Electronic Effects of Linker Substitution on Lewis Acid Catalysis with Metal-Organic Frameworks

Functionalized linkers can greatly increase the activity of metal–organic framework (MOF) catalysts with coordinatively unsaturated sites. A clear linear free‐energy relationship (LFER) was found between Hammett σm values of the linker substituents X and the rate kX of a carbonyl‐ene reaction. This...

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Bibliographic Details

Published in:	Angewandte Chemie International Edition Vol. 51; no. 20; pp. 4887 - 4890
Main Authors:	Vermoortele, Frederik, Vandichel, Matthias, Van de Voorde, Ben, Ameloot, Rob, Waroquier, Michel, Van Speybroeck, Veronique, De Vos, Dirk E.
Format:	Journal Article
Language:	English
Published:	Weinheim WILEY-VCH Verlag 14.05.2012 WILEY‐VCH Verlag Wiley Subscription Services, Inc
Edition:	International ed. in English
Subjects:	Carbonyl compounds Carbonyls Catalysis Catalysts Electronics heterogeneous catalysis Lewis acid Lewis acidity metal-organic framework Metal-organic frameworks Pictures Samarium structure-activity relationships substituent effects Unsaturated
ISSN:	1433-7851, 1521-3773, 1521-3773
Online Access:	Get full text
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