Stability of Filled PDMS Pervaporation Membranes in Bio-Ethanol Recovery from a Real Fermentation Broth
Mixed matrix membranes (MMMs) have shown great potential in pervaporation (PV). As for many novel membrane materials however, lab-scale testing often involves synthetic feed solutions composed of mixed pure components, overlooking the possibly complex interactions and effects caused by the numerous...
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| Vydáno v: | Membranes (Basel) Ročník 13; číslo 11; s. 863 |
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Basel
MDPI AG
01.11.2023
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| ISSN: | 2077-0375, 2077-0375 |
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| Abstract | Mixed matrix membranes (MMMs) have shown great potential in pervaporation (PV). As for many novel membrane materials however, lab-scale testing often involves synthetic feed solutions composed of mixed pure components, overlooking the possibly complex interactions and effects caused by the numerous other components in a real PV feed. This work studies the performance of MMMs with two different types of fillers, a core-shell material consisting of ZIF-8 coated on mesoporous silica and a hollow sphere of silicalite-1, in the PV of a real fermented wheat/hay straw hydrolysate broth for the production of bio-ethanol. All membranes, including a reference unfilled PDMS, show a declining permeability over time. Interestingly, the unfilled PDMS membrane maintains a stable separation factor, whereas the filled PDMS membranes rapidly lose selectivity to levels below that of the reference PDMS membrane. A membrane autopsy using XRD and SEM-EDX revealed an almost complete degradation of the crystalline ZIF-8 in the MMMs. Reference experiments with ZIF-8 nanoparticles in the fermentation broth demonstrated the influence of the broth on the ZIF-8 particles. However, the observed effects from the membrane autopsy could not exactly be replicated, likely due to distinct differences in conditions between the in-situ pervaporation process and the ex-situ reference experiments. These findings raise significant questions regarding the potential applicability of MOF-filled MMMs in real-feed pervaporation processes and, potentially, in harsh condition membrane separations in general. This study clearly confirms the importance of testing membranes in realistic conditions. |
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| AbstractList | Mixed matrix membranes (MMMs) have shown great potential in pervaporation (PV). As for many novel membrane materials however, lab-scale testing often involves synthetic feed solutions composed of mixed pure components, overlooking the possibly complex interactions and effects caused by the numerous other components in a real PV feed. This work studies the performance of MMMs with two different types of fillers, a core-shell material consisting of ZIF-8 coated on mesoporous silica and a hollow sphere of silicalite-1, in the PV of a real fermented wheat/hay straw hydrolysate broth for the production of bio-ethanol. All membranes, including a reference unfilled PDMS, show a declining permeability over time. Interestingly, the unfilled PDMS membrane maintains a stable separation factor, whereas the filled PDMS membranes rapidly lose selectivity to levels below that of the reference PDMS membrane. A membrane autopsy using XRD and SEM-EDX revealed an almost complete degradation of the crystalline ZIF-8 in the MMMs. Reference experiments with ZIF-8 nanoparticles in the fermentation broth demonstrated the influence of the broth on the ZIF-8 particles. However, the observed effects from the membrane autopsy could not exactly be replicated, likely due to distinct differences in conditions between the in-situ pervaporation process and the ex-situ reference experiments. These findings raise significant questions regarding the potential applicability of MOF-filled MMMs in real-feed pervaporation processes and, potentially, in harsh condition membrane separations in general. This study clearly confirms the importance of testing membranes in realistic conditions. Mixed matrix membranes (MMMs) have shown great potential in pervaporation (PV). As for many novel membrane materials however, lab-scale testing often involves synthetic feed solutions composed of mixed pure components, overlooking the possibly complex interactions and effects caused by the numerous other components in a real PV feed. This work studies the performance of MMMs with two different types of fillers, a core-shell material consisting of ZIF-8 coated on mesoporous silica and a hollow sphere of silicalite-1, in the PV of a real fermented wheat/hay straw hydrolysate broth for the production of bio-ethanol. All membranes, including a reference unfilled PDMS, show a declining permeability over time. Interestingly, the unfilled PDMS membrane maintains a stable separation factor, whereas the filled PDMS membranes rapidly lose selectivity to levels below that of the reference PDMS membrane. A membrane autopsy using XRD and SEM-EDX revealed an almost complete degradation of the crystalline ZIF-8 in the MMMs. Reference experiments with ZIF-8 nanoparticles in the fermentation broth demonstrated the influence of the broth on the ZIF-8 particles. However, the observed effects from the membrane autopsy could not exactly be replicated, likely due to distinct differences in conditions between the in-situ pervaporation process and the ex-situ reference experiments. These findings raise significant questions regarding the potential applicability of MOF-filled MMMs in real-feed pervaporation processes and, potentially, in harsh condition membrane separations in general. This study clearly confirms the importance of testing membranes in realistic conditions.Mixed matrix membranes (MMMs) have shown great potential in pervaporation (PV). As for many novel membrane materials however, lab-scale testing often involves synthetic feed solutions composed of mixed pure components, overlooking the possibly complex interactions and effects caused by the numerous other components in a real PV feed. This work studies the performance of MMMs with two different types of fillers, a core-shell material consisting of ZIF-8 coated on mesoporous silica and a hollow sphere of silicalite-1, in the PV of a real fermented wheat/hay straw hydrolysate broth for the production of bio-ethanol. All membranes, including a reference unfilled PDMS, show a declining permeability over time. Interestingly, the unfilled PDMS membrane maintains a stable separation factor, whereas the filled PDMS membranes rapidly lose selectivity to levels below that of the reference PDMS membrane. A membrane autopsy using XRD and SEM-EDX revealed an almost complete degradation of the crystalline ZIF-8 in the MMMs. Reference experiments with ZIF-8 nanoparticles in the fermentation broth demonstrated the influence of the broth on the ZIF-8 particles. However, the observed effects from the membrane autopsy could not exactly be replicated, likely due to distinct differences in conditions between the in-situ pervaporation process and the ex-situ reference experiments. These findings raise significant questions regarding the potential applicability of MOF-filled MMMs in real-feed pervaporation processes and, potentially, in harsh condition membrane separations in general. This study clearly confirms the importance of testing membranes in realistic conditions. |
| Audience | Academic |
| Author | Vankelecom, Ivo F. J. Van Durme, Jim Verplaetse, Alex Naik, Parimal V. Van de Velde, Miet Van Goethem, Cédric |
| Author_xml | – sequence: 1 givenname: Cédric orcidid: 0000-0003-2218-2143 surname: Van Goethem fullname: Van Goethem, Cédric – sequence: 2 givenname: Parimal V. surname: Naik fullname: Naik, Parimal V. – sequence: 3 givenname: Miet surname: Van de Velde fullname: Van de Velde, Miet – sequence: 4 givenname: Jim surname: Van Durme fullname: Van Durme, Jim – sequence: 5 givenname: Alex surname: Verplaetse fullname: Verplaetse, Alex – sequence: 6 givenname: Ivo F. J. orcidid: 0000-0002-0104-9493 surname: Vankelecom fullname: Vankelecom, Ivo F. J. |
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| CitedBy_id | crossref_primary_10_3390_polym16101413 crossref_primary_10_1039_D4CC06508E crossref_primary_10_3390_w17010060 crossref_primary_10_1016_j_seppur_2024_128160 |
| Cites_doi | 10.1002/jctb.2259 10.1039/C6TA04700A 10.1016/j.seppur.2007.12.011 10.1002/anie.201706721 10.1016/j.memsci.2015.12.028 10.1016/j.memsci.2018.06.040 10.1016/j.memsci.2021.119557 10.1016/j.micromeso.2015.11.055 10.1016/j.biortech.2007.01.002 10.1016/j.memsci.2008.02.061 10.1016/j.memsci.2006.07.020 10.1021/acs.macromol.7b01718 10.1016/j.seppur.2019.116263 10.1002/anie.201309534 10.1016/j.memsci.2013.06.036 10.1016/j.apsusc.2012.05.167 10.1021/ar000034b 10.1002/bit.260100610 10.1016/j.biortech.2010.09.092 10.1016/j.memsci.2010.11.005 10.1016/j.memsci.2007.04.007 10.1016/j.memsci.2013.06.025 10.1016/j.memsci.2012.10.050 10.1016/j.progpolymsci.2016.02.003 10.1016/j.micromeso.2012.06.031 10.1016/j.memsci.2017.02.041 10.1016/j.memsci.2003.09.008 10.1016/j.copbio.2011.04.010 10.1039/C4TA04114C 10.1021/ef200111g 10.1038/nature01650 10.1016/S0376-7388(97)00194-4 10.1039/C4TA00316K 10.1016/S0376-7388(00)00667-0 10.1016/j.memlet.2023.100053 10.1016/0376-7388(90)80010-J 10.1002/anie.200700056 10.1002/cctc.201300581 |
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| References | Eddaoudi (ref_19) 2001; 34 Liu (ref_2) 2011; 25 Ong (ref_6) 2016; 57 Li (ref_24) 2020; 236 Naik (ref_34) 2016; 502 Diestel (ref_25) 2012; 164 Li (ref_16) 2014; 2 Cirujano (ref_21) 2017; 56 Chapman (ref_10) 2008; 318 Sanz (ref_30) 2009; 84 Liu (ref_7) 2021; 636 Qureshi (ref_37) 2001; 187 Cardona (ref_3) 2007; 98 Tang (ref_8) 2013; 447 Liu (ref_17) 2013; 446 (ref_1) 2011; 22 Xu (ref_26) 2017; 531 Kruidhof (ref_15) 2006; 284 Wee (ref_35) 2013; 5 Li (ref_9) 2013; 428 Verbeke (ref_31) 2018; 563 Alaerts (ref_22) 2007; 46 Zimmerman (ref_11) 1997; 137 Hu (ref_27) 2023; 3 Bowen (ref_13) 2007; 298 Zhan (ref_14) 2012; 259 Galizia (ref_12) 2017; 50 Chovau (ref_32) 2011; 102 Yaghi (ref_20) 2003; 423 Bengtson (ref_28) 1990; 53 Aiba (ref_4) 1968; 10 Naik (ref_33) 2016; 4 Lipnizki (ref_29) 2004; 228 Offeman (ref_36) 2010; 367 Huang (ref_5) 2008; 62 Fan (ref_23) 2014; 53 Leus (ref_38) 2016; 226 Fan (ref_18) 2014; 2 |
| References_xml | – volume: 84 start-page: 1873 year: 2009 ident: ref_30 article-title: Separation by Pervaporation of Ethanol from Aqueous Solutions and Effect of Other Components Present in Fermentation Broths publication-title: J. Chem. Technol. Biotechnol. doi: 10.1002/jctb.2259 – volume: 4 start-page: 12790 year: 2016 ident: ref_33 article-title: PDMS Membranes Containing ZIF-Coated Mesoporous Silica Spheres for Efficient Ethanol Recovery via Pervaporation publication-title: J. Mater. Chem. A doi: 10.1039/C6TA04700A – volume: 62 start-page: 1 year: 2008 ident: ref_5 article-title: A Review of Separation Technologies in Current and Future Biorefineries publication-title: Sep. Purif. Technol. doi: 10.1016/j.seppur.2007.12.011 – volume: 56 start-page: 13302 year: 2017 ident: ref_21 article-title: Boosting the Catalytic Performance of Metal–Organic Frameworks for Steroid Transformations by Confinement within a Mesoporous Scaffold publication-title: Angew. Chemie Int. Ed. doi: 10.1002/anie.201706721 – volume: 502 start-page: 48 year: 2016 ident: ref_34 article-title: PDMS Mixed Matrix Membranes Containing Hollow Silicalite Sphere for Ethanol/Water Separation by Pervaporation publication-title: J. Memb. Sci. doi: 10.1016/j.memsci.2015.12.028 – volume: 563 start-page: 938 year: 2018 ident: ref_31 article-title: The Role of MOFs in Thin-Film Nanocomposite (TFN) Membranes publication-title: J. Memb. Sci. doi: 10.1016/j.memsci.2018.06.040 – volume: 636 start-page: 119557 year: 2021 ident: ref_7 article-title: Pervaporation Membrane Materials: Recent Trends and Perspectives publication-title: J. Memb. Sci. doi: 10.1016/j.memsci.2021.119557 – volume: 226 start-page: 110 year: 2016 ident: ref_38 article-title: Systematic Study of the Chemical and Hydrothermal Stability of Selected “Stable” Metal Organic Frameworks publication-title: Microporous Mesoporous Mater. doi: 10.1016/j.micromeso.2015.11.055 – volume: 98 start-page: 2415 year: 2007 ident: ref_3 article-title: Fuel Ethanol Production: Process Design Trends and Integration Opportunities publication-title: Bioresour. Technol. doi: 10.1016/j.biortech.2007.01.002 – volume: 318 start-page: 5 year: 2008 ident: ref_10 article-title: Membranes for the Dehydration of Solvents by Pervaporation publication-title: J. Memb. Sci. doi: 10.1016/j.memsci.2008.02.061 – volume: 284 start-page: 128 year: 2006 ident: ref_15 article-title: ZrO2 and TiO2 Membranes for Nanofiltration and Pervaporation: Part 1. Preparation and Characterization of a Corrosion-Resistant ZrO2 Nanofiltration Membrane with a MWCO publication-title: J. Memb. Sci. doi: 10.1016/j.memsci.2006.07.020 – volume: 50 start-page: 7809 year: 2017 ident: ref_12 article-title: 50th Anniversary Perspective: Polymers and Mixed Matrix Membranes for Gas and Vapor Separation: A Review and Prospective Opportunities publication-title: Macromolecules doi: 10.1021/acs.macromol.7b01718 – volume: 236 start-page: 116263 year: 2020 ident: ref_24 article-title: The In-Situ Synthesis of a High-Flux ZIF-8/Polydimethylsiloxane Mixed Matrix Membrane for n-Butanol Pervaporation publication-title: Sep. Purif. Technol. doi: 10.1016/j.seppur.2019.116263 – volume: 53 start-page: 5578 year: 2014 ident: ref_23 article-title: Simultaneous Spray Self-Assembly of Highly Loaded ZIF-8-PDMS Nanohybrid Membranes Exhibiting Exceptionally High Biobutanol-Permselective Pervaporation publication-title: Angew. Chemie Int. Ed. doi: 10.1002/anie.201309534 – volume: 447 start-page: 345 year: 2013 ident: ref_8 article-title: Permeation and Sorption of Organic Solvents and Separation of Their Mixtures through an Amorphous Perfluoropolymer Membrane in Pervaporation publication-title: J. Memb. Sci. doi: 10.1016/j.memsci.2013.06.036 – volume: 259 start-page: 547 year: 2012 ident: ref_14 article-title: Mixed Matrix Membranes with HF Acid Etched ZSM-5 for Ethanol/Water Separation: Preparation and Pervaporation Performance publication-title: Appl. Surf. Sci. doi: 10.1016/j.apsusc.2012.05.167 – volume: 34 start-page: 319 year: 2001 ident: ref_19 article-title: Modular Chemistry: Secondary Building Units as a Basis for the Design of Highly Porous and Robust Metal-Organic Carboxylate Frameworks publication-title: Acc. Chem. Res. doi: 10.1021/ar000034b – volume: 10 start-page: 845 year: 1968 ident: ref_4 article-title: Kinetics of Product Inhibition in Alcohol Fermentation publication-title: Biotechnol. Bioeng. doi: 10.1002/bit.260100610 – volume: 102 start-page: 1669 year: 2011 ident: ref_32 article-title: Influence of Fermentation By-Products on the Purification of Ethanol from Water Using Pervaporation publication-title: Bioresour. Technol. doi: 10.1016/j.biortech.2010.09.092 – volume: 367 start-page: 288 year: 2010 ident: ref_36 article-title: Poisoning of Mixed Matrix Membranes by Fermentation Components in Pervaporation of Ethanol publication-title: J. Memb. Sci. doi: 10.1016/j.memsci.2010.11.005 – volume: 298 start-page: 117 year: 2007 ident: ref_13 article-title: Stability of MFI Zeolite-Filled PDMS Membranes during Pervaporative Ethanol Recovery from Aqueous Mixtures Containing Acetic Acid publication-title: J. Memb. Sci. doi: 10.1016/j.memsci.2007.04.007 – volume: 446 start-page: 181 year: 2013 ident: ref_17 article-title: Hydrophobic-ZIF-71 Filled PEBA Mixed Matrix Membranes for Recovery of Biobutanol via Pervaporation publication-title: J. Memb. Sci. doi: 10.1016/j.memsci.2013.06.025 – volume: 428 start-page: 63 year: 2013 ident: ref_9 article-title: Improving the Flux of PDMS Membranes via Localized Heating through Incorporation of Gold Nanoparticles publication-title: J. Memb. Sci. doi: 10.1016/j.memsci.2012.10.050 – volume: 57 start-page: 1 year: 2016 ident: ref_6 article-title: Recent Membrane Development for Pervaporation Processes publication-title: Prog. Polym. Sci. doi: 10.1016/j.progpolymsci.2016.02.003 – volume: 164 start-page: 288 year: 2012 ident: ref_25 article-title: Pervaporation Studies of N-Hexane, Benzene, Mesitylene and Their Mixtures on Zeolitic Imidazolate Framework-8 Membranes publication-title: Microporous Mesoporous Mater. doi: 10.1016/j.micromeso.2012.06.031 – volume: 531 start-page: 16 year: 2017 ident: ref_26 article-title: High-Performance UiO-66/Polyimide Mixed Matrix Membranes for Ethanol, Isopropanol and n-Butanol Dehydration via Pervaporation publication-title: J. Memb. Sci. doi: 10.1016/j.memsci.2017.02.041 – volume: 228 start-page: 129 year: 2004 ident: ref_29 article-title: Influence of Impermeable Components on the Permeation of Aqueous 1-Propanol Mixtures in Hydrophobic Pervaporation publication-title: Proc. J. Membr. Sci. doi: 10.1016/j.memsci.2003.09.008 – volume: 22 start-page: 331 year: 2011 ident: ref_1 article-title: Fermentative Production of Butanol—The Academic Perspective publication-title: Curr. Opin. Biotechnol. doi: 10.1016/j.copbio.2011.04.010 – volume: 2 start-page: 20947 year: 2014 ident: ref_18 article-title: Nanodisperse ZIF-8/PDMS Hybrid Membranes for Biobutanol Permselective Pervaporation publication-title: J. Mater. Chem. A doi: 10.1039/C4TA04114C – volume: 25 start-page: 1837 year: 2011 ident: ref_2 article-title: Comparison of Ethanol and Butanol as Additives in Soybean Biodiesel Using a Constant Volume Combustion Chamber publication-title: Energy Fuels doi: 10.1021/ef200111g – volume: 423 start-page: 705 year: 2003 ident: ref_20 article-title: Reticular Synthesis and the Design of New Materials publication-title: Nature doi: 10.1038/nature01650 – volume: 137 start-page: 145 year: 1997 ident: ref_11 article-title: Tailoring Mixed Matrix Composite Membranes for Gas Separations publication-title: J. Memb. Sci. doi: 10.1016/S0376-7388(97)00194-4 – volume: 2 start-page: 10034 year: 2014 ident: ref_16 article-title: ZIF-71 as a Potential Filler to Prepare Pervaporation Membranes for Bio-Alcohol Recovery publication-title: J. Mater. Chem. A doi: 10.1039/C4TA00316K – volume: 187 start-page: 93 year: 2001 ident: ref_37 article-title: Acetone Butanol Ethanol (ABE) Recovery by Pervaporation Using Silicalite-Silicone Composite Membrane from Fed-Batch Reactor of Clostridium Acetobutylicum publication-title: J. Memb. Sci. doi: 10.1016/S0376-7388(00)00667-0 – volume: 3 start-page: 100053 year: 2023 ident: ref_27 article-title: Mixed-Linker MOF-303 Membranes for Pervaporation publication-title: J. Membr. Sci. Lett. doi: 10.1016/j.memlet.2023.100053 – volume: 53 start-page: 143 year: 1990 ident: ref_28 article-title: Pervaporation of Low Volatility Aromatics from Water publication-title: J. Memb. Sci. doi: 10.1016/0376-7388(90)80010-J – volume: 46 start-page: 4293 year: 2007 ident: ref_22 article-title: Selective Adsorption and Separation of Xylene Isomers and Ethylbenzene with the Microporous Vanadium(IV) Terephthalate MIL-47 publication-title: Angew. Chemie Int. Ed. doi: 10.1002/anie.200700056 – volume: 5 start-page: 3562 year: 2013 ident: ref_35 article-title: Hierarchical Zeolitic Imidazolate Framework-8 Catalyst for Monoglyceride Synthesis publication-title: ChemCatChem doi: 10.1002/cctc.201300581 |
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| Snippet | Mixed matrix membranes (MMMs) have shown great potential in pervaporation (PV). As for many novel membrane materials however, lab-scale testing often involves... |
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| SubjectTerms | Acids Alcohol Alcohol, Denatured Autopsies Autopsy bio-ethanol Biofuels Chemical properties Dimethylpolysiloxane Ethanol Evaluation Feeds Fermentation Glycerol Hydrolysates Membrane permeability Membranes metal–organic framework Methods MMM Nanoparticles PDMS Pervaporation Polymers Silica Silicalite stability Synthetic feeds |
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| Title | Stability of Filled PDMS Pervaporation Membranes in Bio-Ethanol Recovery from a Real Fermentation Broth |
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