Cobalt and Iron Cyano Benzene Bis(Dithiolene) Complexes

New iron and cobalt bis(dithiolene) complexes [M(3cbdt)2] (3cbdt = 3-cyanobenzene-1,2-dithiolate) were prepared as tetraphenylphosphonium (Ph4P+) salts for Fe in the monoanionic state and for Co in both the dianionic and monoanionic states: (Ph4P)2[Fe(III)(3cbdt)2]2 (1); (Ph4P)2[Co(III)(3cbdt)2]2 (2...

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Bibliographic Details
Published in:	Crystals (Basel) Vol. 14; no. 5; p. 469
Main Authors:	Costa, António G., Lopes, Gonçalo, Rodrigues, João F. G., Santos, Isabel C., Simão, Dulce, Lopes, Elsa B., Pereira, Laura C. J., Le Breton, Nolwenn, Choua, Sylvie, Baudron, Stéphane A., Almeida, Manuel, Rabaça, Sandra
Format:	Journal Article
Language:	English
Published:	Basel MDPI AG 01.05.2024 MDPI
Subjects:	Analysis Antiferromagnetism Benzene bis(dithiolene) metal transition complexes Chemical Sciences Cobalt Coordination Coordination chemistry Cristallography crystal structure cyclic voltammetry Diffraction Geometry Hydrocarbons Hyperfine structure Iron Ligands Magnetic permeability Magnetic properties Metals Oxidation Single crystals Temperature dependence thio-azo ligands Transition metal compounds Transition metals Unit cell Voltammetry X-rays magnetic properties thio-azo ligands cyclic voltammetry electron paramagnetic resonance crystal structure iron bis(dithiolene) metal transition complexes cobalt
ISSN:	2073-4352, 2073-4352
Online Access:	Get full text
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