Adsorption and separation of n-hexane and cyclohexane on the UiO-66 metal–organic framework

•Study of adsorption and separation of n-hexane (nC6) and cyclohexane(cC6) on UiO-66.•Preferential adsorption of cC6 over nC6 is observed in pulse gas chromatography.•cC6 is retained about 5 times longer than nC6.•Adsorption Gibbs energy is more favorable for cyclic compared to linear alkanes.•Break...

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Bibliographic Details
Published in:	Microporous and mesoporous materials Vol. 183; pp. 143 - 149
Main Authors:	Bozbiyik, Belgin, Duerinck, Tim, Lannoeye, Jeroen, De Vos, Dirk E., Baron, Gino V., Denayer, Joeri F.M.
Format:	Journal Article
Language:	English
Published:	San Diego, CA Elsevier Inc 01.01.2014 Elsevier
Subjects:	Adsorption Breakthrough Chemistry Colloidal state and disperse state Cyclohexane Exact sciences and technology General and physical chemistry Hexane MOF Porous materials Surface physical chemistry Hexane Breakthrough Adsorption MOF Cyclohexane Metal organic framework Separation Porous material
ISSN:	1387-1811, 1873-3093
Online Access:	Get full text
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