Investigation of terpinolene + ozone or terpinolene + nitrate radical reaction products using denuder/filter apparatus

Terpinolene's (1-methyl-4-(propan-2-ylidene)cyclohexene) reaction with ozone or the nitrate radical was investigated using a denuder/filter apparatus in order to characterize gas-phase and particulate reaction products. Identification of the reaction products (i.e., aldehydes, ketones, dicarbon...

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Vydáno v:	Atmospheric environment (1994) Ročník 80; s. 524 - 532
Hlavní autoři:	Harrison, Joel C., Wells, J.R.
Médium:	Journal Article
Jazyk:	angličtina
Vydáno:	Kidlington Elsevier Ltd 01.12.2013 Elsevier
Témata:	aldehydes Applied sciences atmospheric chemistry Atmospheric pollution Buildings. Public works carboxylic acids cyclohexenes Denuder derivatization Exact sciences and technology Indoor pollution and occupational exposure ketones Nitrate radical nitrates Oxygenated organic compounds Ozone ozonolysis Pollution Pollution indoor buildings Reaction products terpinolene Reaction products Oxygenated organic compounds Ozone Nitrate radical Denuder Terpenoid Photochemical oxidants Chemical analysis Hydrocarbon Pollutant behavior Reaction product Volatile organic compound Nitrates Precursor Terpene Indoor pollution Monoterpene Qualitative analysis Oxidation Organic compounds Inorganic radical anion
ISSN:	1352-2310, 1873-2844
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Abstract	Terpinolene's (1-methyl-4-(propan-2-ylidene)cyclohexene) reaction with ozone or the nitrate radical was investigated using a denuder/filter apparatus in order to characterize gas-phase and particulate reaction products. Identification of the reaction products (i.e., aldehydes, ketones, dicarbonyls and carboxylic acids) was made using two derivatization methods; O-(2,3,4,5,6-pentafluorobenzyl)hydroxylamine (PFBHA) to derivatize the carbonyl products or 3-Ethyl-1-[3-(dimethylamino)propyl]carbodiimide hydrochloride (EDC) and 2,2,2-trifluoroethylamine hydrochloride (TFEA) to derivatize the carboxylic acid products. Proposed carbonyl products for ozonolysis of terpinolene are: 4-methylcyclohex-3-en-1-one, 2-hydroxy-4-methylcyclohex-3-en-1-one, glyoxal, methyl glyoxal, 3-oxobutanal, and 6-oxo-3-(propan-2-ylidene)heptanal. Proposed carbonyl products for nitrate radical reaction of terpinolene are: 2-hydroxy-4-methylcyclohex-3-en-1-one, glyoxal, methyl glyoxal, and 4-oxopentanal. No carboxylic acid products were detected with either oxidizing reactant. •Determined and contrasted the products of the reaction of terpinolene with ozone or nitrate radical.•Products captured using a denuder/filter apparatus.•Reaction products identified using a dual derivatization method.
AbstractList	Terpinolene's (1-methyl-4-(propan-2-ylidene)cyclohexene) reaction with ozone or the nitrate radical was investigated using a denuder/filter apparatus in order to characterize gas-phase and particulate reaction products. Identification of the reaction products (i.e., aldehydes, ketones, dicarbonyls and carboxylic acids) was made using two derivatization methods; O-(2,3,4,5,6-pentafluorobenzyl)hydroxylamine (PFBHA) to derivatize the carbonyl products or 3-Ethyl-1-[3-(dimethylamino)propyl]carbodiimide hydrochloride (EDC) and 2,2,2-trifluoroethylamine hydrochloride (TFEA) to derivatize the carboxylic acid products. Proposed carbonyl products for ozonolysis of terpinolene are: 4-methylcyclohex-3-en-1-one, 2-hydroxy-4-methylcyclohex-3-en-1-one, glyoxal, methyl glyoxal, 3-oxobutanal, and 6-oxo-3-(propan-2-ylidene)heptanal. Proposed carbonyl products for nitrate radical reaction of terpinolene are: 2-hydroxy-4-methylcyclohex-3-en-1-one, glyoxal, methyl glyoxal, and 4-oxopentanal. No carboxylic acid products were detected with either oxidizing reactant. •Determined and contrasted the products of the reaction of terpinolene with ozone or nitrate radical.•Products captured using a denuder/filter apparatus.•Reaction products identified using a dual derivatization method. Terpinolene’s (1-methyl-4-(propan-2-ylidene)cyclohexene) reaction with ozone or the nitrate radical was investigated using a denuder/filter apparatus in order to characterize gas-phase and particulate reaction products. Identification of the reaction products (i.e., aldehydes, ketones, dicarbonyls and carboxylic acids) was made using two derivatization methods; O-(2,3,4,5,6-pentafluorobenzyl)hydroxylamine (PFBHA) to derivatize the carbonyl products or 3-Ethyl-1-[3-(dimethylamino)propyl]carbodiimide hydrochloride (EDC) and 2,2,2-trifluoroethylamine hydrochloride (TFEA) to derivatize the carboxylic acid products. Proposed carbonyl products for ozonolysis of terpinolene are: 4-methylcyclohex-3-en-1-one, 2-hydroxy-4-methylcyclohex-3-en-1-one, glyoxal, methyl glyoxal, 3-oxobutanal, and 6-oxo-3-(propan-2-ylidene)heptanal. Proposed carbonyl products for nitrate radical reaction of terpinolene are: 2-hydroxy-4-methylcyclohex-3-en-1-one, glyoxal, methyl glyoxal, and 4-oxopentanal. No carboxylic acid products were detected with either oxidizing reactant. Terpinolene's (1-methyl-4-(propan-2-ylidene)cyclohexene) reaction with ozone or the nitrate radical was investigated using a denuder/filter apparatus in order to characterize gas-phase and particulate reaction products. Identification of the reaction products (i.e., aldehydes, ketones, dicarbonyls and carboxylic acids) was made using two derivatization methods; -(2,3,4,5,6-pentafluorobenzyl)hydroxylamine (PFBHA) to derivatize the carbonyl products or 3-Ethyl-1-[3-(dimethylamino)propyl]carbodiimide hydrochloride (EDC) and 2,2,2-trifluoroethylamine hydrochloride (TFEA) to derivatize the carboxylic acid products. Proposed carbonyl products for ozonolysis of terpinolene are: 4-methylcyclohex-3-en-1-one, 2-hydroxy-4-methylcyclohex-3-en-1-one, glyoxal, methyl glyoxal, 3-oxobutanal, and 6-oxo-3-(propan-2-ylidene)heptanal. Proposed carbonyl products for nitrate radical reaction of terpinolene are: 2-hydroxy-4-methylcyclohex-3-en-1-one, glyoxal, methyl glyoxal, and 4-oxopentanal. No carboxylic acid products were detected with either oxidizing reactant. Terpinolene's (1-methyl-4-(propan-2-ylidene)cyclohexene) reaction with ozone or the nitrate radical was investigated using a denuder/filter apparatus in order to characterize gas-phase and particulate reaction products. Identification of the reaction products (i.e., aldehydes, ketones, dicarbonyls and carboxylic acids) was made using two derivatization methods; O-(2,3,4,5,6-pentafluorobenzyl)hydroxylamine (PFBHA) to derivatize the carbonyl products or 3-Ethyl-1-[3-(dimethylamino)propyl]carbodiimide hydrochloride (EDC) and 2,2,2-trifluoroethylamine hydrochloride (TFEA) to derivatize the carboxylic acid products. Proposed carbonyl products for ozonolysis of terpinolene are: 4-methylcyclohex-3-en-1-one, 2-hydroxy-4-methylcyclohex-3-en-1-one, glyoxal, methyl glyoxal, 3-oxobutanal, and 6-oxo-3-(propan-2-ylidene)heptanal. Proposed carbonyl products for nitrate radical reaction of terpinolene are: 2-hydroxy-4-methylcyclohex-3-en-1-one, glyoxal, methyl glyoxal, and 4-oxopentanal. No carboxylic acid products were detected with either oxidizing reactant.Terpinolene's (1-methyl-4-(propan-2-ylidene)cyclohexene) reaction with ozone or the nitrate radical was investigated using a denuder/filter apparatus in order to characterize gas-phase and particulate reaction products. Identification of the reaction products (i.e., aldehydes, ketones, dicarbonyls and carboxylic acids) was made using two derivatization methods; O-(2,3,4,5,6-pentafluorobenzyl)hydroxylamine (PFBHA) to derivatize the carbonyl products or 3-Ethyl-1-[3-(dimethylamino)propyl]carbodiimide hydrochloride (EDC) and 2,2,2-trifluoroethylamine hydrochloride (TFEA) to derivatize the carboxylic acid products. Proposed carbonyl products for ozonolysis of terpinolene are: 4-methylcyclohex-3-en-1-one, 2-hydroxy-4-methylcyclohex-3-en-1-one, glyoxal, methyl glyoxal, 3-oxobutanal, and 6-oxo-3-(propan-2-ylidene)heptanal. Proposed carbonyl products for nitrate radical reaction of terpinolene are: 2-hydroxy-4-methylcyclohex-3-en-1-one, glyoxal, methyl glyoxal, and 4-oxopentanal. No carboxylic acid products were detected with either oxidizing reactant.
Author	Harrison, Joel C. Wells, J.R.
Author_xml	– sequence: 1 givenname: Joel C. surname: Harrison fullname: Harrison, Joel C. – sequence: 2 givenname: J.R. surname: Wells fullname: Wells, J.R. email: ozw0@cdc.gov, rwells@cdc.gov
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Cites_doi	10.1021/es980129x 10.1021/j100323a028 10.1021/cr0206420 10.1007/BF00694375 10.1016/j.atmosenv.2005.09.093 10.1002/ajim.20800 10.1016/j.atmosenv.2013.01.036 10.1016/j.atmosenv.2007.01.042 10.1016/j.atmosenv.2010.05.011 10.1016/j.atmosenv.2004.02.040 10.1016/S1352-2310(02)00355-2 10.1021/es960958n 10.1016/j.chroma.2007.01.096 10.1093/occmed/kqq192 10.1111/j.1600-0668.2005.00414.x 10.1023/B:JOCH.0000044420.94492.fa 10.1021/es00043a010 10.1039/c2em10799f 10.1039/b818789d 10.1111/j.1600-0536.2009.01647.x 10.1029/1999JD900198
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Keywords	Reaction products Oxygenated organic compounds Ozone Nitrate radical Denuder Terpenoid Photochemical oxidants Chemical analysis Hydrocarbon Pollutant behavior Reaction product Volatile organic compound Nitrates Precursor Terpene Indoor pollution Monoterpene Qualitative analysis Oxidation Organic compounds Inorganic radical anion
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References	Sarwar, Corsi, Allen, Weschler (bib19) 2002 McHugh, Symanski, Pompeii, Delclos (bib14) 2010; 53 Spittler, Barnes, Bejan, Brockmann, Benter, Wirtz (bib21) 2006; 40 Nazaroff, Weschler (bib16) 2004; 38 EPA (bib6) 2000 Wangberg, Barnes, Becker (bib23) 1997; 31 Harrison, Ham, Wells (bib9) 2007; 41 Yu, Flagan, Seinfeld (bib26) 1998; 32 Ford, Burns, Ferry (bib7) 2007; 1145 Atkinson, Aschmann, Pitts (bib3) 1988; 92 Wells (bib24) 2012; 14 Hakola, Arey, Aschmann, Atkinson (bib8) 1994; 18 Reissell, Harry, Aschmann, Atkinson, Arey (bib18) 1999; 104 Makela, Kauppi, Suuronen, Tuppurainen, Hannu (bib13) 2011; 61 Aschmann, Arey, Atkinson (bib1) 2002; 36 Stewart, Almabrok, Lockhart, Mohamed, Nutt, Pfrang, Marston (bib22) 2013; 70 Quirce, Barranco (bib17) 2010; 20 Dungworth, Clarke, Plata (bib5) 1969; 99 Baker, Arey, Atkinson (bib4) 2004; 48 Singer, Destaillats, Hodgson, Nazaroff (bib20) 2006; 16 Ma, Marston (bib11) 2009; 11 Atkinson, Arey (bib2) 2003; 103 Magnano, Silvani, Vincenzi, Nino, Tosti (bib12) 2009; 61 Herrmann, Winterhalter, Moortgat, Williams (bib10) 2010; 44 Muthuramu, Shepson, Obrien (bib15) 1993; 27 Wilson, Colome, Tian, Becker, Baker, Behrens, Billick, Garrison (bib25) 1996; 6 Quirce (10.1016/j.atmosenv.2013.08.032_bib17) 2010; 20 Reissell (10.1016/j.atmosenv.2013.08.032_bib18) 1999; 104 Makela (10.1016/j.atmosenv.2013.08.032_bib13) 2011; 61 Nazaroff (10.1016/j.atmosenv.2013.08.032_bib16) 2004; 38 Dungworth (10.1016/j.atmosenv.2013.08.032_bib5) 1969; 99 Sarwar (10.1016/j.atmosenv.2013.08.032_bib19) 2002 Aschmann (10.1016/j.atmosenv.2013.08.032_bib1) 2002; 36 Herrmann (10.1016/j.atmosenv.2013.08.032_bib10) 2010; 44 Yu (10.1016/j.atmosenv.2013.08.032_bib26) 1998; 32 Baker (10.1016/j.atmosenv.2013.08.032_bib4) 2004; 48 EPA (10.1016/j.atmosenv.2013.08.032_bib6) 2000 Singer (10.1016/j.atmosenv.2013.08.032_bib20) 2006; 16 Wilson (10.1016/j.atmosenv.2013.08.032_bib25) 1996; 6 McHugh (10.1016/j.atmosenv.2013.08.032_bib14) 2010; 53 Ma (10.1016/j.atmosenv.2013.08.032_bib11) 2009; 11 Muthuramu (10.1016/j.atmosenv.2013.08.032_bib15) 1993; 27 Magnano (10.1016/j.atmosenv.2013.08.032_bib12) 2009; 61 Ford (10.1016/j.atmosenv.2013.08.032_bib7) 2007; 1145 Hakola (10.1016/j.atmosenv.2013.08.032_bib8) 1994; 18 Harrison (10.1016/j.atmosenv.2013.08.032_bib9) 2007; 41 Wells (10.1016/j.atmosenv.2013.08.032_bib24) 2012; 14 Atkinson (10.1016/j.atmosenv.2013.08.032_bib2) 2003; 103 Spittler (10.1016/j.atmosenv.2013.08.032_bib21) 2006; 40 Stewart (10.1016/j.atmosenv.2013.08.032_bib22) 2013; 70 Wangberg (10.1016/j.atmosenv.2013.08.032_bib23) 1997; 31 Atkinson (10.1016/j.atmosenv.2013.08.032_bib3) 1988; 92
References_xml	– volume: 61 start-page: 121 year: 2011 end-page: 126 ident: bib13 article-title: Occupational asthma in professional cleaning work: a clinical study publication-title: Occup. Med. Oxf. – volume: 41 start-page: 4482 year: 2007 end-page: 4491 ident: bib9 article-title: Citronellal reactions with ozone and OH radical: rate constants and gas-phase products detected using PFBHA derivatization publication-title: Atmos. Environ. – volume: 20 start-page: 542 year: 2010 end-page: 550 ident: bib17 article-title: Cleaning agents and asthma publication-title: J. Investig. Allergol. Clin. Immunol. – volume: 38 start-page: 2841 year: 2004 end-page: 2865 ident: bib16 article-title: Cleaning products and air fresheners: exposure to primary and secondary air pollutants publication-title: Atmos. Environ. – volume: 92 start-page: 3454 year: 1988 end-page: 3457 ident: bib3 article-title: Rate constants for the gas-phase reactions of the NO publication-title: J. Phys. Chem. – volume: 36 start-page: 4347 year: 2002 end-page: 4355 ident: bib1 article-title: OH radical formation from the gas-phase reactions of O-3 with a series of terpenes publication-title: Atmos. Environ. – volume: 14 start-page: 1044 year: 2012 end-page: 1054 ident: bib24 article-title: Use of denuder/filter apparatus to investigate terpene ozonolysis publication-title: J. Environ. Monit. – volume: 103 start-page: 4605 year: 2003 end-page: 4638 ident: bib2 article-title: Atmospheric degradation of volatile organic compounds publication-title: Chem. Rev. – volume: 99 start-page: 565 year: 1969 end-page: 574 ident: bib5 article-title: Pulmonary lesions produced in a A-strain mice by long-term exposure to peroxyacetyl nitrate publication-title: Am. Rev. Respir. Dis. – start-page: 80 year: 2002 end-page: 85 ident: bib19 article-title: Production and levels of selected indoor radicals: a modeling assessment publication-title: Indoor Air 2002, Monterey, CA – volume: 16 start-page: 179 year: 2006 end-page: 191 ident: bib20 article-title: Cleaning products and air fresheners: emissions and resulting concentrations of glycol ethers and terpenoids publication-title: Indoor Air – volume: 44 start-page: 3458 year: 2010 end-page: 3464 ident: bib10 article-title: Hydroxyl radical (OH) yields from the ozonolysis of both double bonds for five monoterpenes publication-title: Atmos. Environ. – volume: 1145 start-page: 241 year: 2007 end-page: 245 ident: bib7 article-title: Aqueous in situ derivatization of carboxylic acids by an ionic carbodiimide and 2,2,2-trifluoroethylamine for electron-capture detection publication-title: J. Chromatogr. A – volume: 31 start-page: 2130 year: 1997 end-page: 2135 ident: bib23 article-title: Product and mechanistic study of the reaction of NO publication-title: Environ. Sci. Technol. – volume: 32 start-page: 2357 year: 1998 end-page: 2370 ident: bib26 article-title: Identification of products containing –COOH, –OH, and –C publication-title: Environ. Sci. Technol. – volume: 70 start-page: 227 year: 2013 end-page: 235 ident: bib22 article-title: The kinetics of the gas-phase reactions of selected monoterpenes and cyclo-alkenes with ozone and the NO publication-title: Atmos. Environ. – volume: 48 start-page: 241 year: 2004 end-page: 260 ident: bib4 article-title: Kinetics of the gas-phase reactions of OH radicals, NO publication-title: J. Atmos. Chem. – volume: 61 start-page: 337 year: 2009 end-page: 341 ident: bib12 article-title: Contact allergens and irritants in household washing and cleaning products publication-title: Contact Derm. – volume: 104 start-page: 13869 year: 1999 end-page: 13879 ident: bib18 article-title: Formation of acetone from the OH radical- and O-3-initiated reactions of a series of monoterpenes publication-title: J. Geophys. Res. Atmos. – volume: 40 start-page: S116 year: 2006 end-page: S127 ident: bib21 article-title: Reaction of NO publication-title: Atmos. Environ. – year: 2000 ident: bib6 article-title: AOPWIN v1.91 – volume: 27 start-page: 1117 year: 1993 end-page: 1124 ident: bib15 article-title: Preparation, analysis, and atmospheric production of multifunctional organic nitrates publication-title: Environ. Sci. Technol. – volume: 11 start-page: 4198 year: 2009 end-page: 4209 ident: bib11 article-title: Formation of organic acids from the gas-phase ozonolysis of terpinolene publication-title: Phys. Chem. Chem. Phys. – volume: 6 start-page: 311 year: 1996 end-page: 326 ident: bib25 article-title: California residential air exchange rates and residence volumes publication-title: J. Expos. Anal. Environ. Epidemiol. – volume: 53 start-page: 463 year: 2010 end-page: 475 ident: bib14 article-title: Prevalence of asthma by industry and occupation in the US working population publication-title: Am. J. Ind. Med. – volume: 18 start-page: 75 year: 1994 end-page: 102 ident: bib8 article-title: Product formation from the gas-phase reactions of OH radicals and O publication-title: J. Atmos. Chem. – start-page: 80 year: 2002 ident: 10.1016/j.atmosenv.2013.08.032_bib19 article-title: Production and levels of selected indoor radicals: a modeling assessment – volume: 32 start-page: 2357 year: 1998 ident: 10.1016/j.atmosenv.2013.08.032_bib26 article-title: Identification of products containing –COOH, –OH, and –CO in atmospheric oxidation of hydrocarbons publication-title: Environ. Sci. Technol. doi: 10.1021/es980129x – volume: 92 start-page: 3454 year: 1988 ident: 10.1016/j.atmosenv.2013.08.032_bib3 article-title: Rate constants for the gas-phase reactions of the NO3 radical with a series of organic compounds at 296 ± 2K publication-title: J. Phys. Chem. doi: 10.1021/j100323a028 – volume: 103 start-page: 4605 year: 2003 ident: 10.1016/j.atmosenv.2013.08.032_bib2 article-title: Atmospheric degradation of volatile organic compounds publication-title: Chem. Rev. doi: 10.1021/cr0206420 – volume: 18 start-page: 75 year: 1994 ident: 10.1016/j.atmosenv.2013.08.032_bib8 article-title: Product formation from the gas-phase reactions of OH radicals and O3 with a series of monoterpenes publication-title: J. Atmos. Chem. doi: 10.1007/BF00694375 – volume: 40 start-page: S116 year: 2006 ident: 10.1016/j.atmosenv.2013.08.032_bib21 article-title: Reaction of NO3 radicals with limonene and α-pinene: product and SOA formation publication-title: Atmos. Environ. doi: 10.1016/j.atmosenv.2005.09.093 – volume: 53 start-page: 463 year: 2010 ident: 10.1016/j.atmosenv.2013.08.032_bib14 article-title: Prevalence of asthma by industry and occupation in the US working population publication-title: Am. J. Ind. Med. doi: 10.1002/ajim.20800 – volume: 70 start-page: 227 year: 2013 ident: 10.1016/j.atmosenv.2013.08.032_bib22 article-title: The kinetics of the gas-phase reactions of selected monoterpenes and cyclo-alkenes with ozone and the NO3 radical publication-title: Atmos. Environ. doi: 10.1016/j.atmosenv.2013.01.036 – volume: 41 start-page: 4482 year: 2007 ident: 10.1016/j.atmosenv.2013.08.032_bib9 article-title: Citronellal reactions with ozone and OH radical: rate constants and gas-phase products detected using PFBHA derivatization publication-title: Atmos. Environ. doi: 10.1016/j.atmosenv.2007.01.042 – volume: 44 start-page: 3458 year: 2010 ident: 10.1016/j.atmosenv.2013.08.032_bib10 article-title: Hydroxyl radical (OH) yields from the ozonolysis of both double bonds for five monoterpenes publication-title: Atmos. Environ. doi: 10.1016/j.atmosenv.2010.05.011 – volume: 38 start-page: 2841 year: 2004 ident: 10.1016/j.atmosenv.2013.08.032_bib16 article-title: Cleaning products and air fresheners: exposure to primary and secondary air pollutants publication-title: Atmos. Environ. doi: 10.1016/j.atmosenv.2004.02.040 – year: 2000 ident: 10.1016/j.atmosenv.2013.08.032_bib6 – volume: 36 start-page: 4347 year: 2002 ident: 10.1016/j.atmosenv.2013.08.032_bib1 article-title: OH radical formation from the gas-phase reactions of O-3 with a series of terpenes publication-title: Atmos. Environ. doi: 10.1016/S1352-2310(02)00355-2 – volume: 31 start-page: 2130 year: 1997 ident: 10.1016/j.atmosenv.2013.08.032_bib23 article-title: Product and mechanistic study of the reaction of NO3 radicals with a-pinene publication-title: Environ. Sci. Technol. doi: 10.1021/es960958n – volume: 1145 start-page: 241 year: 2007 ident: 10.1016/j.atmosenv.2013.08.032_bib7 article-title: Aqueous in situ derivatization of carboxylic acids by an ionic carbodiimide and 2,2,2-trifluoroethylamine for electron-capture detection publication-title: J. Chromatogr. A doi: 10.1016/j.chroma.2007.01.096 – volume: 99 start-page: 565 year: 1969 ident: 10.1016/j.atmosenv.2013.08.032_bib5 article-title: Pulmonary lesions produced in a A-strain mice by long-term exposure to peroxyacetyl nitrate publication-title: Am. Rev. Respir. Dis. – volume: 61 start-page: 121 year: 2011 ident: 10.1016/j.atmosenv.2013.08.032_bib13 article-title: Occupational asthma in professional cleaning work: a clinical study publication-title: Occup. Med. Oxf. doi: 10.1093/occmed/kqq192 – volume: 16 start-page: 179 year: 2006 ident: 10.1016/j.atmosenv.2013.08.032_bib20 article-title: Cleaning products and air fresheners: emissions and resulting concentrations of glycol ethers and terpenoids publication-title: Indoor Air doi: 10.1111/j.1600-0668.2005.00414.x – volume: 48 start-page: 241 year: 2004 ident: 10.1016/j.atmosenv.2013.08.032_bib4 article-title: Kinetics of the gas-phase reactions of OH radicals, NO3 radicals and O-3 with three C-7-carbonyls formed from the atmospheric reactions of myrcene, ocimene and terpinolene publication-title: J. Atmos. Chem. doi: 10.1023/B:JOCH.0000044420.94492.fa – volume: 27 start-page: 1117 year: 1993 ident: 10.1016/j.atmosenv.2013.08.032_bib15 article-title: Preparation, analysis, and atmospheric production of multifunctional organic nitrates publication-title: Environ. Sci. Technol. doi: 10.1021/es00043a010 – volume: 14 start-page: 1044 year: 2012 ident: 10.1016/j.atmosenv.2013.08.032_bib24 article-title: Use of denuder/filter apparatus to investigate terpene ozonolysis publication-title: J. Environ. Monit. doi: 10.1039/c2em10799f – volume: 11 start-page: 4198 year: 2009 ident: 10.1016/j.atmosenv.2013.08.032_bib11 article-title: Formation of organic acids from the gas-phase ozonolysis of terpinolene publication-title: Phys. Chem. Chem. Phys. doi: 10.1039/b818789d – volume: 61 start-page: 337 year: 2009 ident: 10.1016/j.atmosenv.2013.08.032_bib12 article-title: Contact allergens and irritants in household washing and cleaning products publication-title: Contact Derm. doi: 10.1111/j.1600-0536.2009.01647.x – volume: 20 start-page: 542 year: 2010 ident: 10.1016/j.atmosenv.2013.08.032_bib17 article-title: Cleaning agents and asthma publication-title: J. Investig. Allergol. Clin. Immunol. – volume: 104 start-page: 13869 year: 1999 ident: 10.1016/j.atmosenv.2013.08.032_bib18 article-title: Formation of acetone from the OH radical- and O-3-initiated reactions of a series of monoterpenes publication-title: J. Geophys. Res. Atmos. doi: 10.1029/1999JD900198 – volume: 6 start-page: 311 year: 1996 ident: 10.1016/j.atmosenv.2013.08.032_bib25 article-title: California residential air exchange rates and residence volumes publication-title: J. Expos. Anal. Environ. Epidemiol.
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Snippet	Terpinolene's (1-methyl-4-(propan-2-ylidene)cyclohexene) reaction with ozone or the nitrate radical was investigated using a denuder/filter apparatus in order... Terpinolene’s (1-methyl-4-(propan-2-ylidene)cyclohexene) reaction with ozone or the nitrate radical was investigated using a denuder/filter apparatus in order...
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SubjectTerms	aldehydes Applied sciences atmospheric chemistry Atmospheric pollution Buildings. Public works carboxylic acids cyclohexenes Denuder derivatization Exact sciences and technology Indoor pollution and occupational exposure ketones Nitrate radical nitrates Oxygenated organic compounds Ozone ozonolysis Pollution Pollution indoor buildings Reaction products terpinolene
Title	Investigation of terpinolene + ozone or terpinolene + nitrate radical reaction products using denuder/filter apparatus
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