Aerobic one-step oxidation of benzene to phenol on copper exchanged HZSM5 zeolites: A mechanistic study

•Dioxygen is activated at the copper centers in the zeolite.•Cu+ oxidation by O2 and Cu2+ reduction by benzene represent a catalytic redox cycle.•Both, Brønsted acid sites and Cu ions are essential, proving bifunctional phenol formation catalysis.•The superoxide ion is the likely intermediate in a r...

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Vydáno v:	Journal of molecular catalysis. A, Chemical Ročník 379; s. 139 - 145
Hlavní autoři:	Tabler, Andreas, Häusser, Anette, Roduner, Emil
Médium:	Journal Article
Jazyk:	angličtina
Vydáno:	Amsterdam Elsevier B.V 15.11.2013 Elsevier
Témata:	benzene Benzene oxidation Bifunctional catalyst carbon dioxide carbon monoxide Catalysis catalytic activity Chemistry copper Copper zeolite Exact sciences and technology gas chromatography-mass spectrometry gases General and physical chemistry Ion-exchange oxidation oxygen Oxygen activation phenol superoxide anion Surface physical chemistry Theory of reactions, general kinetics. Catalysis. Nomenclature, chemical documentation, computer chemistry tumor necrosis factors zeolites Zeolites: preparations and properties Copper zeolite Oxygen activation Bifunctional catalyst Benzene oxidation Oxygen Alcohol Transition metal Activation Zeolite Molecular sieve Heterogeneous catalysis Phenol Benzene Phenols Benzenic compound Oxidation Copper
ISSN:	1381-1169, 1873-314X
On-line přístup:	Získat plný text
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