Intrinsic Catalytic Activity versus Effective Light Usage--A Reply to Professor Kisch's Comments

Breaking the impasse: Earlier this year Maschmeyer and Che outlined an approach for normalizing and comparing the apparent quantum yields (AQY) for hydrogen photogeneration catalyzed by semiconductor powders. In the plot of photocatalyst concentration versus AQY they proposed that the linear region...

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Published in:Angewandte Chemie (International ed.) Vol. 49; no. 50; pp. 9590 - 9591
Main Authors: Maschmeyer, Thomas, Che, Michel
Format: Journal Article
Language:English
Published: Weinheim Wiley-VCH Verlag 10.12.2010
WILEY-VCH Verlag
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ISSN:1433-7851, 1521-3773
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Abstract Breaking the impasse: Earlier this year Maschmeyer and Che outlined an approach for normalizing and comparing the apparent quantum yields (AQY) for hydrogen photogeneration catalyzed by semiconductor powders. In the plot of photocatalyst concentration versus AQY they proposed that the linear region was the most appropriate region for comparison. In his Correspondence Kisch refutes this proposal and states that the area at the onset of the plateau region (B) in a plot of catalyst concentration versus reaction rate is relevant. Maschmeyer and Che explain their rationale and conclude that the discussion has arisen because of different emphases in studying photocatalysis.
AbstractList Breaking the impasse: Earlier this year Maschmeyer and Che outlined an approach for normalizing and comparing the apparent quantum yields (AQY) for hydrogen photogeneration catalyzed by semiconductor powders. In the plot of photocatalyst concentration versus AQY they proposed that the linear region was the most appropriate region for comparison. In his Correspondence Kisch refutes this proposal and states that the area at the onset of the plateau region (B) in a plot of catalyst concentration versus reaction rate is relevant. Maschmeyer and Che explain their rationale and conclude that the discussion has arisen because of different emphases in studying photocatalysis.
Author Maschmeyer, Thomas
Che, Michel
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Cites_doi 10.1002/anie.200903921
10.1351/pac199971020321
10.1021/ie901753k
10.1002/ange.200903921
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References T. Maschmeyer, M. Che, Angew. Chem. 2010, 122, 1578
A. Salinaro, A. V. Emeline, J. C. Zhao, H. Hidaka, V. K. Ryabchuk, N. Serpone, Pure Appl. Chem. 1999, 71, 321.
G. Sagawe, M. L. Satuf, R. J. Brandi, J. P. Muschner, C. Federer, O. M. Alfano, D. Bahnemann and A. E. Cassano, Ind. Eng. Chem. Res. 2010, 49, 6898.
Angew. Chem. Int. Ed. 2010, 49, 1536.
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Snippet Breaking the impasse: Earlier this year Maschmeyer and Che outlined an approach for normalizing and comparing the apparent quantum yields (AQY) for hydrogen...
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SubjectTerms hydrogen
photocatalysis
quantum yields
semiconductors
Title Intrinsic Catalytic Activity versus Effective Light Usage--A Reply to Professor Kisch's Comments
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