Direct Patterning of Oriented Metal-Organic Framework Crystals via Control over Crystallization Kinetics in Clear Precursor Solutions

Processing metal–organic frameworks with spatial and temporal control over crystal formation will increase the applicability of these highly porous materials. By exploiting solvent effects, stable synthesis solutions can be obtained, which can be used in combination with soft lithographic techniques...

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Vydáno v:Advanced materials (Weinheim) Ročník 22; číslo 24; s. 2685 - 2688
Hlavní autoři: Ameloot, Rob, Gobechiya, Elena, Uji-i, Hiroshi, Martens, Johan A., Hofkens, Johan, Alaerts, Luc, Sels, Bert F., De Vos, Dirk E.
Médium: Journal Article
Jazyk:angličtina
Vydáno: Weinheim WILEY-VCH Verlag 25.06.2010
WILEY‐VCH Verlag
Témata:
Crystallization
Kinetics
Metal-Organic frameworks
Microcontact printing
Organometallic Compounds - chemistry
Soft lithography
Solutions
Solvents - chemistry
Volatilization
ISSN:0935-9648, 1521-4095, 1521-4095
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Shrnutí:Processing metal–organic frameworks with spatial and temporal control over crystal formation will increase the applicability of these highly porous materials. By exploiting solvent effects, stable synthesis solutions can be obtained, which can be used in combination with soft lithographic techniques to deposit oriented crystals in patterns by in situ crystallization (see figure).
Bibliografie:ArticleID:ADMA200903867
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ark:/67375/WNG-2ZMW86ZB-N
ObjectType-Article-1
SourceType-Scholarly Journals-1
ObjectType-Feature-2
content type line 23
ISSN:0935-9648
1521-4095
1521-4095
DOI:10.1002/adma.200903867