Structure and Magnetization of Small Monodisperse Platinum Clusters
Magnetization measurements of well-characterized monodisperse Pt clusters consisting of 13+/-2 atoms in a zeolite confirm the predicted extraordinary magnetic polarization with up to 8 unpaired electrons on a cluster, corresponding to a magnetic moment of 0.65(5) microB per atom. The effect is partl...
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| Vydané v: | Physical review letters Ročník 97; číslo 25; s. 253401 |
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| Hlavní autori: | , , , , , |
| Médium: | Journal Article |
| Jazyk: | English |
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22.12.2006
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| ISSN: | 0031-9007, 1079-7114 |
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| Abstract | Magnetization measurements of well-characterized monodisperse Pt clusters consisting of 13+/-2 atoms in a zeolite confirm the predicted extraordinary magnetic polarization with up to 8 unpaired electrons on a cluster, corresponding to a magnetic moment of 0.65(5) microB per atom. The effect is partly quenched by hydrogen chemisorption. The study provides insight into the electronic structure of the cluster and is fundamental for an understanding of how magnetism develops in small clusters. |
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| AbstractList | Magnetization measurements of well-characterized monodisperse Pt clusters consisting of 13{+-}2 atoms in a zeolite confirm the predicted extraordinary magnetic polarization with up to 8 unpaired electrons on a cluster, corresponding to a magnetic moment of 0.65(5){mu}{sub B} per atom. The effect is partly quenched by hydrogen chemisorption. The study provides insight into the electronic structure of the cluster and is fundamental for an understanding of how magnetism develops in small clusters. Magnetization measurements of well-characterized monodisperse Pt clusters consisting of 13+/-2 atoms in a zeolite confirm the predicted extraordinary magnetic polarization with up to 8 unpaired electrons on a cluster, corresponding to a magnetic moment of 0.65(5) microB per atom. The effect is partly quenched by hydrogen chemisorption. The study provides insight into the electronic structure of the cluster and is fundamental for an understanding of how magnetism develops in small clusters. Magnetization measurements of well-characterized monodisperse Pt clusters consisting of 13+/-2 atoms in a zeolite confirm the predicted extraordinary magnetic polarization with up to 8 unpaired electrons on a cluster, corresponding to a magnetic moment of 0.65(5) microB per atom. The effect is partly quenched by hydrogen chemisorption. The study provides insight into the electronic structure of the cluster and is fundamental for an understanding of how magnetism develops in small clusters.Magnetization measurements of well-characterized monodisperse Pt clusters consisting of 13+/-2 atoms in a zeolite confirm the predicted extraordinary magnetic polarization with up to 8 unpaired electrons on a cluster, corresponding to a magnetic moment of 0.65(5) microB per atom. The effect is partly quenched by hydrogen chemisorption. The study provides insight into the electronic structure of the cluster and is fundamental for an understanding of how magnetism develops in small clusters. |
| ArticleNumber | 253401 |
| Author | Bertagnolli, Helmut van Slageren, Joris Phillipp, Fritz Bauer, Matthias Liu, Xiong Roduner, Emil |
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| BackLink | https://www.ncbi.nlm.nih.gov/pubmed/17280350$$D View this record in MEDLINE/PubMed https://www.osti.gov/biblio/20861521$$D View this record in Osti.gov |
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| Cites_doi | 10.1103/PhysRevLett.86.2545 10.1103/PhysRevB.66.144413 10.1006/jcat.2001.3337 10.1016/S0921-4526(99)02928-2 10.1098/rspa.1961.0030 10.1021/jp0561874 10.1143/JPSJ.17.975 10.1016/0021-9517(85)90133-2 10.1088/0953-8984/9/5/002 10.1103/PhysRevB.47.14126 10.1021/jp012769j 10.1103/PhysRevB.58.1665 10.1006/jcat.1993.1147 10.1039/a904654b 10.1016/S0921-4526(02)02102-6 10.1126/science.265.5179.1682 |
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| Snippet | Magnetization measurements of well-characterized monodisperse Pt clusters consisting of 13+/-2 atoms in a zeolite confirm the predicted extraordinary magnetic... Magnetization measurements of well-characterized monodisperse Pt clusters consisting of 13{+-}2 atoms in a zeolite confirm the predicted extraordinary magnetic... |
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| SubjectTerms | ATOMIC AND MOLECULAR PHYSICS ATOMIC CLUSTERS ATOMS CHEMISORPTION ELECTRONIC STRUCTURE ELECTRONS HYDROGEN MAGNETIC MOMENTS MAGNETISM MAGNETIZATION PLATINUM POLARIZATION ZEOLITES |
| Title | Structure and Magnetization of Small Monodisperse Platinum Clusters |
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