Catalytic Hydrogen Production from Methane Partial Oxidation: Mechanism and Kinetic Study
The multifunctional potential of a transition and noble metal catalyst supported on either a single support or combined oxide support in the catalytic partial oxidation of methane (CPOM) is reviewed. The close interaction and interfacial area between the metal, reducible oxide, and acidic support ar...
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| Vydáno v: | Chemical engineering & technology Ročník 43; číslo 4; s. 641 - 648 |
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| Médium: | Journal Article |
| Jazyk: | angličtina |
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Frankfurt
Wiley Subscription Services, Inc
01.04.2020
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| ISSN: | 0930-7516, 1521-4125 |
| On-line přístup: | Získat plný text |
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| Abstract | The multifunctional potential of a transition and noble metal catalyst supported on either a single support or combined oxide support in the catalytic partial oxidation of methane (CPOM) is reviewed. The close interaction and interfacial area between the metal, reducible oxide, and acidic support are highlighted, which are crucial for low‐temperature CPOM. The effects of the catalyst components and their preparation methods are considered. Their impact on the catalytic performance and stability on the CPOM reaction is evaluated. The two main mechanisms of CPOM, namely, direct partial oxidation and combustion and reforming reaction, are also covered along with the most recent kinetic studies. Finally, the deactivation of the CPOM catalysts is evaluated in terms of coke and carbon deposition along with CO poisoning.
An overview is given on the multifunctional potential of a transition and noble metal catalyst supported on either single support or combined oxide support in the catalytic partial oxidation of methane. The factors influencing the oxidation reaction along with the mechanism and recent kinetic studies are reported. The deactivation of the catalytic partial oxidation of methane catalysts is evaluated. |
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| AbstractList | The multifunctional potential of a transition and noble metal catalyst supported on either a single support or combined oxide support in the catalytic partial oxidation of methane (CPOM) is reviewed. The close interaction and interfacial area between the metal, reducible oxide, and acidic support are highlighted, which are crucial for low‐temperature CPOM. The effects of the catalyst components and their preparation methods are considered. Their impact on the catalytic performance and stability on the CPOM reaction is evaluated. The two main mechanisms of CPOM, namely, direct partial oxidation and combustion and reforming reaction, are also covered along with the most recent kinetic studies. Finally, the deactivation of the CPOM catalysts is evaluated in terms of coke and carbon deposition along with CO poisoning. The multifunctional potential of a transition and noble metal catalyst supported on either a single support or combined oxide support in the catalytic partial oxidation of methane (CPOM) is reviewed. The close interaction and interfacial area between the metal, reducible oxide, and acidic support are highlighted, which are crucial for low‐temperature CPOM. The effects of the catalyst components and their preparation methods are considered. Their impact on the catalytic performance and stability on the CPOM reaction is evaluated. The two main mechanisms of CPOM, namely, direct partial oxidation and combustion and reforming reaction, are also covered along with the most recent kinetic studies. Finally, the deactivation of the CPOM catalysts is evaluated in terms of coke and carbon deposition along with CO poisoning. An overview is given on the multifunctional potential of a transition and noble metal catalyst supported on either single support or combined oxide support in the catalytic partial oxidation of methane. The factors influencing the oxidation reaction along with the mechanism and recent kinetic studies are reported. The deactivation of the catalytic partial oxidation of methane catalysts is evaluated. |
| Author | Osman, Ahmed I. |
| Author_xml | – sequence: 1 givenname: Ahmed I. surname: Osman fullname: Osman, Ahmed I. email: aosmanahmed01@qub.ac.uk organization: Queen's University Belfast, David Keir Building |
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| SubjectTerms | Acidic oxides Carbon monoxide poisoning Catalysts Catalytic hydrogen production Deactivation Hydrogen production Methane Methane partial oxidation Nickel Noble metals Oxidation Oxygen carriers Reforming Stability analysis Zeolite supports |
| Title | Catalytic Hydrogen Production from Methane Partial Oxidation: Mechanism and Kinetic Study |
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