A thermal self-healing polyurethane thermoset based on phenolic urethane

Thermosetting polyurethanes have excellent elastic properties and solvent resistance, but they cannot be reshaped like thermoplastic polymers after molding. In this study, we designed a thermosetting polyurethane based on a reversible reaction between isocyanates and phenolic hydroxyls instead of al...

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Published in:	Polymer journal Vol. 49; no. 11; pp. 775 - 781
Main Authors:	Cao, Shan, Li, Shouhai, Li, Mei, Xu, Lina, Ding, Haiyang, Xia, Jianling, Zhang, Meng, Huang, Kun
Format:	Journal Article
Language:	English
Published:	London Nature Publishing Group UK 01.11.2017 Nature Publishing Group
Subjects:	639/638/298/303 639/638/455/941 Adhesive bonding Biomaterials Bioorganic Chemistry Bond strength Chemistry Chemistry and Materials Science Chemistry/Food Science Coatings Cooling Corrosion resistance Decomposition Elastic properties Elastomers Elongation Isocyanates original-article Polymer Sciences Polyurethane Polyurethane resins Repair Self healing materials Surfaces and Interfaces Tensile strength Thermosetting resins Thin Films
ISSN:	0032-3896, 1349-0540
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Abstract	Thermosetting polyurethanes have excellent elastic properties and solvent resistance, but they cannot be reshaped like thermoplastic polymers after molding. In this study, we designed a thermosetting polyurethane based on a reversible reaction between isocyanates and phenolic hydroxyls instead of alcoholic hydroxyls. The phenolic urethane partially decomposed above 120 °C, but the phenolic hydroxyl and isocyanate groups reconnected upon cooling. These reversible urethane bonds contributed to the thermal self-repair of the thermosetting polyurethane network. This thermosetting elastomer was organic-insoluble below 120 °C. Compared to the original material, the healed thermoset preserved approximately 70% of its tensile strength and exhibited 86% elongation at break. This thermosetting polyurethane can be applied in self-healing coatings or adhesives. We designed a thermosetting polyurethane based on the reversible reaction between isocyanates and phenolic hydroxyls instead of alcoholic hydroxyls. The phenolic urethane partially decomposed at above 120 °C, but the phenolic hydroxyl and isocyanate reconnected upon cooling. This reversible urethane bond contributed to the thermal self-repair of the thermosetting polyurethane network and can be applied into self-healing coatings or adhesives.
AbstractList	Thermosetting polyurethanes have excellent elastic properties and solvent resistance, but they cannot be reshaped like thermoplastic polymers after molding. In this study, we designed a thermosetting polyurethane based on a reversible reaction between isocyanates and phenolic hydroxyls instead of alcoholic hydroxyls. The phenolic urethane partially decomposed above 120 °C, but the phenolic hydroxyl and isocyanate groups reconnected upon cooling. These reversible urethane bonds contributed to the thermal self-repair of the thermosetting polyurethane network. This thermosetting elastomer was organic-insoluble below 120 °C. Compared to the original material, the healed thermoset preserved approximately 70% of its tensile strength and exhibited 86% elongation at break. This thermosetting polyurethane can be applied in self-healing coatings or adhesives. Thermosetting polyurethanes have excellent elastic properties and solvent resistance, but they cannot be reshaped like thermoplastic polymers after molding. In this study, we designed a thermosetting polyurethane based on a reversible reaction between isocyanates and phenolic hydroxyls instead of alcoholic hydroxyls. The phenolic urethane partially decomposed above 120 °C, but the phenolic hydroxyl and isocyanate groups reconnected upon cooling. These reversible urethane bonds contributed to the thermal self-repair of the thermosetting polyurethane network. This thermosetting elastomer was organic-insoluble below 120 °C. Compared to the original material, the healed thermoset preserved approximately 70% of its tensile strength and exhibited 86% elongation at break. This thermosetting polyurethane can be applied in self-healing coatings or adhesives.We designed a thermosetting polyurethane based on the reversible reaction between isocyanates and phenolic hydroxyls instead of alcoholic hydroxyls. The phenolic urethane partially decomposed at above 120 °C, but the phenolic hydroxyl and isocyanate reconnected upon cooling. This reversible urethane bond contributed to the thermal self-repair of the thermosetting polyurethane network and can be applied into self-healing coatings or adhesives. Thermosetting polyurethanes have excellent elastic properties and solvent resistance, but they cannot be reshaped like thermoplastic polymers after molding. In this study, we designed a thermosetting polyurethane based on a reversible reaction between isocyanates and phenolic hydroxyls instead of alcoholic hydroxyls. The phenolic urethane partially decomposed above 120 °C, but the phenolic hydroxyl and isocyanate groups reconnected upon cooling. These reversible urethane bonds contributed to the thermal self-repair of the thermosetting polyurethane network. This thermosetting elastomer was organic-insoluble below 120 °C. Compared to the original material, the healed thermoset preserved approximately 70% of its tensile strength and exhibited 86% elongation at break. This thermosetting polyurethane can be applied in self-healing coatings or adhesives. We designed a thermosetting polyurethane based on the reversible reaction between isocyanates and phenolic hydroxyls instead of alcoholic hydroxyls. The phenolic urethane partially decomposed at above 120 °C, but the phenolic hydroxyl and isocyanate reconnected upon cooling. This reversible urethane bond contributed to the thermal self-repair of the thermosetting polyurethane network and can be applied into self-healing coatings or adhesives.
Author	Li, Mei Ding, Haiyang Cao, Shan Li, Shouhai Zhang, Meng Xu, Lina Xia, Jianling Huang, Kun
Author_xml	– sequence: 1 givenname: Shan surname: Cao fullname: Cao, Shan organization: Institute of Chemical Industry of Forestry Products, CAF; Institute of Forest New Technology, CAF; National Engineering Lab for Biomass Chemical Utilization; Key Lab on Forest Chemical Engineering, SFA; Key Lab of Biomass Energy and Material, Institute of Forest New Technology, CAF – sequence: 2 givenname: Shouhai surname: Li fullname: Li, Shouhai organization: Institute of Chemical Industry of Forestry Products, CAF; Institute of Forest New Technology, CAF; National Engineering Lab for Biomass Chemical Utilization; Key Lab on Forest Chemical Engineering, SFA; Key Lab of Biomass Energy and Material, Institute of Forest New Technology, CAF – sequence: 3 givenname: Mei surname: Li fullname: Li, Mei organization: Institute of Chemical Industry of Forestry Products, CAF; Institute of Forest New Technology, CAF; National Engineering Lab for Biomass Chemical Utilization; Key Lab on Forest Chemical Engineering, SFA; Key Lab of Biomass Energy and Material, Institute of Forest New Technology, CAF – sequence: 4 givenname: Lina surname: Xu fullname: Xu, Lina organization: Institute of Chemical Industry of Forestry Products, CAF; Institute of Forest New Technology, CAF; National Engineering Lab for Biomass Chemical Utilization; Key Lab on Forest Chemical Engineering, SFA; Key Lab of Biomass Energy and Material, Institute of Forest New Technology, CAF – sequence: 5 givenname: Haiyang surname: Ding fullname: Ding, Haiyang organization: Institute of Chemical Industry of Forestry Products, CAF; Institute of Forest New Technology, CAF; National Engineering Lab for Biomass Chemical Utilization; Key Lab on Forest Chemical Engineering, SFA; Key Lab of Biomass Energy and Material, Institute of Forest New Technology, CAF – sequence: 6 givenname: Jianling surname: Xia fullname: Xia, Jianling organization: Institute of Chemical Industry of Forestry Products, CAF; Institute of Forest New Technology, CAF; National Engineering Lab for Biomass Chemical Utilization; Key Lab on Forest Chemical Engineering, SFA; Key Lab of Biomass Energy and Material, Institute of Forest New Technology, CAF – sequence: 7 givenname: Meng surname: Zhang fullname: Zhang, Meng organization: Institute of Chemical Industry of Forestry Products, CAF; Institute of Forest New Technology, CAF; National Engineering Lab for Biomass Chemical Utilization; Key Lab on Forest Chemical Engineering, SFA; Key Lab of Biomass Energy and Material, Institute of Forest New Technology, CAF – sequence: 8 givenname: Kun surname: Huang fullname: Huang, Kun email: maotsedong@163.com organization: Institute of Chemical Industry of Forestry Products, CAF; Institute of Forest New Technology, CAF; National Engineering Lab for Biomass Chemical Utilization; Key Lab on Forest Chemical Engineering, SFA; Key Lab of Biomass Energy and Material, Institute of Forest New Technology, CAF
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Snippet	Thermosetting polyurethanes have excellent elastic properties and solvent resistance, but they cannot be reshaped like thermoplastic polymers after molding. In...
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SubjectTerms	639/638/298/303 639/638/455/941 Adhesive bonding Biomaterials Bioorganic Chemistry Bond strength Chemistry Chemistry and Materials Science Chemistry/Food Science Coatings Cooling Corrosion resistance Decomposition Elastic properties Elastomers Elongation Isocyanates original-article Polymer Sciences Polyurethane Polyurethane resins Repair Self healing materials Surfaces and Interfaces Tensile strength Thermosetting resins Thin Films
Title	A thermal self-healing polyurethane thermoset based on phenolic urethane
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