Dependence of n-Butane Activation on Active Site of Vanadium Phosphate Catalysts

The nature and the role of oxygen species and vanadium oxidation states on the activation of n-butane for selective oxidation to maleic anhydride were investigated. Bi-Fe doped and undoped vanadium phosphate catalysts were used a model catalyst. XRD revealed that Bi-Fe mixture dopants led to formati...

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Published in:	Catalysis letters Vol. 130; no. 3-4; pp. 327 - 334
Main Authors:	Taufiq-Yap, Y. H, Goh, C. K, Hutchings, G. J, Dummer, N, Bartley, J
Format:	Journal Article
Language:	English
Published:	Boston Boston : Springer US 01.07.2009 Springer US Springer Springer Nature B.V
Subjects:	Activation Anhydrides Bismuth Catalysis Catalysts Chemistry Chemistry and Materials Science Dependence Exact sciences and technology General and physical chemistry Industrial Chemistry/Chemical Engineering Maleic anhydride Organometallic Chemistry Oxidation Oxygen Physical Chemistry Reduction Selectivity Theory of reactions, general kinetics. Catalysis. Nomenclature, chemical documentation, computer chemistry Vanadium Activation Oxygen species Vanadium phosphate Butane oxidation Vanadium Maleic anhydride Oxygen Active site Transition metal Selectivity Air Conversion X ray diffraction n-Butane oxidation Chemical reduction Butane Heterogeneous catalysis Models Oxidation Catalyst
ISSN:	1011-372X, 1572-879X
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Abstract	The nature and the role of oxygen species and vanadium oxidation states on the activation of n-butane for selective oxidation to maleic anhydride were investigated. Bi-Fe doped and undoped vanadium phosphate catalysts were used a model catalyst. XRD revealed that Bi-Fe mixture dopants led to formation of αII-VOPO₄ phase together with (VO)₂P₂O₇ as a dominant phase when the materials were heated in n-butane/air to form the final catalysts. TPR analysis showed that the reduction behaviour of Bi-Fe doped catalysts was dominated by the reduction peak assigned to the reduction of V⁵⁺ species as compared to the undoped catalyst, which gave the reduction of V⁴⁺ as the major feature. An excess of the oxygen species (O²⁻) associated with V⁵⁺ in Bi-Fe doped catalysts improved the maleic anhydride selectivity but significantly lowering the rate of n-butane conversion. The reactive pairing of V⁴⁺-O⁻ was shown to be the centre for n-butane activation. It is proposed that the availability and appearance of active oxygen species (O⁻) on the surface of vanadium phosphate catalyst is the rate determining step of the overall reaction.
AbstractList	The nature and the role of oxygen species and vanadium oxidation states on the activation of n-butane for selective oxidation to maleic anhydride were investigated. Bi-Fe doped and undoped vanadium phosphate catalysts were used a model catalyst. XRD revealed that Bi-Fe mixture dopants led to formation of αII-VOPO₄ phase together with (VO)₂P₂O₇ as a dominant phase when the materials were heated in n-butane/air to form the final catalysts. TPR analysis showed that the reduction behaviour of Bi-Fe doped catalysts was dominated by the reduction peak assigned to the reduction of V⁵⁺ species as compared to the undoped catalyst, which gave the reduction of V⁴⁺ as the major feature. An excess of the oxygen species (O²⁻) associated with V⁵⁺ in Bi-Fe doped catalysts improved the maleic anhydride selectivity but significantly lowering the rate of n-butane conversion. The reactive pairing of V⁴⁺-O⁻ was shown to be the centre for n-butane activation. It is proposed that the availability and appearance of active oxygen species (O⁻) on the surface of vanadium phosphate catalyst is the rate determining step of the overall reaction. The nature and the role of oxygen species and vanadium oxidation states on the activation of n-butane for selective oxidation to maleic anhydride were investigated. Bi-Fe doped and undoped vanadium phosphate catalysts were used a model catalyst. XRD revealed that Bi-Fe mixture dopants led to formation of Î±II-VOPO₄ phase together with (VO)(2)P(2)O, as a dominant phase when the materials were heated in n-butane/air to form the final catalysts. TPR analysis showed that the reduction behaviour of Bi-Fe doped catalysts was dominated by the reduction peak assigned to the reduction of V⁵⁺ species as compared to the undoped catalyst, which gave the reduction of V´⁺ as the major feature. An excess of the oxygen species (O²) associated with V⁵⁺ in Bi-Fe doped catalysts improved the maleic anhydride selectivity but significantly lowering the rate of n-butane conversion. The reactive pairing of V´⁺-O was shown to be the centre for n-butane activation. It is proposed that the availability and appearance of active oxygen species (O) on the surface of vanadium phosphate catalyst is the rate determining step of the overall reaction. The nature and the role of oxygen species and vanadium oxidation states on the activation of n -butane for selective oxidation to maleic anhydride were investigated. Bi–Fe doped and undoped vanadium phosphate catalysts were used a model catalyst. XRD revealed that Bi–Fe mixture dopants led to formation of α II -VOPO 4 phase together with (VO) 2 P 2 O 7 as a dominant phase when the materials were heated in n -butane/air to form the final catalysts. TPR analysis showed that the reduction behaviour of Bi–Fe doped catalysts was dominated by the reduction peak assigned to the reduction of V 5+ species as compared to the undoped catalyst, which gave the reduction of V 4+ as the major feature. An excess of the oxygen species (O 2− ) associated with V 5+ in Bi–Fe doped catalysts improved the maleic anhydride selectivity but significantly lowering the rate of n -butane conversion. The reactive pairing of V 4+ -O − was shown to be the centre for n -butane activation. It is proposed that the availability and appearance of active oxygen species (O − ) on the surface of vanadium phosphate catalyst is the rate determining step of the overall reaction. The nature and the role of oxygen species and vanadium oxidation states on the activation of n-butane for selective oxidation to maleic anhydride were investigated. Bi–Fe doped and undoped vanadium phosphate catalysts were used a model catalyst. XRD revealed that Bi–Fe mixture dopants led to formation of αII-VOPO4 phase together with (VO)2P2O7 as a dominant phase when the materials were heated in n-butane/air to form the final catalysts. TPR analysis showed that the reduction behaviour of Bi–Fe doped catalysts was dominated by the reduction peak assigned to the reduction of V5+ species as compared to the undoped catalyst, which gave the reduction of V4+ as the major feature. An excess of the oxygen species (O2−) associated with V5+ in Bi–Fe doped catalysts improved the maleic anhydride selectivity but significantly lowering the rate of n-butane conversion. The reactive pairing of V4+-O− was shown to be the centre for n-butane activation. It is proposed that the availability and appearance of active oxygen species (O−) on the surface of vanadium phosphate catalyst is the rate determining step of the overall reaction.
Author	Taufiq-Yap, Y. H Hutchings, G. J Goh, C. K Dummer, N Bartley, J
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Cites_doi	10.1016/0021-9517(82)90231-7 10.1007/s11144-005-0219-0 10.1023/A:1019070502640 10.1016/S1381-1169(03)00422-9 10.1006/jcat.1999.2613 10.1023/A:1027238217490 10.1006/jcat.1996.0257 10.1016/S0920-5861(01)00434-5 10.1006/jcat.1997.1814 10.1016/S1003-9953(07)60009-7 10.1006/jcat.1997.1537 10.1021/j100129a023 10.1016/j.matchemphys.2005.01.009 10.1021/i300022a009 10.1016/j.molcata.2006.06.047 10.1016/S0926-860X(99)00052-6
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Keywords	Activation Oxygen species Vanadium phosphate Butane oxidation Vanadium Maleic anhydride Oxygen Active site Transition metal Selectivity Air Conversion X ray diffraction n-Butane oxidation Chemical reduction Butane Heterogeneous catalysis Models Oxidation Catalyst
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Snippet	The nature and the role of oxygen species and vanadium oxidation states on the activation of n-butane for selective oxidation to maleic anhydride were... The nature and the role of oxygen species and vanadium oxidation states on the activation of n -butane for selective oxidation to maleic anhydride were...
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SubjectTerms	Activation Anhydrides Bismuth Catalysis Catalysts Chemistry Chemistry and Materials Science Dependence Exact sciences and technology General and physical chemistry Industrial Chemistry/Chemical Engineering Maleic anhydride Organometallic Chemistry Oxidation Oxygen Physical Chemistry Reduction Selectivity Theory of reactions, general kinetics. Catalysis. Nomenclature, chemical documentation, computer chemistry Vanadium
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Title	Dependence of n-Butane Activation on Active Site of Vanadium Phosphate Catalysts
URI	https://link.springer.com/article/10.1007/s10562-009-0003-2 https://www.proquest.com/docview/2258949953 https://www.proquest.com/docview/46308450
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