On the monoclinic distortion of β-anhydrite CaSO4
β-anhydrite, the stable form of CaSO4, is a common mineral and a key phase in gypsum's dehydration mechanism. An in-depth multi-scale investigation of its structure by powder X-ray diffraction revealed a very slight distortion of the crystal cell at room temperature (β = 90.092(9) °), that led...
Gespeichert in:
| Veröffentlicht in: | Solid state sciences Jg. 108; S. 106399 |
|---|---|
| Hauptverfasser: | , , , |
| Format: | Journal Article |
| Sprache: | Englisch |
| Veröffentlicht: |
Elsevier Masson SAS
01.10.2020
Elsevier |
| Schlagworte: | |
| ISSN: | 1293-2558, 1873-3085 |
| Online-Zugang: | Volltext |
| Tags: |
Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
|
| Abstract | β-anhydrite, the stable form of CaSO4, is a common mineral and a key phase in gypsum's dehydration mechanism. An in-depth multi-scale investigation of its structure by powder X-ray diffraction revealed a very slight distortion of the crystal cell at room temperature (β = 90.092(9) °), that led to rule out the commonly admitted orthorhombic model (space group Cmcm) in favor of monoclinic C2/c subgroup. According to high-temperature XRD, the structure resumes however the orthorhombic symmetry around 400 °C.
[Display omitted]
•The first evidence of a lattice distortion in β-anhydrite.•A “pseudo tetragonal – pseudo orthorhombic” monoclinic symmetry.•A second-order phase transition is observed around 400 °C. |
|---|---|
| AbstractList | β-anhydrite, the stable form of CaSO4, is a common mineral and a key phase in gypsum's dehydration mechanism. An in-depth multi-scale investigation of its structure by powder X-ray diffraction revealed a very slight distortion of the crystal cell at room temperature (β = 90.092(9) °), that led to rule out the commonly admitted orthorhombic model (space group Cmcm) in favor of monoclinic C2/c subgroup. According to high-temperature XRD, the structure resumes however the orthorhombic symmetry around 400 °C.
[Display omitted]
•The first evidence of a lattice distortion in β-anhydrite.•A “pseudo tetragonal – pseudo orthorhombic” monoclinic symmetry.•A second-order phase transition is observed around 400 °C. β-anhydrite, the stable form of CaSO4, is a common mineral and a key phase in gypsum's dehydration mechanism. An in-depth multi-scale investigation of its structure by powder X-ray diffraction revealed a very slight distortion of the crystal cell at room temperature (β = 90.092(9) °), that led to rule out the commonly admitted orthorhombic model (space group Cmcm) in favor of monoclinic C2/c subgroup. According to high-temperature XRD, the structure resumes however the orthorhombic symmetry around 400 °C. |
| ArticleNumber | 106399 |
| Author | Beaugnon, Florian Chevreux, Sylviane Wallez, Gilles Quiligotti, Sara |
| Author_xml | – sequence: 1 givenname: Florian surname: Beaugnon fullname: Beaugnon, Florian organization: Chimie ParisTech, PSL University, CNRS, Institut de Recherche de Chimie Paris, 75005, Paris, France – sequence: 2 givenname: Sara surname: Quiligotti fullname: Quiligotti, Sara organization: Saint-Gobain Research Paris, 39 quai Lucien Lefranc, 93300, Aubervilliers, France – sequence: 3 givenname: Sylviane surname: Chevreux fullname: Chevreux, Sylviane organization: Chimie ParisTech, PSL University, CNRS, Institut de Recherche de Chimie Paris, 75005, Paris, France – sequence: 4 givenname: Gilles surname: Wallez fullname: Wallez, Gilles email: gilles.wallez@sorbonne-universite.fr organization: Chimie ParisTech, PSL University, CNRS, Institut de Recherche de Chimie Paris, 75005, Paris, France |
| BackLink | https://hal.sorbonne-universite.fr/hal-03081518$$DView record in HAL |
| BookMark | eNqVkMFKAzEQhoNUsFbfYY962JrsbrKbm6VYqxR6UM8hTSY0ZbuRJBT6Wj6Iz2SWrRe96GmGmZ9vmO8SjTrXAUI3BE8JJuxuNw2utTpEGSEoC52CMC1w0a9ZyfkZGpOmLvMSN3SU-oKXeUFpc4EuQ9hhjBmrqzEq1l0Wt5DtXedUazurMm1DdD5a12XOZJ8fuey2R-1thGwuX9bVFTo3sg1wfaoT9LZ4eJ0v89X68Wk-W-WqKquYmwqaQpGGUs642XCJASSrzaZiWrOUoYaB1JJzUhCzqaHRGDCVoLgpC0nLCboduFvZindv99IfhZNWLGcr0c9w-o1Q0hxIyi6GrPIuBA9GKJvMpB-il7YVBIvemtiJ39ZEb00M1hLo_gfo-_I_EM8DApKcgwUvTjFtPagotLN_h30BWd-a8g |
| CitedBy_id | crossref_primary_10_5194_esurf_13_257_2025 crossref_primary_10_3390_polym14122360 crossref_primary_10_1002_adfm_202310600 crossref_primary_10_3390_cryst13071054 crossref_primary_10_1155_2022_6921150 |
| Cites_doi | 10.1007/BF00308361 10.1154/1.3659285 10.1127/ejm/1/5/0721 10.1080/14786442608564042 10.1107/S0021889890008391 10.1002/1521-4079(200210)37:10<1075::AID-CRAT1075>3.0.CO;2-X 10.1007/BF00592322 10.1038/1841481a0 10.1006/jssc.1995.1260 10.1007/s00269-007-0186-2 10.1021/acs.iecr.9b00856 10.1180/minmag.2009.073.3.421 10.1111/j.1151-2916.1954.tb14027.x |
| ContentType | Journal Article |
| Copyright | 2020 Elsevier Masson SAS Distributed under a Creative Commons Attribution 4.0 International License |
| Copyright_xml | – notice: 2020 Elsevier Masson SAS – notice: Distributed under a Creative Commons Attribution 4.0 International License |
| DBID | AAYXX CITATION 1XC VOOES |
| DOI | 10.1016/j.solidstatesciences.2020.106399 |
| DatabaseName | CrossRef Hyper Article en Ligne (HAL) Hyper Article en Ligne (HAL) (Open Access) |
| DatabaseTitle | CrossRef |
| DatabaseTitleList | |
| DeliveryMethod | fulltext_linktorsrc |
| Discipline | Chemistry |
| EISSN | 1873-3085 |
| ExternalDocumentID | oai:HAL:hal-03081518v1 10_1016_j_solidstatesciences_2020_106399 S1293255820312711 |
| GroupedDBID | --K --M -~X .~1 0R~ 123 1B1 1RT 1~. 1~5 4.4 457 4G. 5VS 7-5 71M 8P~ AABXZ AACTN AAEDT AAEDW AAEPC AAIAV AAIKJ AAKOC AALRI AAOAW AAQFI AAQXK AAXUO ABFNM ABMAC ABXDB ABXRA ABYKQ ACDAQ ACGFS ACNNM ACRLP ADBBV ADEZE ADMUD AEBSH AEKER AENEX AEZYN AFKWA AFRZQ AFTJW AGHFR AGUBO AGYEJ AIEXJ AIKHN AITUG AJBFU AJOXV ALMA_UNASSIGNED_HOLDINGS AMFUW AMRAJ ASPBG AVWKF AXJTR AZFZN BKOJK BLXMC CS3 DU5 EBS EFJIC EFLBG EJD EO8 EO9 EP2 EP3 FDB FEDTE FGOYB FIRID FNPLU FYGXN G-Q GBLVA HVGLF HZ~ IHE J1W KOM M41 MAGPM MO0 N9A O-L O9- OAUVE OZT P-8 P-9 P2P PC. Q38 R2- RIG RNS ROL RPZ SDF SDG SES SEW SPC SPCBC SSM SSZ T5K ~02 ~G- 9DU AATTM AAXKI AAYWO AAYXX ABJNI ABWVN ACLOT ACRPL ACVFH ADCNI ADNMO AEIPS AEUPX AFJKZ AFPUW AGQPQ AIGII AIIUN AKBMS AKRWK AKYEP ANKPU APXCP CITATION EFKBS ~HD 1XC VOOES |
| ID | FETCH-LOGICAL-c434t-f4e82c1855969fb9a0eea67fb46dd6c435f6eada99121fb7e8d0e05aec9f32a53 |
| ISICitedReferencesCount | 6 |
| ISICitedReferencesURI | http://www.webofscience.com/api/gateway?GWVersion=2&SrcApp=Summon&SrcAuth=ProQuest&DestLinkType=CitingArticles&DestApp=WOS_CPL&KeyUT=000591715500006&url=https%3A%2F%2Fcvtisr.summon.serialssolutions.com%2F%23%21%2Fsearch%3Fho%3Df%26include.ft.matches%3Dt%26l%3Dnull%26q%3D |
| ISSN | 1293-2558 |
| IngestDate | Tue Oct 14 20:41:20 EDT 2025 Sat Nov 29 07:01:09 EST 2025 Tue Nov 18 21:02:38 EST 2025 Fri Feb 23 02:45:51 EST 2024 |
| IsDoiOpenAccess | true |
| IsOpenAccess | true |
| IsPeerReviewed | true |
| IsScholarly | true |
| Keywords | Gypsum X-ray diffraction Rietveld method Anhydrite Crystal structure Phase transition crystal structure phase transition gypsum anhydrite |
| Language | English |
| License | Distributed under a Creative Commons Attribution 4.0 International License: http://creativecommons.org/licenses/by/4.0 |
| LinkModel | OpenURL |
| MergedId | FETCHMERGED-LOGICAL-c434t-f4e82c1855969fb9a0eea67fb46dd6c435f6eada99121fb7e8d0e05aec9f32a53 |
| OpenAccessLink | https://hal.sorbonne-universite.fr/hal-03081518 |
| ParticipantIDs | hal_primary_oai_HAL_hal_03081518v1 crossref_citationtrail_10_1016_j_solidstatesciences_2020_106399 crossref_primary_10_1016_j_solidstatesciences_2020_106399 elsevier_sciencedirect_doi_10_1016_j_solidstatesciences_2020_106399 |
| PublicationCentury | 2000 |
| PublicationDate | October 2020 2020-10-00 2020-10 |
| PublicationDateYYYYMMDD | 2020-10-01 |
| PublicationDate_xml | – month: 10 year: 2020 text: October 2020 |
| PublicationDecade | 2020 |
| PublicationTitle | Solid state sciences |
| PublicationYear | 2020 |
| Publisher | Elsevier Masson SAS Elsevier |
| Publisher_xml | – name: Elsevier Masson SAS – name: Elsevier |
| References | Evans (bib17) 1979; 4 Dickson, Binks (bib3) 1926; 2 Takahashi, Setoyama (bib8) 1989; 220 Flörke (bib16) 1952; 39 West, Sutton (bib15) 1953; 37 Rodriguez-Carvajal (bib11) 2001; 26 Jacques, Gonzalez-Saborido, Leynaud, Bensted, Tyrer, Greaves, Barnes (bib9) 2009; 73 Ballirano, Melis (bib18) 2007; 34 Bezou, Mutin, Nonat (bib1) 1995; 117 Haüy (bib2) 1801 Hartman (bib5) 1989; 1 Rodriguez-Carvajal, Roisnel (bib12) 1998; 20 Bérar, Lelann (bib14) 1991; 24 Antao (bib4) 2011; 26 Williamson, Hall (bib13) 1953; 1 Preturlan, Vieille, Quiligotti, Favergeon (bib6) 2019; 58 Follner, Wolter, Preusser, Indris, Silber, Follner (bib7) 2002; 37 Anthony, Bideaux, Bladh, Nichols (bib19) Mitsuki, Kita (bib10) 1959; 184 Ballirano (10.1016/j.solidstatesciences.2020.106399_bib18) 2007; 34 Preturlan (10.1016/j.solidstatesciences.2020.106399_bib6) 2019; 58 Flörke (10.1016/j.solidstatesciences.2020.106399_bib16) 1952; 39 Williamson (10.1016/j.solidstatesciences.2020.106399_bib13) 1953; 1 Rodriguez-Carvajal (10.1016/j.solidstatesciences.2020.106399_bib11) 2001; 26 Hartman (10.1016/j.solidstatesciences.2020.106399_bib5) 1989; 1 Jacques (10.1016/j.solidstatesciences.2020.106399_bib9) 2009; 73 Bérar (10.1016/j.solidstatesciences.2020.106399_bib14) 1991; 24 Anthony (10.1016/j.solidstatesciences.2020.106399_bib19) Rodriguez-Carvajal (10.1016/j.solidstatesciences.2020.106399_bib12) 1998; 20 Evans (10.1016/j.solidstatesciences.2020.106399_bib17) 1979; 4 West (10.1016/j.solidstatesciences.2020.106399_bib15) 1953; 37 Takahashi (10.1016/j.solidstatesciences.2020.106399_bib8) 1989; 220 Dickson (10.1016/j.solidstatesciences.2020.106399_bib3) 1926; 2 Antao (10.1016/j.solidstatesciences.2020.106399_bib4) 2011; 26 Follner (10.1016/j.solidstatesciences.2020.106399_bib7) 2002; 37 Haüy (10.1016/j.solidstatesciences.2020.106399_bib2) 1801 Mitsuki (10.1016/j.solidstatesciences.2020.106399_bib10) 1959; 184 Bezou (10.1016/j.solidstatesciences.2020.106399_bib1) 1995; 117 |
| References_xml | – volume: 1 start-page: 721 year: 1989 end-page: 722 ident: bib5 article-title: On the unit cell dimensions and bond lengths of anhydrite publication-title: Eur. J. Mineral – volume: 184 start-page: 1481 year: 1959 ident: bib10 article-title: Transition of calcium sulfate hemihydrate to insoluble anhydrite publication-title: Nature – volume: 37 start-page: 1075 year: 2002 end-page: 1087 ident: bib7 article-title: The setting behaviour of publication-title: Cryst. Res. Technol. – volume: 37 start-page: 221 year: 1953 end-page: 224 ident: bib15 article-title: Thermography of gypsum publication-title: J. Am. Ceram. Soc. – volume: 117 start-page: 165 year: 1995 end-page: 176 ident: bib1 article-title: Investigation of the crystal structure of publication-title: J. Solid State Chem. – volume: 2 start-page: 114 year: 1926 end-page: 128 ident: bib3 article-title: The crystalline structure of anhydrite publication-title: Phil. Mag. – volume: 220 start-page: 135 year: 1989 end-page: 141 ident: bib8 article-title: SEM observation of publication-title: Gypsum & Lime – volume: 58 start-page: 9596 year: 2019 end-page: 9606 ident: bib6 article-title: Comprehensive thermodynamic study of the calcium sulfate-water vapor system. Part 1: experimental measurements and phase equilibria publication-title: Ind. Eng. Chem. Res. – volume: 26 start-page: 12 year: 2001 end-page: 19 ident: bib11 article-title: Recent developments of the program FULLPROF publication-title: Commission for Powder Diffraction (IUCR) Newsletter – start-page: 348 year: 1801 end-page: 353 ident: bib2 article-title: Traité de Minéralogie – volume: 39 start-page: 478 year: 1952 end-page: 479 ident: bib16 article-title: Die Hochtemperaturmodifikationen von Kalzium-, Strontium- und Bariumsulfat publication-title: Naturwissenschaften – volume: 34 start-page: 699 year: 2007 end-page: 704 ident: bib18 article-title: Thermal behaviour of beta-anhydrite CaSO publication-title: Phys. Chem. Miner. – volume: 73 start-page: 421 year: 2009 end-page: 432 ident: bib9 article-title: Structural evolution during the dehydration of gypsum materials publication-title: Min. Mag. – volume: 26 start-page: 326 year: 2011 end-page: 330 ident: bib4 article-title: Crystal-structure analysis of four mineral samples of anhydrite, CaSO publication-title: Powder Diffr. – volume: 20 start-page: 35 year: 1998 ident: bib12 article-title: FullProf 98 and WinPLOTR: new windows 95/NT applications for diffraction publication-title: Commission for Powder Diffraction (IUCR) Newsletter – volume: 24 start-page: 1 year: 1991 end-page: 5 ident: bib14 article-title: E.S.D.'s and estimated probable error obtained in Rietveld refinements with local correlations publication-title: J. Appl. Crystallogr. – volume: 4 start-page: 77 year: 1979 end-page: 82 ident: bib17 article-title: The thermal expansion of anhydrite to 1000 °C publication-title: Phys. Chem. Miner. – ident: bib19 article-title: Handbook of Mineralogy, Mineralogical Society of America, Chantilly, VA 20151-1110, USA – volume: 1 start-page: 22 year: 1953 end-page: 31 ident: bib13 article-title: X-ray line broadening from filed aluminum and tungsten Acta publication-title: Metall – volume: 4 start-page: 77 year: 1979 ident: 10.1016/j.solidstatesciences.2020.106399_bib17 article-title: The thermal expansion of anhydrite to 1000 °C publication-title: Phys. Chem. Miner. doi: 10.1007/BF00308361 – volume: 26 start-page: 326 year: 2011 ident: 10.1016/j.solidstatesciences.2020.106399_bib4 article-title: Crystal-structure analysis of four mineral samples of anhydrite, CaSO4, using synchrotron high-resolution powder X-ray diffraction data publication-title: Powder Diffr. doi: 10.1154/1.3659285 – volume: 1 start-page: 721 year: 1989 ident: 10.1016/j.solidstatesciences.2020.106399_bib5 article-title: On the unit cell dimensions and bond lengths of anhydrite publication-title: Eur. J. Mineral doi: 10.1127/ejm/1/5/0721 – volume: 2 start-page: 114 year: 1926 ident: 10.1016/j.solidstatesciences.2020.106399_bib3 article-title: The crystalline structure of anhydrite publication-title: Phil. Mag. doi: 10.1080/14786442608564042 – volume: 24 start-page: 1 year: 1991 ident: 10.1016/j.solidstatesciences.2020.106399_bib14 article-title: E.S.D.'s and estimated probable error obtained in Rietveld refinements with local correlations publication-title: J. Appl. Crystallogr. doi: 10.1107/S0021889890008391 – volume: 37 start-page: 1075 year: 2002 ident: 10.1016/j.solidstatesciences.2020.106399_bib7 article-title: The setting behaviour of α- and β- CaSO4·0.5H2O as a function of crystal structure and morphology publication-title: Cryst. Res. Technol. doi: 10.1002/1521-4079(200210)37:10<1075::AID-CRAT1075>3.0.CO;2-X – ident: 10.1016/j.solidstatesciences.2020.106399_bib19 – volume: 26 start-page: 12 year: 2001 ident: 10.1016/j.solidstatesciences.2020.106399_bib11 article-title: Recent developments of the program FULLPROF publication-title: Commission for Powder Diffraction (IUCR) Newsletter – volume: 39 start-page: 478 year: 1952 ident: 10.1016/j.solidstatesciences.2020.106399_bib16 article-title: Die Hochtemperaturmodifikationen von Kalzium-, Strontium- und Bariumsulfat publication-title: Naturwissenschaften doi: 10.1007/BF00592322 – volume: 184 start-page: 1481 year: 1959 ident: 10.1016/j.solidstatesciences.2020.106399_bib10 article-title: Transition of calcium sulfate hemihydrate to insoluble anhydrite publication-title: Nature doi: 10.1038/1841481a0 – volume: 220 start-page: 135 year: 1989 ident: 10.1016/j.solidstatesciences.2020.106399_bib8 article-title: SEM observation of β-calcium sulfate hemihydrate particles II. Effects of raw gypsum and condition of production on internal microstructure publication-title: Gypsum & Lime – volume: 1 start-page: 22 year: 1953 ident: 10.1016/j.solidstatesciences.2020.106399_bib13 article-title: X-ray line broadening from filed aluminum and tungsten Acta publication-title: Metall – volume: 117 start-page: 165 year: 1995 ident: 10.1016/j.solidstatesciences.2020.106399_bib1 article-title: Investigation of the crystal structure of γ-CaSO4, CaSO4·0.5H2O and CaSO4·0.6H2O by powder diffraction methods publication-title: J. Solid State Chem. doi: 10.1006/jssc.1995.1260 – volume: 20 start-page: 35 year: 1998 ident: 10.1016/j.solidstatesciences.2020.106399_bib12 article-title: FullProf 98 and WinPLOTR: new windows 95/NT applications for diffraction publication-title: Commission for Powder Diffraction (IUCR) Newsletter – start-page: 348 year: 1801 ident: 10.1016/j.solidstatesciences.2020.106399_bib2 – volume: 34 start-page: 699 year: 2007 ident: 10.1016/j.solidstatesciences.2020.106399_bib18 article-title: Thermal behaviour of beta-anhydrite CaSO4 to 1263 K publication-title: Phys. Chem. Miner. doi: 10.1007/s00269-007-0186-2 – volume: 58 start-page: 9596 year: 2019 ident: 10.1016/j.solidstatesciences.2020.106399_bib6 article-title: Comprehensive thermodynamic study of the calcium sulfate-water vapor system. Part 1: experimental measurements and phase equilibria publication-title: Ind. Eng. Chem. Res. doi: 10.1021/acs.iecr.9b00856 – volume: 73 start-page: 421 year: 2009 ident: 10.1016/j.solidstatesciences.2020.106399_bib9 article-title: Structural evolution during the dehydration of gypsum materials publication-title: Min. Mag. doi: 10.1180/minmag.2009.073.3.421 – volume: 37 start-page: 221 year: 1953 ident: 10.1016/j.solidstatesciences.2020.106399_bib15 article-title: Thermography of gypsum publication-title: J. Am. Ceram. Soc. doi: 10.1111/j.1151-2916.1954.tb14027.x |
| SSID | ssj0006674 |
| Score | 2.3116434 |
| Snippet | β-anhydrite, the stable form of CaSO4, is a common mineral and a key phase in gypsum's dehydration mechanism. An in-depth multi-scale investigation of its... |
| SourceID | hal crossref elsevier |
| SourceType | Open Access Repository Enrichment Source Index Database Publisher |
| StartPage | 106399 |
| SubjectTerms | Anhydrite Chemical Sciences Crystal structure Gypsum Phase transition Rietveld method X-ray diffraction |
| Title | On the monoclinic distortion of β-anhydrite CaSO4 |
| URI | https://dx.doi.org/10.1016/j.solidstatesciences.2020.106399 https://hal.sorbonne-universite.fr/hal-03081518 |
| Volume | 108 |
| WOSCitedRecordID | wos000591715500006&url=https%3A%2F%2Fcvtisr.summon.serialssolutions.com%2F%23%21%2Fsearch%3Fho%3Df%26include.ft.matches%3Dt%26l%3Dnull%26q%3D |
| hasFullText | 1 |
| inHoldings | 1 |
| isFullTextHit | |
| isPrint | |
| journalDatabaseRights | – providerCode: PRVESC databaseName: Elsevier SD Freedom Collection Journals 2021 customDbUrl: eissn: 1873-3085 dateEnd: 99991231 omitProxy: false ssIdentifier: ssj0006674 issn: 1293-2558 databaseCode: AIEXJ dateStart: 19990101 isFulltext: true titleUrlDefault: https://www.sciencedirect.com providerName: Elsevier |
| link | http://cvtisr.summon.serialssolutions.com/2.0.0/link/0/eLvHCXMwtV3dbtMwFLbKhmA3iF8xBihCTEKqPKWJ48RXqJSWDqp2qAP1znISe-0UpVXXRttr8SA8E8f5c6sJtF5wY0WJY8c-X-zvHB8fI_TelnZkK0Kwr1SMCREMs5AKHBPXlRT4eZg7Y_4c-MNhMJmws0ZjUe2FyRI_TYPra7b4r6KGeyBsvXV2B3HXhcINuAahQwpih_ROgh8VjotQ37zY9qgXYUCzrqjhcad7_MnBIp3exEsgnM2OGI_IJkkdz5NZ3My3GjXLGdIY06VYX6TFUn1Pe-8ZdH1fz5LZxXxVOAhoU7PxHZDZUq7zeW58k2TwklkS0oe55FbsL3pb4pYZAnTOyqGttI2VE_nGUApEAoPCEmyNtXkQh9vjdmFCuDy50g3M21c170RXBhk0kzJzVrVO32-P-dnnHh-cDr9tP93wM-y3B5BORYJ1cB6gOEEG-vK-43sMxsH99ml38rWevSnNI3fXX_8AfTA-gf_-vL9Rm3vTykifk5bzx-hRqW1Y7QIlT1BDpk_Rw051yN8z5IxSC9BiGbRYBi3WXFm_fxmkWDlSnqMfve55p4_LYzRwRFyyworIwImAl3mMMhUyYUspqK9CQuOYQh5PURhPBGgKTkuFvgxi-IM9ISOmXEd47gu0B7iSL5HltjwlaMDCllSERRELHS9yvVAGthuKFjtEH6se4FEZY14fdZLwypnwkt_uQ677kBd9eIhYXcKiiLeyw7udqtN5-bzghRxgtkMp70BedeU6_DoAiOt7Bj6v7pLpCB2YP-U12lst1_INuh9lq9nV8m0JvD_eyKQ8 |
| linkProvider | Elsevier |
| openUrl | ctx_ver=Z39.88-2004&ctx_enc=info%3Aofi%2Fenc%3AUTF-8&rfr_id=info%3Asid%2Fsummon.serialssolutions.com&rft_val_fmt=info%3Aofi%2Ffmt%3Akev%3Amtx%3Ajournal&rft.genre=article&rft.atitle=On+the+monoclinic+distortion+of+%CE%B2-anhydrite+CaSO4&rft.jtitle=Solid+state+sciences&rft.au=Beaugnon%2C+Florian&rft.au=Quiligotti%2C+Sara&rft.au=Chevreux%2C+Sylviane&rft.au=Wallez%2C+Gilles&rft.date=2020-10-01&rft.pub=Elsevier&rft.issn=1293-2558&rft.volume=108&rft_id=info:doi/10.1016%2Fj.solidstatesciences.2020.106399&rft.externalDBID=HAS_PDF_LINK&rft.externalDocID=oai%3AHAL%3Ahal-03081518v1 |
| thumbnail_l | http://covers-cdn.summon.serialssolutions.com/index.aspx?isbn=/lc.gif&issn=1293-2558&client=summon |
| thumbnail_m | http://covers-cdn.summon.serialssolutions.com/index.aspx?isbn=/mc.gif&issn=1293-2558&client=summon |
| thumbnail_s | http://covers-cdn.summon.serialssolutions.com/index.aspx?isbn=/sc.gif&issn=1293-2558&client=summon |