Organocatalytic oxidative dehydrogenation of aromatic amines for the preparation of azobenzenes under mild conditions

(Diacetoxyiodo)benzene used as stoichiometrically and catalytically in the preparation of azobenzenes under mild reaction conditions was developed. The metal-free oxidation systems demonstrated wide substituents tolerance, alkyls, halogens, and several versatile functional groups, such as amino, eth...

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Bibliographic Details
Published in:	Tetrahedron Vol. 68; no. 39; pp. 8358 - 8366
Main Authors:	Ma, Hengchang, Li, Wenfeng, Wang, Jian, Xiao, Guanghai, Gong, Yuan, Qi, Chunxuan, Feng, Yunpeng, Li, Xiufang, Bao, Zhikang, Cao, Wei, Sun, Qiangsheng, Veaceslav, Caraus, Wang, Feng, Lei, Ziqiang
Format:	Journal Article
Language:	English
Published:	OXFORD Elsevier Ltd 30.09.2012 Elsevier
Subjects:	(Diacetoxyiodo)benzene Acceptability Amine aromatic amines Asymmetry Azo Azo compounds benzene Catalysis Catalysts: preparations and properties chemical structure Chemistry Chemistry, Organic Compatibility Dehydrogenation Exact sciences and technology General and physical chemistry Halogens Noncondensed benzenic compounds Organic chemistry Organocatalytic oxidation Physical Sciences Preparations and properties Science & Technology Tetrahedrons Theory of reactions, general kinetics. Catalysis. Nomenclature, chemical documentation, computer chemistry Tolerances Organocatalytic Amine (Diacetoxyiodo)benzene Azo POLYMERS AZO-COMPOUNDS EFFICIENT METHOD O-IODOXYBENZOIC ACID HYPERVALENT IODINE NITRO-COMPOUNDS SYMMETRIC HYDRAZO COMPOUNDS CHEMISTRY DERIVATIVES IBX Diacetoxyiodobenzene Catalytic reaction Acetylenic compound Mild operating conditions Organocatalyst Aniline derivatives Azo compound Dehydrogenation Halogen compound Benzenic compound Oxidation Large scale Chemical synthesis Arylamine Azobenzene Functional group
ISSN:	0040-4020, 1464-5416
Online Access:	Get full text
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