Study of mesoporous CdS-quantum-dot-sensitized TiO2 films by using X-ray photoelectron spectroscopy and AFM

CdS quantum dots were grown on mesoporous TiO 2 films by successive ionic layer adsorption and reaction processes in order to obtain CdS particles of various sizes. AFM analysis shows that the growth of the CdS particles is a two-step process. The first step is the formation of new crystallites at e...

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Veröffentlicht in:Beilstein journal of nanotechnology Jg. 5; H. 1; S. 68 - 76
Hauptverfasser: Ghazzal, Mohamed Nawfal, Wojcieszak, Robert, Raj, Gijo, Gaigneaux, Eric M
Format: Journal Article
Sprache:Englisch
Veröffentlicht: Germany Beilstein-Institut 2014
Schlagworte:
afm
cds
Full Research Paper
heterojunction
Nanoscience
Nanotechnology
particle size
quantum dots
tio2
xps
particle size
quantum dots
CdS
heterojunction
AFM
XPS
TiO2
ISSN:2190-4286, 2190-4286
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Zusammenfassung:CdS quantum dots were grown on mesoporous TiO 2 films by successive ionic layer adsorption and reaction processes in order to obtain CdS particles of various sizes. AFM analysis shows that the growth of the CdS particles is a two-step process. The first step is the formation of new crystallites at each deposition cycle. In the next step the pre-deposited crystallites grow to form larger aggregates. Special attention is paid to the estimation of the CdS particle size by X-ray photoelectron spectroscopy (XPS). Among the classical methods of characterization the XPS model is described in detail. In order to make an attempt to validate the XPS model, the results are compared to those obtained from AFM analysis and to the evolution of the band gap energy of the CdS nanoparticles as obtained by UV–vis spectroscopy. The results showed that XPS technique is a powerful tool in the estimation of the CdS particle size. In conjunction with these results, a very good correlation has been found between the number of deposition cycles and the particle size.
Bibliographie:ObjectType-Article-1
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ISSN:2190-4286
2190-4286
DOI:10.3762/bjnano.5.6