The concentration and origins of carboxylic acid groups in oil paint

Although the concentration of carboxylic acid (COOH) groups is crucial to understand oil paint chemistry, analytical challenges hindered COOH quantification in complex polymerised oil samples thus far. The concentration of COOH groups is important in understanding oil paint degradation because it dr...

Celý popis

Uloženo v:

Podrobná bibliografie
Vydáno v:	RSC advances Ročník 9; číslo 61; s. 35559 - 35564
Hlavní autoři:	Baij, Lambert, Chassouant, Louise, Hermans, Joen J, Keune, Katrien, Iedema, Piet D
Médium:	Journal Article
Jazyk:	angličtina
Vydáno:	England Royal Society of Chemistry 01.11.2019 The Royal Society of Chemistry
Témata:	Alcohols Autoxidation Carboxylates Carboxylic acids Chemistry Coordination compounds Fatty acids Fourier transform infrared spectroscopy Humidity hydrolysis Linseed oil metal ions metals Organic chemistry Paints Pigments polymerization polymers quantitative analysis Relative humidity saturated fatty acids Soaps triacylglycerols Triglycerides Zinc oxide
ISSN:	2046-2069, 2046-2069
On-line přístup:	Získat plný text
Tagy:	Přidat tag Žádné tagy, Buďte první, kdo vytvoří štítek k tomuto záznamu!

Abstract	Although the concentration of carboxylic acid (COOH) groups is crucial to understand oil paint chemistry, analytical challenges hindered COOH quantification in complex polymerised oil samples thus far. The concentration of COOH groups is important in understanding oil paint degradation because it drives the breakdown of reactive inorganic pigments to dissolve in the oil network and form metal carboxylates. The metal ions in such an ionomeric polymer network can exchange with saturated fatty acids to form crystalline metal soaps (metal complexes of saturated fatty acids), leading to serious problems in many paintings worldwide. We developed two methods based on ATR-FTIR spectroscopy to accurately estimate the COOH concentration in artificially aged oil paint models. Using tailored model systems composed of linseed oil, ZnO and inert filler pigments, these dried oil paints were found to contain one COOH group per triacylglycerol unit. Model systems based on a mixture of long chain alcohols showed that the calculated COOH concentration originates from side chain autoxidation at low relative humidity (RH). The influence of increasing RH and ZnO concentration on COOH formation was studied and high relative humidity conditions were shown to promote the formation of COOH groups. No significant ester hydrolysis was found under the conditions studied. Our results show the potential of quantitative analysis of oil paint model systems for aiding careful (re)evaluation of conservation strategies. Zinc complexation can be used to quantify the concentration of carboxylic acid groups in an oil painting.
AbstractList	Although the concentration of carboxylic acid (COOH) groups is crucial to understand oil paint chemistry, analytical challenges hindered COOH quantification in complex polymerised oil samples thus far. The concentration of COOH groups is important in understanding oil paint degradation because it drives the breakdown of reactive inorganic pigments to dissolve in the oil network and form metal carboxylates. The metal ions in such an ionomeric polymer network can exchange with saturated fatty acids to form crystalline metal soaps (metal complexes of saturated fatty acids), leading to serious problems in many paintings worldwide. We developed two methods based on ATR-FTIR spectroscopy to accurately estimate the COOH concentration in artificially aged oil paint models. Using tailored model systems composed of linseed oil, ZnO and inert filler pigments, these dried oil paints were found to contain one COOH group per triacylglycerol unit. Model systems based on a mixture of long chain alcohols showed that the calculated COOH concentration originates from side chain autoxidation at low relative humidity (RH). The influence of increasing RH and ZnO concentration on COOH formation was studied and high relative humidity conditions were shown to promote the formation of COOH groups. No significant ester hydrolysis was found under the conditions studied. Our results show the potential of quantitative analysis of oil paint model systems for aiding careful (re)evaluation of conservation strategies. Zinc complexation can be used to quantify the concentration of carboxylic acid groups in an oil painting. Although the concentration of carboxylic acid (COOH) groups is crucial to understand oil paint chemistry, analytical challenges hindered COOH quantification in complex polymerised oil samples thus far. The concentration of COOH groups is important in understanding oil paint degradation because it drives the breakdown of reactive inorganic pigments to dissolve in the oil network and form metal carboxylates. The metal ions in such an ionomeric polymer network can exchange with saturated fatty acids to form crystalline metal soaps (metal complexes of saturated fatty acids), leading to serious problems in many paintings worldwide. We developed two methods based on ATR-FTIR spectroscopy to accurately estimate the COOH concentration in artificially aged oil paint models. Using tailored model systems composed of linseed oil, ZnO and inert filler pigments, these dried oil paints were found to contain one COOH group per triacylglycerol unit. Model systems based on a mixture of long chain alcohols showed that the calculated COOH concentration originates from side chain autoxidation at low relative humidity (RH). The influence of increasing RH and ZnO concentration on COOH formation was studied and high relative humidity conditions were shown to promote the formation of COOH groups. No significant ester hydrolysis was found under the conditions studied. Our results show the potential of quantitative analysis of oil paint model systems for aiding careful (re)evaluation of conservation strategies. Although the concentration of carboxylic acid (COOH) groups is crucial to understand oil paint chemistry, analytical challenges hindered COOH quantification in complex polymerised oil samples thus far. The concentration of COOH groups is important in understanding oil paint degradation because it drives the breakdown of reactive inorganic pigments to dissolve in the oil network and form metal carboxylates. The metal ions in such an ionomeric polymer network can exchange with saturated fatty acids to form crystalline metal soaps (metal complexes of saturated fatty acids), leading to serious problems in many paintings worldwide. We developed two methods based on ATR-FTIR spectroscopy to accurately estimate the COOH concentration in artificially aged oil paint models. Using tailored model systems composed of linseed oil, ZnO and inert filler pigments, these dried oil paints were found to contain one COOH group per triacylglycerol unit. Model systems based on a mixture of long chain alcohols showed that the calculated COOH concentration originates from side chain autoxidation at low relative humidity (RH). The influence of increasing RH and ZnO concentration on COOH formation was studied and high relative humidity conditions were shown to promote the formation of COOH groups. No significant ester hydrolysis was found under the conditions studied. Our results show the potential of quantitative analysis of oil paint model systems for aiding careful (re)evaluation of conservation strategies.Although the concentration of carboxylic acid (COOH) groups is crucial to understand oil paint chemistry, analytical challenges hindered COOH quantification in complex polymerised oil samples thus far. The concentration of COOH groups is important in understanding oil paint degradation because it drives the breakdown of reactive inorganic pigments to dissolve in the oil network and form metal carboxylates. The metal ions in such an ionomeric polymer network can exchange with saturated fatty acids to form crystalline metal soaps (metal complexes of saturated fatty acids), leading to serious problems in many paintings worldwide. We developed two methods based on ATR-FTIR spectroscopy to accurately estimate the COOH concentration in artificially aged oil paint models. Using tailored model systems composed of linseed oil, ZnO and inert filler pigments, these dried oil paints were found to contain one COOH group per triacylglycerol unit. Model systems based on a mixture of long chain alcohols showed that the calculated COOH concentration originates from side chain autoxidation at low relative humidity (RH). The influence of increasing RH and ZnO concentration on COOH formation was studied and high relative humidity conditions were shown to promote the formation of COOH groups. No significant ester hydrolysis was found under the conditions studied. Our results show the potential of quantitative analysis of oil paint model systems for aiding careful (re)evaluation of conservation strategies. Although the concentration of carboxylic acid (COOH) groups is crucial to understand oil paint chemistry, analytical challenges hindered COOH quantification in complex polymerised oil samples thus far. The concentration of COOH groups is important in understanding oil paint degradation because it drives the breakdown of reactive inorganic pigments to dissolve in the oil network and form metal carboxylates. The metal ions in such an ionomeric polymer network can exchange with saturated fatty acids to form crystalline metal soaps (metal complexes of saturated fatty acids), leading to serious problems in many paintings worldwide. We developed two methods based on ATR-FTIR spectroscopy to accurately estimate the COOH concentration in artificially aged oil paint models. Using tailored model systems composed of linseed oil, ZnO and inert filler pigments, these dried oil paints were found to contain one COOH group per triacylglycerol unit. Model systems based on a mixture of long chain alcohols showed that the calculated COOH concentration originates from side chain autoxidation at low relative humidity (RH). The influence of increasing RH and ZnO concentration on COOH formation was studied and high relative humidity conditions were shown to promote the formation of COOH groups. No significant ester hydrolysis was found under the conditions studied. Our results show the potential of quantitative analysis of oil paint model systems for aiding careful (re)evaluation of conservation strategies. Zinc complexation can be used to quantify the concentration of carboxylic acid groups in an oil painting.
Author	Iedema, Piet D Baij, Lambert Keune, Katrien Chassouant, Louise Hermans, Joen J
AuthorAffiliation	Rijksmuseum Amsterdam, Conservation and Science University of Amsterdam Van 't Hoff Institute for Molecular Sciences
AuthorAffiliation_xml	– sequence: 0 name: Rijksmuseum Amsterdam, Conservation and Science – sequence: 0 name: University of Amsterdam – sequence: 0 name: Van 't Hoff Institute for Molecular Sciences
Author_xml	– sequence: 1 givenname: Lambert surname: Baij fullname: Baij, Lambert – sequence: 2 givenname: Louise surname: Chassouant fullname: Chassouant, Louise – sequence: 3 givenname: Joen J surname: Hermans fullname: Hermans, Joen J – sequence: 4 givenname: Katrien surname: Keune fullname: Keune, Katrien – sequence: 5 givenname: Piet D surname: Iedema fullname: Iedema, Piet D
BackLink	https://www.ncbi.nlm.nih.gov/pubmed/35528099$$D View this record in MEDLINE/PubMed
BookMark	eNqNks1rVDEUxYNU7IfduFcCboowevMxybsboYxaSwuC1HXIy8ubpr5JxuQ9sf-9aacda3FhNjeQ3z2c3HP3yU5M0RPygsFbBgLfOcwWlNbq-xOyx0GqGQeFOw_uu-SwlCuoR80ZV-wZ2RXzOW8AcY98uLj01KXofByzHUOK1MaOphyWIRaaeupsbtOv6yE4al3o6DKnaV1oiDSFga5tiONz8rS3Q_GHd_WAfPv08WLxeXb-5eR0cXw-c1KxcdZ0DMC22GsNElvWa26B2aaBlvHWYa-8q35b181RAjomkFvBJHZca45OHJD3G9311K58t_E8mHUOK5uvTbLB_P0Sw6VZpp8GQUsldBU4uhPI6cfky2hWoTg_DDb6NBXDlWKykZr9BypEnWaD_AZ9_Qi9SlOOdRKVYlwiNgoq9eqh-a3r-ywq8GYDuJxKyb7fIgzMTdZmgV-Pb7M-qzA8gl0Yb_OrHw_Dv1teblpycVvpP-sjfgOvObN_
CitedBy_id	crossref_primary_10_1016_j_ijheatmasstransfer_2022_123682 crossref_primary_10_1186_s40494_024_01309_y crossref_primary_10_1186_s40494_023_00988_3 crossref_primary_10_1186_s40494_022_00733_2 crossref_primary_10_1016_j_saa_2022_121414 crossref_primary_10_1038_s40494_025_01986_3 crossref_primary_10_1016_j_matchemphys_2020_123640 crossref_primary_10_1186_s40494_023_01082_4 crossref_primary_10_1038_s41598_020_67115_1 crossref_primary_10_1016_j_cej_2020_126485 crossref_primary_10_1186_s40494_020_00451_7 crossref_primary_10_3390_molecules27113362 crossref_primary_10_1016_j_microc_2020_104842 crossref_primary_10_1016_j_porgcoat_2020_106041 crossref_primary_10_1016_j_saa_2023_122962 crossref_primary_10_1007_s10973_024_13463_3 crossref_primary_10_1016_j_microc_2021_107012 crossref_primary_10_1177_0003702820935183 crossref_primary_10_1186_s40494_020_00388_x crossref_primary_10_1016_j_microc_2024_112534 crossref_primary_10_1038_s41598_021_93268_8 crossref_primary_10_1016_j_molstruc_2025_144016 crossref_primary_10_1038_s40494_025_01861_1 crossref_primary_10_1016_j_euromechsol_2022_104827 crossref_primary_10_1016_j_culher_2024_06_008 crossref_primary_10_1186_s40494_021_00599_w
Cites_doi	10.1016/S0141-3910(99)00020-8 10.1179/sic.2003.48.2.111 10.1111/1750-3841.12197 10.1007/BF02679607 10.1039/C7RA13364B 10.1021/acs.macromol.8b00890 10.1007/978-3-319-90617-1 10.1016/S0021-9673(02)00049-3 10.1016/0032-3861(87)90248-5 10.1016/S0300-9440(00)00126-0 10.1016/j.aca.2017.11.017 10.1016/j.porgcoat.2011.08.021 10.1007/s11746-999-0114-3 10.1080/00393630.2016.1230978 10.1021/acs.analchem.6b04065 10.1016/j.ccr.2005.02.002 10.1002/anie.201712751 10.1038/s41598-019-41893-9 10.1126/sciadv.aaw3592 10.1016/j.porgcoat.2015.12.010 10.1021/ac049350k 10.1007/BF02540572 10.1021/ma00138a029 10.1016/j.microc.2018.01.017 10.1016/j.foodchem.2016.06.035 10.1039/C4AY00344F 10.1016/j.microc.2015.11.048 10.1179/sic.1965.015 10.1039/C6RA18267D 10.1021/la981187z 10.1371/journal.pone.0049333 10.1039/C5JA00120J
ContentType	Journal Article
Copyright	This journal is © The Royal Society of Chemistry. Copyright Royal Society of Chemistry 2019 This journal is © The Royal Society of Chemistry 2019 The Royal Society of Chemistry
Copyright_xml	– notice: This journal is © The Royal Society of Chemistry. – notice: Copyright Royal Society of Chemistry 2019 – notice: This journal is © The Royal Society of Chemistry 2019 The Royal Society of Chemistry
DBID	AAYXX CITATION NPM 7SR 8BQ 8FD JG9 7S9 L.6 7X8 5PM
DOI	10.1039/c9ra06776k
DatabaseName	CrossRef PubMed Engineered Materials Abstracts METADEX Technology Research Database Materials Research Database AGRICOLA AGRICOLA - Academic MEDLINE - Academic PubMed Central (Full Participant titles)
DatabaseTitle	CrossRef PubMed Materials Research Database Engineered Materials Abstracts Technology Research Database METADEX AGRICOLA AGRICOLA - Academic MEDLINE - Academic
DatabaseTitleList	AGRICOLA Materials Research Database PubMed CrossRef MEDLINE - Academic
Database_xml	– sequence: 1 dbid: NPM name: PubMed url: http://www.ncbi.nlm.nih.gov/entrez/query.fcgi?db=PubMed sourceTypes: Index Database – sequence: 2 dbid: 7X8 name: MEDLINE - Academic url: https://search.proquest.com/medline sourceTypes: Aggregation Database
DeliveryMethod	fulltext_linktorsrc
Discipline	Chemistry
EISSN	2046-2069
EndPage	35564
ExternalDocumentID	PMC9074637 35528099 10_1039_C9RA06776K c9ra06776k
Genre	Journal Article
GrantInformation_xml	– fundername: ; grantid: 646063
GroupedDBID	-JG 0-7 0R~ 53G AAFWJ AAHBH AAIWI AAJAE AARTK AAWGC AAXHV ABEMK ABGFH ABPDG ABXOH ACGFS ADBBV ADMRA AEFDR AENEX AESAV AFLYV AFVBQ AGEGJ AGRSR AGSTE AHGCF AKBGW ALMA_UNASSIGNED_HOLDINGS ANUXI APEMP ASKNT AUDPV BCNDV BLAPV BSQNT C6K EBS EE0 EF- EJD GROUPED_DOAJ H13 HZ~ H~N J3I M~E O9- OK1 PGMZT R7C R7G RCNCU RPM RPMJG RRC RSCEA RVUXY SLH SMJ ZCN AAYXX ABIQK AFPKN AGMRB CITATION NPM 7SR 8BQ 8FD JG9 7S9 L.6 7X8 5PM
ID	FETCH-LOGICAL-c461t-8d100ab9f77049b1f72a01a880b12bc9f6ec069bcd59409c1392a3149d27729c3
ISICitedReferencesCount	38
ISICitedReferencesURI	http://www.webofscience.com/api/gateway?GWVersion=2&SrcApp=Summon&SrcAuth=ProQuest&DestLinkType=CitingArticles&DestApp=WOS_CPL&KeyUT=000498861100025&url=https%3A%2F%2Fcvtisr.summon.serialssolutions.com%2F%23%21%2Fsearch%3Fho%3Df%26include.ft.matches%3Dt%26l%3Dnull%26q%3D
ISSN	2046-2069
IngestDate	Tue Nov 04 01:57:36 EST 2025 Wed Oct 01 15:04:39 EDT 2025 Fri Sep 05 07:23:04 EDT 2025 Sun Nov 09 06:28:30 EST 2025 Thu Apr 03 07:05:34 EDT 2025 Sat Nov 29 06:33:14 EST 2025 Tue Nov 18 21:37:20 EST 2025 Tue Dec 17 20:59:08 EST 2024
IsDoiOpenAccess	true
IsOpenAccess	true
IsPeerReviewed	true
IsScholarly	true
Issue	61
Language	English
License	This journal is © The Royal Society of Chemistry.
LinkModel	OpenURL
MergedId	FETCHMERGED-LOGICAL-c461t-8d100ab9f77049b1f72a01a880b12bc9f6ec069bcd59409c1392a3149d27729c3
Notes	10.1039/c9ra06776k Electronic supplementary information (ESI) available. See DOI ObjectType-Article-1 SourceType-Scholarly Journals-1 ObjectType-Feature-2 content type line 14 content type line 23
ORCID	0000-0002-9196-2955 0000-0002-9446-9904
OpenAccessLink	http://dx.doi.org/10.1039/c9ra06776k
PMID	35528099
PQID	2312499860
PQPubID	2047525
PageCount	6
ParticipantIDs	pubmedcentral_primary_oai_pubmedcentral_nih_gov_9074637 proquest_journals_2312499860 pubmed_primary_35528099 crossref_primary_10_1039_C9RA06776K proquest_miscellaneous_2335128927 rsc_primary_c9ra06776k proquest_miscellaneous_2661484717 crossref_citationtrail_10_1039_C9RA06776K
PublicationCentury	2000
PublicationDate	2019-November-01
PublicationDateYYYYMMDD	2019-11-01
PublicationDate_xml	– month: 11 year: 2019 text: 2019-November-01 day: 01
PublicationDecade	2010
PublicationPlace	England
PublicationPlace_xml	– name: England – name: Cambridge
PublicationTitle	RSC advances
PublicationTitleAlternate	RSC Adv
PublicationYear	2019
Publisher	Royal Society of Chemistry The Royal Society of Chemistry
Publisher_xml	– name: Royal Society of Chemistry – name: The Royal Society of Chemistry
References	van den Berg (C9RA06776K-(cit9)/[position()=1]) 2002; 950 Hermans (C9RA06776K-(cit6)/[position()=1]) 2019; 5 Mahesar (C9RA06776K-(cit21)/[position()=1]) 2014; 6 Lee (C9RA06776K-(cit15)/[position()=1]) 2018; 138 Lazzari (C9RA06776K-(cit17)/[position()=1]) 1999; 65 Jiang (C9RA06776K-(cit20)/[position()=1]) 2016; 212 Mallégol (C9RA06776K-(cit26)/[position()=1]) 2000; 39 van Driel (C9RA06776K-(cit30)/[position()=1]) 2016; 126 Marshall (C9RA06776K-(cit27)/[position()=1]) 1987; 28 Spyros (C9RA06776K-(cit11)/[position()=1]) 2004; 76 Modugno (C9RA06776K-(cit16)/[position()=1]) 2019; 9 Casadio (C9RA06776K-(cit1)/[position()=1]) 2019 Jones (C9RA06776K-(cit8)/[position()=1]) 1965; 10 Choe (C9RA06776K-(cit32)/[position()=1]) 2013; 78 Hermans (C9RA06776K-(cit2)/[position()=1]) 2015; 30 Sutherland (C9RA06776K-(cit10)/[position()=1]) 2003; 48 Banti (C9RA06776K-(cit13)/[position()=1]) 2018; 8 Brozoski (C9RA06776K-(cit7)/[position()=1]) 1984; 17 La Nasa (C9RA06776K-(cit14)/[position()=1]) 2018; 1001 Bonaduce (C9RA06776K-(cit12)/[position()=1]) 2012; 7 Baij (C9RA06776K-(cit24)/[position()=1]) 2018; 51 Suzuki (C9RA06776K-(cit23)/[position()=1]) 1999; 15 Baij (C9RA06776K-(cit5)/[position()=1]) 2018; 57 Miyashita (C9RA06776K-(cit33)/[position()=1]) 1986; 63 Hermans (C9RA06776K-(cit3)/[position()=1]) 2016; 6 van Gorkum (C9RA06776K-(cit18)/[position()=1]) 2005; 249 Mallégol (C9RA06776K-(cit25)/[position()=1]) 1999; 76 Gopala Krishna (C9RA06776K-(cit31)/[position()=1]) 1992; 69 (C9RA06776K-(cit29)/[position()=1]) 1986; vol. 1 de Viguerie (C9RA06776K-(cit28)/[position()=1]) 2016; 93 Schilling (C9RA06776K-(cit22)/[position()=1]) 2016; 61 Gabrieli (C9RA06776K-(cit4)/[position()=1]) 2017; 89 Soucek (C9RA06776K-(cit19)/*[position()=1]) 2012; 73
References_xml	– issn: 2019 publication-title: Metal Soaps in Art: Conservation and Research doi: Casadio Keune Noble van Loon Hendriks Centeno Osmond – issn: 1986 issue: vol. 1 end-page: 61 publication-title: Artists Pigments – volume: 65 start-page: 303 year: 1999 ident: C9RA06776K-(cit17)/[position()=1] publication-title: Polym. Degrad. Stab. doi: 10.1016/S0141-3910(99)00020-8 – volume: 48 start-page: 111 year: 2003 ident: C9RA06776K-(cit10)/[position()=1] publication-title: Stud. Conserv. doi: 10.1179/sic.2003.48.2.111 – volume: 78 start-page: C1144 year: 2013 ident: C9RA06776K-(cit32)/[position()=1] publication-title: J. Food Sci. doi: 10.1111/1750-3841.12197 – volume: 63 start-page: 1380 year: 1986 ident: C9RA06776K-(cit33)/[position()=1] publication-title: J. Am. Oil Chem. Soc. doi: 10.1007/BF02679607 – volume: 8 start-page: 6001 year: 2018 ident: C9RA06776K-(cit13)/[position()=1] publication-title: RSC Adv. doi: 10.1039/C7RA13364B – volume: vol. 1 start-page: 61 volume-title: Artists Pigments year: 1986 ident: C9RA06776K-(cit29)/[position()=1] – volume: 51 start-page: 7134 year: 2018 ident: C9RA06776K-(cit24)/[position()=1] publication-title: Macromolecules doi: 10.1021/acs.macromol.8b00890 – volume-title: Metal Soaps in Art: Conservation and Research year: 2019 ident: C9RA06776K-(cit1)/[position()=1] doi: 10.1007/978-3-319-90617-1 – volume: 950 start-page: 195 issue: 1 year: 2002 ident: C9RA06776K-(cit9)/[position()=1] publication-title: J. Chromatogr. A doi: 10.1016/S0021-9673(02)00049-3 – volume: 28 start-page: 1093 year: 1987 ident: C9RA06776K-(cit27)/[position()=1] publication-title: Polymer doi: 10.1016/0032-3861(87)90248-5 – volume: 39 start-page: 107 year: 2000 ident: C9RA06776K-(cit26)/[position()=1] publication-title: Prog. Org. Coat. doi: 10.1016/S0300-9440(00)00126-0 – volume: 1001 start-page: 51 year: 2018 ident: C9RA06776K-(cit14)/[position()=1] publication-title: Anal. Chim. Acta doi: 10.1016/j.aca.2017.11.017 – volume: 73 start-page: 435 year: 2012 ident: C9RA06776K-(cit19)/[position()=1] publication-title: Prog. Org. Coat. doi: 10.1016/j.porgcoat.2011.08.021 – volume: 76 start-page: 967 year: 1999 ident: C9RA06776K-(cit25)/[position()=1] publication-title: J. Am. Oil Chem. Soc. doi: 10.1007/s11746-999-0114-3 – volume: 61 start-page: 3 year: 2016 ident: C9RA06776K-(cit22)/[position()=1] publication-title: Stud. Conserv. doi: 10.1080/00393630.2016.1230978 – volume: 89 start-page: 1283 year: 2017 ident: C9RA06776K-(cit4)/[position()=1] publication-title: Anal. Chem. doi: 10.1021/acs.analchem.6b04065 – volume: 249 start-page: 1709 year: 2005 ident: C9RA06776K-(cit18)/[position()=1] publication-title: Coord. Chem. Rev. doi: 10.1016/j.ccr.2005.02.002 – volume: 57 start-page: 7351 year: 2018 ident: C9RA06776K-(cit5)/[position()=1] publication-title: Angew. Chem., Int. Ed. doi: 10.1002/anie.201712751 – volume: 9 start-page: 5533 year: 2019 ident: C9RA06776K-(cit16)/[position()=1] publication-title: Sci. Rep. doi: 10.1038/s41598-019-41893-9 – volume: 5 start-page: eaaw3592 year: 2019 ident: C9RA06776K-(cit6)/[position()=1] publication-title: Sci. Adv. doi: 10.1126/sciadv.aaw3592 – volume: 93 start-page: 46 year: 2016 ident: C9RA06776K-(cit28)/[position()=1] publication-title: Prog. Org. Coat. doi: 10.1016/j.porgcoat.2015.12.010 – volume: 76 start-page: 4929 year: 2004 ident: C9RA06776K-(cit11)/[position()=1] publication-title: Anal. Chem. doi: 10.1021/ac049350k – volume: 69 start-page: 178 year: 1992 ident: C9RA06776K-(cit31)/[position()=1] publication-title: J. Am. Oil Chem. Soc. doi: 10.1007/BF02540572 – volume: 17 start-page: 1591 year: 1984 ident: C9RA06776K-(cit7)/[position()=1] publication-title: Macromolecules doi: 10.1021/ma00138a029 – volume: 138 start-page: 282 year: 2018 ident: C9RA06776K-(cit15)/[position()=1] publication-title: Microchem. J. doi: 10.1016/j.microc.2018.01.017 – volume: 212 start-page: 585 year: 2016 ident: C9RA06776K-(cit20)/[position()=1] publication-title: Food Chem. doi: 10.1016/j.foodchem.2016.06.035 – volume: 6 start-page: 4956 year: 2014 ident: C9RA06776K-(cit21)/[position()=1] publication-title: Anal. Methods doi: 10.1039/C4AY00344F – volume: 126 start-page: 162 year: 2016 ident: C9RA06776K-(cit30)/[position()=1] publication-title: Microchem. J. doi: 10.1016/j.microc.2015.11.048 – volume: 10 start-page: 119 year: 1965 ident: C9RA06776K-(cit8)/[position()=1] publication-title: Stud. Conserv. doi: 10.1179/sic.1965.015 – volume: 6 start-page: 93363 year: 2016 ident: C9RA06776K-(cit3)/[position()=1] publication-title: RSC Adv. doi: 10.1039/C6RA18267D – volume: 15 start-page: 4283 year: 1999 ident: C9RA06776K-(cit23)/[position()=1] publication-title: Langmuir doi: 10.1021/la981187z – volume: 7 start-page: e49333 year: 2012 ident: C9RA06776K-(cit12)/[position()=1] publication-title: PLoS One doi: 10.1371/journal.pone.0049333 – volume: 30 start-page: 1600 year: 2015 ident: C9RA06776K-(cit2)/*[position()=1] publication-title: J. Anal. At. Spectrom. doi: 10.1039/C5JA00120J
SSID	ssj0000651261
Score	2.4449277
Snippet	Although the concentration of carboxylic acid (COOH) groups is crucial to understand oil paint chemistry, analytical challenges hindered COOH quantification in...
SourceID	pubmedcentral proquest pubmed crossref rsc
SourceType	Open Access Repository Aggregation Database Index Database Enrichment Source Publisher
StartPage	35559
SubjectTerms	Alcohols Autoxidation Carboxylates Carboxylic acids Chemistry Coordination compounds Fatty acids Fourier transform infrared spectroscopy Humidity hydrolysis Linseed oil metal ions metals Organic chemistry Paints Pigments polymerization polymers quantitative analysis Relative humidity saturated fatty acids Soaps triacylglycerols Triglycerides Zinc oxide
Title	The concentration and origins of carboxylic acid groups in oil paint
URI	https://www.ncbi.nlm.nih.gov/pubmed/35528099 https://www.proquest.com/docview/2312499860 https://www.proquest.com/docview/2335128927 https://www.proquest.com/docview/2661484717 https://pubmed.ncbi.nlm.nih.gov/PMC9074637
Volume	9
WOSCitedRecordID	wos000498861100025&url=https%3A%2F%2Fcvtisr.summon.serialssolutions.com%2F%23%21%2Fsearch%3Fho%3Df%26include.ft.matches%3Dt%26l%3Dnull%26q%3D
hasFullText	1
inHoldings	1
isFullTextHit
isPrint
journalDatabaseRights	– providerCode: PRVAON databaseName: Directory of Open Access Journals (DOAJ) customDbUrl: eissn: 2046-2069 dateEnd: 99991231 omitProxy: false ssIdentifier: ssj0000651261 issn: 2046-2069 databaseCode: DOA dateStart: 20170101 isFulltext: true titleUrlDefault: https://www.doaj.org/ providerName: Directory of Open Access Journals – providerCode: PRVHPJ databaseName: ROAD: Directory of Open Access Scholarly Resources customDbUrl: eissn: 2046-2069 dateEnd: 99991231 omitProxy: false ssIdentifier: ssj0000651261 issn: 2046-2069 databaseCode: M~E dateStart: 20110101 isFulltext: true titleUrlDefault: https://road.issn.org providerName: ISSN International Centre
link	http://cvtisr.summon.serialssolutions.com/2.0.0/link/0/eLvHCXMwtV1bb9MwFLboQIIXxG3QMSojEBKaAonTJvbjVDZNailodFLfIttJtIjJ6XpB5YXfzjmOk1B1QuOBl6hKjlLH54tzbv4OIW8FWrUqTL2Qax-jVZmn0lR4AzDt8xQbSKeWxHUcTyZ8NhNf3e6SpW0nEBvDNxsx_6-qhnOgbNw6-w_qbm4KJ-A3KB2OoHY43lrxGjcjGseIa_MDVQMsW7eh5UKVm5_Ibi11kR7ZjR22LLYsro7msjBb8frzb8O6UqANqcsq6zOW2E-kqZwZXoIpXq5lxWUwLtdFm_o5w0-AcVmHzLTpqFG2rqKqI-wW4HamuThEINyGvGa5YuBpgyKqxisfshvOufVW_AGriojdLZ5g-lTs4DvLuh8iK6oWC4mEd9H39uNVJ-wnX5LTi_E4mZ7Mpu_m1x7OKqbfXY-VDrnL4oHAmr_Pv9ogHNhfAbOcus1IawrbUHxs_2_baNnxRHYLajuLun-MtVOmj8hD52DQ4woYj8mdzDwh94d1X7-n5BMAhG4BhAJAqAMILXPaAoQiQGgFEFoYCgChFiDPyMXpyXR45rleGp7uR8HK42ng-1KJPI7BJ1RBHjPpBxJWbxUwpUUeZRqeXul0IMDl1-AYMBmC-5wy9L90uE_2TGmyF4RGnKV5oAaZ6kd9zhTP-jBxvM9YoGQUpl3yvp6sRDuieex3cpXYgodQJENxfmwndtQlbxrZeUWvcqPUYT3niXvTlgk4JgzcdR75XfK6uQxziRkvabJyjTIhKJgLFv9FBi1UtNFA5nmlxmYogEjGwYfqknhLwY0AkrNvXzHFpSVpx6BTFMI99wEKjXwLqYNbDOgledC-aYdkb7VYZ6_IPf1jVSwXPdKJZ7xng0g9C-vfYge4HQ
linkProvider	ISSN International Centre
openUrl	ctx_ver=Z39.88-2004&ctx_enc=info%3Aofi%2Fenc%3AUTF-8&rfr_id=info%3Asid%2Fsummon.serialssolutions.com&rft_val_fmt=info%3Aofi%2Ffmt%3Akev%3Amtx%3Ajournal&rft.genre=article&rft.atitle=The+concentration+and+origins+of+carboxylic+acid+groups+in+oil+paint&rft.jtitle=RSC+advances&rft.au=Baij%2C+Lambert&rft.au=Chassouant%2C+Louise&rft.au=Hermans%2C+Joen+J&rft.au=Keune%2C+Katrien&rft.date=2019-11-01&rft.issn=2046-2069&rft.eissn=2046-2069&rft.volume=9&rft.issue=61&rft.spage=35559&rft_id=info:doi/10.1039%2Fc9ra06776k&rft.externalDBID=NO_FULL_TEXT
thumbnail_l	http://covers-cdn.summon.serialssolutions.com/index.aspx?isbn=/lc.gif&issn=2046-2069&client=summon
thumbnail_m	http://covers-cdn.summon.serialssolutions.com/index.aspx?isbn=/mc.gif&issn=2046-2069&client=summon
thumbnail_s	http://covers-cdn.summon.serialssolutions.com/index.aspx?isbn=/sc.gif&issn=2046-2069&client=summon