Mechanical Reinforcement of Polyethylene Using Polyethylene-Grafted Multiwalled Carbon Nanotubes
The incorporation of carbon nanotubes to a polymer generally improves the stiffness and strength of the polymer, but the ductility and toughness of the polymer are compromised in most cases. Here we report the mechanical reinforcement of polyethylene (PE) using polyethylene‐grafted multiwalled carbo...
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| Vydané v: | Advanced functional materials Ročník 17; číslo 13; s. 2062 - 2069 |
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| Hlavní autori: | , , , |
| Médium: | Journal Article |
| Jazyk: | English |
| Vydavateľské údaje: |
Weinheim
WILEY-VCH Verlag
03.09.2007
WILEY‐VCH Verlag |
| Predmet: | |
| ISSN: | 1616-301X, 1616-3028 |
| On-line prístup: | Získať plný text |
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| Shrnutí: | The incorporation of carbon nanotubes to a polymer generally improves the stiffness and strength of the polymer, but the ductility and toughness of the polymer are compromised in most cases. Here we report the mechanical reinforcement of polyethylene (PE) using polyethylene‐grafted multiwalled carbon nanotubes (PE‐g‐MWNTs). The stiffness, strength, ductility and toughness of PE are all improved by the addition of PE‐g‐MWNTs. The grafting of PE onto MWNTs enables the well‐dispersion of nanotubes in the PE matrix and improves MWNT/PE interfacial adhesion. The grafting was achieved by a reactive blending process through melt blending of PE containing 0.85 wt % of maleic anhydride and amine‐functionalized MWNTs. The reaction between maleic anhydride and amine groups, as evidenced by X‐ray photoelectron spectroscopy and Raman spectroscopy, leads to the grafting of PE onto the nanotubes.
Polyethylene is grafted onto multiwalled carbon nanotubes by a reactive blending process. The stiffness, strength, ductility and toughness of polyethylene are all improved by the addition of PE‐g‐MWNTs. |
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| Bibliografia: | The authors gratefully acknowledge the financial support of this research by the National University of Singapore (grant number R-143-000-270-112). ArticleID:ADFM200600599 National University of Singapore - No. R-143-000-270-112 istex:73E0DA2A7E97A8FF27A976CE050DFC10BFB0BAA2 ark:/67375/WNG-R91Q8CJJ-Q The authors gratefully acknowledge the financial support of this research by the National University of Singapore (grant number R‐143‐000‐270‐112). ObjectType-Article-2 SourceType-Scholarly Journals-1 ObjectType-Feature-1 content type line 23 |
| ISSN: | 1616-301X 1616-3028 |
| DOI: | 10.1002/adfm.200600599 |