.8 kg/ha/yr for Cu, Zn, Cd, and Pb, respectively, which probably occurred through transport of fine tailings by wind and runoff, and mine drainage as well. These findings indicate the significant need for proper containment of the mine tailings at small-scale metal ore mines.Although metal ore mining activities are well known as an important source of heavy metals, soil pollution caused by small-scale mining activities has long been overlooked. This study investigated the pollution of surface soils in an area surrounding a recently abandoned small-scale polymetallic mining district in Guangdong province of south China. A total of 13 tailing samples, 145 surface soil samples, and 29 water samples were collected, and the concentrations of major heavy metals, including Cr, Mn, Co, Ni, Cu, Zn, As, Cd, Pb, and Se, were determined. The results show that the tailings contained high levels of heavy metals, with Cu, Zn, As, Cd, and Pb occurring in the ranges of 739-4.15 × 103, 1.81 × 103-5.00 × 103, 118-1.26 × 103, 8.14-57.7, and 1.23 × 103-6.99 × 103 mg/kg, respectively. Heavy metals also occurred at high concentrations in the mine drainages (15.4-17.9 mg/L for Cu, 21.1-29.3 mg/L for Zn, 0.553-0.770 mg/L for Cd, and 1.17-2.57 mg/L for Pb), particularly those with pH below 3. The mean contents of Cu, Zn, As, Cd, and Pb in the surface soils of local farmlands were up to 7 times higher than the corresponding background values, and results of multivariate statistical analysis clearly indicate that Cu, Zn, Cd, and Pb were largely contributed by the mining activities. The surface soils from farmlands surrounding the mining district were moderately to seriously polluted, while the potential ecological risk of heavy metal pollution was extremely high. It was estimated that the input fluxes from the mining district to the surrounding farmlands were approximately 17.1, 59.2, 0.311, and 93.8 kg/ha/yr for Cu, Zn, Cd, and Pb, respectively, which probably occurred through transport of fine tailings by wind and runoff, and mine drainage as well. These findings indicate the significant need for proper containment of the mine tailings at small-scale metal ore mines. Although metal ore mining activities are well known as an important source of heavy metals, soil pollution caused by small-scale mining activities has long been overlooked. This study investigated the pollution of surface soils in an area surrounding a recently abandoned small-scale polymetallic mining district in Guangdong province of south China. A total of 13 tailing samples, 145 surface soil samples, and 29 water samples were collected, and the concentrations of major heavy metals, including Cr, Mn, Co, Ni, Cu, Zn, As, Cd, Pb, and Se, were determined. The results show that the tailings contained high levels of heavy metals, with Cu, Zn, As, Cd, and Pb occurring in the ranges of 739–4.15 × 10³, 1.81 × 10³–5.00 × 10³, 118–1.26 × 10³, 8.14–57.7, and 1.23 × 10³–6.99 × 10³ mg/kg, respectively. Heavy metals also occurred at high concentrations in the mine drainages (15.4–17.9 mg/L for Cu, 21.1–29.3 mg/L for Zn, 0.553–0.770 mg/L for Cd, and 1.17–2.57 mg/L for Pb), particularly those with pH below 3. The mean contents of Cu, Zn, As, Cd, and Pb in the surface soils of local farmlands were up to 7 times higher than the corresponding background values, and results of multivariate statistical analysis clearly indicate that Cu, Zn, Cd, and Pb were largely contributed by the mining activities. The surface soils from farmlands surrounding the mining district were moderately to seriously polluted, while the potential ecological risk of heavy metal pollution was extremely high. It was estimated that the input fluxes from the mining district to the surrounding farmlands were approximately 17.1, 59.2, 0.311, and 93.8 kg/ha/yr for Cu, Zn, Cd, and Pb, respectively, which probably occurred through transport of fine tailings by wind and runoff, and mine drainage as well. These findings indicate the significant need for proper containment of the mine tailings at small-scale metal ore mines. Although metal ore mining activities are well known as an important source of heavy metals, soil pollution caused by small-scale mining activities has long been overlooked. This study investigated the pollution of surface soils in an area surrounding a recently abandoned small-scale polymetallic mining district in Guangdong province of south China. A total of 13 tailing samples, 145 surface soil samples, and 29 water samples were collected, and the concentrations of major heavy metals, including Cr, Mn, Co, Ni, Cu, Zn, As, Cd, Pb, and Se, were determined. The results show that the tailings contained high levels of heavy metals, with Cu, Zn, As, Cd, and Pb occurring in the ranges of 739–4.15 × 103, 1.81 × 103–5.00 × 103, 118–1.26 × 103, 8.14–57.7, and 1.23 × 103–6.99 × 103 mg/kg, respectively. Heavy metals also occurred at high concentrations in the mine drainages (15.4–17.9 mg/L for Cu, 21.1–29.3 mg/L for Zn, 0.553–0.770 mg/L for Cd, and 1.17–2.57 mg/L for Pb), particularly those with pH below 3. The mean contents of Cu, Zn, As, Cd, and Pb in the surface soils of local farmlands were up to 7 times higher than the corresponding background values, and results of multivariate statistical analysis clearly indicate that Cu, Zn, Cd, and Pb were largely contributed by the mining activities. The surface soils from farmlands surrounding the mining district were moderately to seriously polluted, while the potential ecological risk of heavy metal pollution was extremely high. It was estimated that the input fluxes from the mining district to the surrounding farmlands were approximately 17.1, 59.2, 0.311, and 93.8 kg/ha/yr for Cu, Zn, Cd, and Pb, respectively, which probably occurred through transport of fine tailings by wind and runoff, and mine drainage as well. These findings indicate the significant need for proper containment of the mine tailings at small-scale metal ore mines. [Display omitted] •Heavy metal pollution in a small-scale metal ore mining area was investigated.•Pollution generally decreased with increasing distance from the mining district.•Cu, Zn, Cd, and Pb in local farmland soils came primarily from the mining activities.•Heavy metal pollution of local farmland soils posed high potential ecological risk.•Significant attention needs to be paid to the dumped tailings of small-scale mines. |
| Author | Sun, Zehang Xie, Xiande Hu, Yuanan Cheng, Hefa Wang, Ping |
| Author_xml | – sequence: 1 givenname: Zehang surname: Sun fullname: Sun, Zehang organization: State Key Laboratory of Organic Geochemistry, Guangzhou Institute of Geochemistry, Chinese Academy of Sciences, Guangzhou 510640, China – sequence: 2 givenname: Xiande surname: Xie fullname: Xie, Xiande organization: MOE Key Laboratory for Earth Surface Processes, College of Urban and Environmental Sciences, Peking University, Beijing 100871, China – sequence: 3 givenname: Ping surname: Wang fullname: Wang, Ping organization: MOE Key Laboratory for Earth Surface Processes, College of Urban and Environmental Sciences, Peking University, Beijing 100871, China – sequence: 4 givenname: Yuanan surname: Hu fullname: Hu, Yuanan organization: MOE Laboratory of Groundwater Circulation and Evolution, School of Water Resources and Environment, China University of Geosciences (Beijing), Beijing 100083, China – sequence: 5 givenname: Hefa orcidid: 0000-0003-4911-6971 surname: Cheng fullname: Cheng, Hefa email: hefac@umich.edu organization: MOE Key Laboratory for Earth Surface Processes, College of Urban and Environmental Sciences, Peking University, Beijing 100871, China |
| BackLink | https://www.ncbi.nlm.nih.gov/pubmed/29787905$$D View this record in MEDLINE/PubMed |
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| SubjectTerms | agricultural land arsenic cadmium case studies China chromium cobalt copper drainage Environmental Monitoring Heavy metals lead manganese Metals, Heavy - analysis Mine tailings Mining multivariate analysis nickel risk runoff Small-scale mining activities Soil Soil Pollutants - analysis Soil pollution soil sampling Water pollution wind zinc |
| Title | Heavy metal pollution caused by small-scale metal ore mining activities: A case study from a polymetallic mine in South China |
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