ICTAC Kinetics Committee recommendations for collecting experimental thermal analysis data for kinetic computations

•Recommendations developed for collecting TG, DSC, and DTA data for successful kinetic analysis.•Focus is on preparing proper samples and selecting adequate experimental conditions.•Specific advice is offered for most common types of thermal processes, chemical and physical. The present recommendati...

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Vydané v:Thermochimica acta Ročník 590; s. 1 - 23
Hlavní autori: Vyazovkin, Sergey, Chrissafis, Konstantinos, Di Lorenzo, Maria Laura, Koga, Nobuyoshi, Pijolat, Michèle, Roduit, Bertrand, Sbirrazzuoli, Nicolas, Suñol, Joan Josep
Médium: Journal Article
Jazyk:English
Vydavateľské údaje: Elsevier B.V 20.08.2014
Elsevier
Predmet:
ISSN:0040-6031, 1872-762X
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Abstract •Recommendations developed for collecting TG, DSC, and DTA data for successful kinetic analysis.•Focus is on preparing proper samples and selecting adequate experimental conditions.•Specific advice is offered for most common types of thermal processes, chemical and physical. The present recommendations have been developed by the Kinetics Committee of the International Confederation for Thermal Analysis and Calorimetry (ICTAC). The recommendations offer guidance for obtaining kinetic data that are adequate to the actual kinetics of various processes, including thermal decomposition of inorganic solids; thermal and thermo-oxidative degradation of polymers and organics; reactions of solids with gases; polymerization and crosslinking; crystallization of polymers and inorganics; hazardous processes. The recommendations focus on kinetic measurements performed by means of thermal analysis methods such as thermogravimetry (TG) or thermogravimetric analysis (TGA), differential scanning calorimetry (DSC), and differential thermal analysis (DTA). The objective of these recommendations is to assist a non-expert with collecting adequate kinetic data by properly selecting the samples and measurement conditions.
AbstractList The present recommendations have been developed by the Kinetics Committee of the International Confederation for Thermal Analysis and Calorimetry (ICTAC). The recommendations offer guidance for obtaining kinetic data that are adequate to the actual kinetics of various processes, including thermal decomposition of inorganic solids; thermal and thermo-oxidative degradation of polymers and organics; reactions of solids with gases; polymerization and crosslinking; crystallization of polymers and inorganics; hazardous processes. The recommendations focus on kinetic measurements performed by means of thermal analysis methods such as thermogravimetry (TG) or thermogravimetric analysis (TGA), differential scanning calorimetry (DSC), and differential thermal analysis (DTA). The objective of these recommendations is to assist a non-expert with collecting adequate kinetic data by properly selecting the samples and measurement conditions.
•Recommendations developed for collecting TG, DSC, and DTA data for successful kinetic analysis.•Focus is on preparing proper samples and selecting adequate experimental conditions.•Specific advice is offered for most common types of thermal processes, chemical and physical. The present recommendations have been developed by the Kinetics Committee of the International Confederation for Thermal Analysis and Calorimetry (ICTAC). The recommendations offer guidance for obtaining kinetic data that are adequate to the actual kinetics of various processes, including thermal decomposition of inorganic solids; thermal and thermo-oxidative degradation of polymers and organics; reactions of solids with gases; polymerization and crosslinking; crystallization of polymers and inorganics; hazardous processes. The recommendations focus on kinetic measurements performed by means of thermal analysis methods such as thermogravimetry (TG) or thermogravimetric analysis (TGA), differential scanning calorimetry (DSC), and differential thermal analysis (DTA). The objective of these recommendations is to assist a non-expert with collecting adequate kinetic data by properly selecting the samples and measurement conditions.
Author Koga, Nobuyoshi
Sbirrazzuoli, Nicolas
Vyazovkin, Sergey
Roduit, Bertrand
Chrissafis, Konstantinos
Di Lorenzo, Maria Laura
Pijolat, Michèle
Suñol, Joan Josep
Author_xml – sequence: 1
  givenname: Sergey
  orcidid: 0000-0002-6335-4215
  surname: Vyazovkin
  fullname: Vyazovkin, Sergey
  email: vyazovkin@uab.edu
  organization: Department of Chemistry, University of Alabama at Birmingham, 901 S. 14th Street, Birmingham, AL 35294, USA
– sequence: 2
  givenname: Konstantinos
  surname: Chrissafis
  fullname: Chrissafis, Konstantinos
  organization: Solid State Physics Department, School of Physics, Aristotle University of Thessaloniki, Macedonia, Thessaloniki 541 24, Greece
– sequence: 3
  givenname: Maria Laura
  surname: Di Lorenzo
  fullname: Di Lorenzo, Maria Laura
  organization: Istituto per i Polimeri, Compositi e Biomateriali (CNR), c/o Comprensorio Olivetti, Via Campi Flegrei 34, Pozzuoli, NA 80078, Italy
– sequence: 4
  givenname: Nobuyoshi
  surname: Koga
  fullname: Koga, Nobuyoshi
  organization: Department of Science Education, Graduate School of Education, Hiroshima University, 1-1-1 Kagamiyama, Higashi-Hiroshima 739-8524, Japan
– sequence: 5
  givenname: Michèle
  surname: Pijolat
  fullname: Pijolat, Michèle
  organization: École Nationale Supérieure des Mines, Laboratoire Georges Friedel, CNRS UMR 5307, Centre SPIN, Saint-Étienne 42023, France
– sequence: 6
  givenname: Bertrand
  surname: Roduit
  fullname: Roduit, Bertrand
  organization: AKTS Inc., Advanced Kinetics and Technology Solutions, TECHNOArk 1, Siders 3960, Switzerland
– sequence: 7
  givenname: Nicolas
  surname: Sbirrazzuoli
  fullname: Sbirrazzuoli, Nicolas
  organization: Université Nice Sophia Antipolis, Laboratoire de Physique de la Matière Condensée, Equipe Fluides et Matériaux Complexes, CNRS UMR 7336, Parc Valrose Nice Cedex 2 06108, France
– sequence: 8
  givenname: Joan Josep
  surname: Suñol
  fullname: Suñol, Joan Josep
  organization: Departament de Física, Universitat de Girona, Girona, Catalonia 17071, Spain
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Snippet •Recommendations developed for collecting TG, DSC, and DTA data for successful kinetic analysis.•Focus is on preparing proper samples and selecting adequate...
The present recommendations have been developed by the Kinetics Committee of the International Confederation for Thermal Analysis and Calorimetry (ICTAC). The...
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SubjectTerms Chemical and Process Engineering
Chemical Sciences
crosslinking
crystallization
differential scanning calorimetry
differential thermal analysis
Engineering Sciences
gases
Glass
Kinetics
Liquid
Material chemistry
polymerization
polymers
Solid
Temperature gradient
thermal degradation
thermogravimetry
Title ICTAC Kinetics Committee recommendations for collecting experimental thermal analysis data for kinetic computations
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https://hal.science/hal-01056407
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