Principles of Water Electrolysis and Recent Progress in Cobalt‐, Nickel‐, and Iron‐Based Oxides for the Oxygen Evolution Reaction

Water electrolysis that results in green hydrogen is the key process towards a circular economy. The supply of sustainable electricity and availability of oxygen evolution reaction (OER) electrocatalysts are the main bottlenecks of the process for large‐scale production of green hydrogen. A broad ra...

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Vydáno v:Angewandte Chemie International Edition Ročník 61; číslo 1; s. e202103824 - n/a
Hlavní autoři: Yu, Mingquan, Budiyanto, Eko, Tüysüz, Harun
Médium: Journal Article
Jazyk:angličtina
Vydáno: Germany Wiley Subscription Services, Inc 03.01.2022
John Wiley and Sons Inc
Vydání:International ed. in English
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ISSN:1433-7851, 1521-3773, 1521-3773
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Shrnutí:Water electrolysis that results in green hydrogen is the key process towards a circular economy. The supply of sustainable electricity and availability of oxygen evolution reaction (OER) electrocatalysts are the main bottlenecks of the process for large‐scale production of green hydrogen. A broad range of OER electrocatalysts have been explored to decrease the overpotential and boost the kinetics of this sluggish half‐reaction. Co‐, Ni‐, and Fe‐based catalysts have been considered to be potential candidates to replace noble metals due to their tunable 3d electron configuration and spin state, versatility in terms of crystal and electronic structures, as well as abundance in nature. This Review provides some basic principles of water electrolysis, key aspects of OER, and significant criteria for the development of the catalysts. It provides also some insights on recent advances of Co‐, Ni‐, and Fe‐based oxides and a brief perspective on green hydrogen production and the challenges of water electrolysis. This Review describes the basic principles of water electrolysis, key aspects of the oxygen evolution reaction (OER), and significant criteria for the development of new catalysts. Recent advances in catalysts based on Co, Ni, and Fe oxides are described, and a brief perspective is given on green hydrogen production and the challenges of water electrolysis.
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ISSN:1433-7851
1521-3773
1521-3773
DOI:10.1002/anie.202103824