2,7-Carbazole Derived Organoboron Compounds: Synthesis and Molecular Fluorescence

Triarylboranes have drawn much attention in OLEDs owing to their remarkable solid-state luminescence properties. Here two new A-D-A type compounds, 2,7-bis(dimesitylboryl)-N-ethyl-carbazole (BCz) using triarylborane as electron acceptor and carbazole as electron donor while 2,7-bis((4-(dimesitylbory...

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Veröffentlicht in:Frontiers in chemistry Jg. 9; S. 754298
Hauptverfasser: Chen, Minhui, Wei, Juan, Zhang, Yufeng, Wu, Lin, Tan, Leibo, Shi, Shanglong, Shi, Junqing, Ji, Lei
Format: Journal Article
Sprache:Englisch
Veröffentlicht: Frontiers Media S.A 22.10.2021
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ISSN:2296-2646, 2296-2646
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Zusammenfassung:Triarylboranes have drawn much attention in OLEDs owing to their remarkable solid-state luminescence properties. Here two new A-D-A type compounds, 2,7-bis(dimesitylboryl)-N-ethyl-carbazole (BCz) using triarylborane as electron acceptor and carbazole as electron donor while 2,7-bis((4-(dimesitylboryl)phenyl)ethynyl)-9-ethyl-carbazole (BPACz) using phenylacetylene as extra conjugated bridge, have been synthesized and their photoluminescence related properties in various states have been investigated both experimentally and theoretically. Both compounds show blue emission with high quantum yields, being potential candidates for blue OLED materials.
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Edited by: Jinyi Lin, Nanjing Tech University, China
This article was submitted to Physical Chemistry and Chemical Physics, a section of the journal Frontiers in Chemistry
Reviewed by: Xue-Dong Wang, Soochow University, China
Xiangqing Jia, The University of Texas at Dallas, United States
ISSN:2296-2646
2296-2646
DOI:10.3389/fchem.2021.754298