New Spectroelectrochemical Insights into Manganese and Rhenium Bipyridine Complexes as Catalysts for the Electrochemical Reduction of Carbon Dioxide
This study aimed to demonstrate the behavior of different complexes using IR spectroelectrochemistry (SEC), a technique that combines IR spectroscopy with electrochemistry. Four different Mn and Re catalysts for electrochemical CO2 reduction were studied in dry acetonitrile. In the case of Mn(apbpy)...
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| Vydáno v: | Molecules (Basel, Switzerland) Ročník 28; číslo 22; s. 7535 |
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01.11.2023
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| Abstract | This study aimed to demonstrate the behavior of different complexes using IR spectroelectrochemistry (SEC), a technique that combines IR spectroscopy with electrochemistry. Four different Mn and Re catalysts for electrochemical CO2 reduction were studied in dry acetonitrile. In the case of Mn(apbpy)(CO)3Br (apbpy = 4(4-aminophenyl)-2,2′-bipyridine), SEC suggested that a very slow catalytic reduction of CO2 also occurs in acetonitrile in the absence of proton donors, but at rather negative potentials. In contrast, the corresponding Re(apbpy)(CO)3Br clearly demonstrated slow catalytic conversion at the first reduction potential. Switching to saturated CO2 solutions in a mixture of acetonitrile and 5% water as a proton donor, the SEC of Mn(apbpy)(CO)3Br displayed a faster catalytic behavior. |
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| AbstractList | This study aimed to demonstrate the behavior of different complexes using IR spectroelectrochemistry (SEC), a technique that combines IR spectroscopy with electrochemistry. Four different Mn and Re catalysts for electrochemical CO2 reduction were studied in dry acetonitrile. In the case of Mn(apbpy)(CO)3Br (apbpy = 4(4-aminophenyl)-2,2'-bipyridine), SEC suggested that a very slow catalytic reduction of CO2 also occurs in acetonitrile in the absence of proton donors, but at rather negative potentials. In contrast, the corresponding Re(apbpy)(CO)3Br clearly demonstrated slow catalytic conversion at the first reduction potential. Switching to saturated CO2 solutions in a mixture of acetonitrile and 5% water as a proton donor, the SEC of Mn(apbpy)(CO)3Br displayed a faster catalytic behavior.This study aimed to demonstrate the behavior of different complexes using IR spectroelectrochemistry (SEC), a technique that combines IR spectroscopy with electrochemistry. Four different Mn and Re catalysts for electrochemical CO2 reduction were studied in dry acetonitrile. In the case of Mn(apbpy)(CO)3Br (apbpy = 4(4-aminophenyl)-2,2'-bipyridine), SEC suggested that a very slow catalytic reduction of CO2 also occurs in acetonitrile in the absence of proton donors, but at rather negative potentials. In contrast, the corresponding Re(apbpy)(CO)3Br clearly demonstrated slow catalytic conversion at the first reduction potential. Switching to saturated CO2 solutions in a mixture of acetonitrile and 5% water as a proton donor, the SEC of Mn(apbpy)(CO)3Br displayed a faster catalytic behavior. This study aimed to demonstrate the behavior of different complexes using IR spectroelectrochemistry (SEC), a technique that combines IR spectroscopy with electrochemistry. Four different Mn and Re catalysts for electrochemical CO2 reduction were studied in dry acetonitrile. In the case of Mn(apbpy)(CO)3Br (apbpy = 4(4-aminophenyl)-2,2'-bipyridine), SEC suggested that a very slow catalytic reduction of CO2 also occurs in acetonitrile in the absence of proton donors, but at rather negative potentials. In contrast, the corresponding Re(apbpy)(CO)3Br clearly demonstrated slow catalytic conversion at the first reduction potential. Switching to saturated CO2 solutions in a mixture of acetonitrile and 5% water as a proton donor, the SEC of Mn(apbpy)(CO)3Br displayed a faster catalytic behavior. This study aimed to demonstrate the behavior of different complexes using IR spectroelectrochemistry (SEC), a technique that combines IR spectroscopy with electrochemistry. Four different Mn and Re catalysts for electrochemical CO[sub.2] reduction were studied in dry acetonitrile. In the case of Mn(apbpy)(CO)[sub.3]Br (apbpy = 4(4-aminophenyl)-2,2′-bipyridine), SEC suggested that a very slow catalytic reduction of CO[sub.2] also occurs in acetonitrile in the absence of proton donors, but at rather negative potentials. In contrast, the corresponding Re(apbpy)(CO)[sub.3]Br clearly demonstrated slow catalytic conversion at the first reduction potential. Switching to saturated CO[sub.2] solutions in a mixture of acetonitrile and 5% water as a proton donor, the SEC of Mn(apbpy)(CO)[sub.3]Br displayed a faster catalytic behavior. |
| Audience | Academic |
| Author | Fiedler, Jan Nervi, Carlo Rotundo, Laura Sokolova, Romana Gobetto, Roberto Reviglio, Chiara Barbero, Alice |
| Author_xml | – sequence: 1 givenname: Alice orcidid: 0000-0001-9617-1733 surname: Barbero fullname: Barbero, Alice – sequence: 2 givenname: Laura surname: Rotundo fullname: Rotundo, Laura – sequence: 3 givenname: Chiara orcidid: 0009-0003-3368-1076 surname: Reviglio fullname: Reviglio, Chiara – sequence: 4 givenname: Roberto orcidid: 0000-0002-2431-8051 surname: Gobetto fullname: Gobetto, Roberto – sequence: 5 givenname: Romana orcidid: 0000-0003-1705-7401 surname: Sokolova fullname: Sokolova, Romana – sequence: 6 givenname: Jan surname: Fiedler fullname: Fiedler, Jan – sequence: 7 givenname: Carlo orcidid: 0000-0002-3712-7369 surname: Nervi fullname: Nervi, Carlo |
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| Cites_doi | 10.1039/C9CP00504H 10.1021/acs.accounts.2c00129 10.1021/acs.inorgchem.0c00263 10.1039/b508541a 10.1002/chem.201605546 10.1039/C8DT02873G 10.1246/cl.2004.1624 10.1016/j.cej.2021.129050 10.1021/om960044+ 10.1002/cphc.201700739 10.1021/jacs.9b11806 10.1021/ic020420k 10.1021/jacs.1c10805 10.1039/b515623h 10.1021/acscatal.2c01667 10.1002/ejic.201402912 10.1021/om500044a 10.1135/cccc19961342 10.1021/acscatal.1c05043 10.1021/ic9512385 10.1002/celc.202100279 10.3389/fchem.2019.00417 10.1002/jcc.21759 10.1103/PhysRevB.37.785 10.1021/ja501252f 10.1063/1.464913 10.1039/C8CC08385A 10.1021/cr4002758 10.1021/acs.organomet.9b00815 10.1039/C3SC53470G 10.1021/acs.organomet.8b00588 10.1016/0022-0728(91)85012-E 10.1063/1.1480445 10.1002/anie.201103616 10.1039/b504286k 10.1021/om00003a013 |
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| References | Chen (ref_5) 2012; 28 Rotundo (ref_16) 2019; 7 Tang (ref_3) 2022; 12 ref_33 Neri (ref_11) 2019; 21 Behnke (ref_8) 2018; 47 Machan (ref_27) 2014; 33 Hartl (ref_6) 1996; 61 Taylor (ref_19) 2020; 59 Johansson (ref_30) 2003; 42 Madsen (ref_23) 2021; 8 Grimme (ref_40) 2011; 32 Scrocco (ref_34) 1981; 55 Johnson (ref_10) 1996; 15 Lee (ref_37) 1988; 37 Becke (ref_36) 1993; 98 Cheng (ref_29) 1996; 35 Stor (ref_25) 1995; 14 Sampson (ref_26) 2014; 136 Filippi (ref_12) 2021; 416 Bourrez (ref_17) 2011; 50 Franco (ref_18) 2015; 2015 Madsen (ref_24) 2020; 39 Clark (ref_28) 2014; 5 Franco (ref_21) 2017; 23 Cossi (ref_35) 2002; 117 Breelove (ref_7) 2004; 33 Weigend (ref_39) 2005; 7 Rotundo (ref_1) 2021; 31 Hartl (ref_31) 1991; 317 Rotundo (ref_13) 2019; 55 Weigend (ref_38) 2006; 8 Aresta (ref_2) 2014; 114 Kaim (ref_32) 2009; 38 Sun (ref_15) 2017; 18 Cho (ref_22) 2020; 142 Cheon (ref_4) 2022; 55 Rotundo (ref_14) 2019; 38 Madsen (ref_20) 2021; 143 Polyansky (ref_9) 2022; 12 |
| References_xml | – volume: 21 start-page: 7389 year: 2019 ident: ref_11 article-title: In situ study of the low overpotential “dimer pathway” for electrocatalytic carbon dioxide reduction by manganese carbonyl complexes publication-title: Phys. Chem. Chem. Phys. doi: 10.1039/C9CP00504H – volume: 55 start-page: 931 year: 2022 ident: ref_4 article-title: From Pollutant to Chemical Feedstock: Valorizing Carbon Dioxide through Photo-and Electrochemical Processes publication-title: Acc. Chem. Res. doi: 10.1021/acs.accounts.2c00129 – volume: 59 start-page: 5564 year: 2020 ident: ref_19 article-title: Strong impact of intramolecular hydrogen bonding on the cathodic path of [Re (3,3′-dihydroxy-2, 2′-bipyridine)(CO)3Cl] and catalytic reduction of carbon dioxide publication-title: Inorg. Chem. doi: 10.1021/acs.inorgchem.0c00263 – volume: 7 start-page: 3297 year: 2005 ident: ref_39 article-title: Balanced basis sets of split valence, triple zeta valence and quadruple zeta valence quality for H to Rn: Design and assessment of accuracy publication-title: Phys. Chem. Chem. Phys. doi: 10.1039/b508541a – volume: 23 start-page: 4782 year: 2017 ident: ref_21 article-title: Local proton source in electrocatalytic CO2 reduction with [Mn (bpy–R)(CO)3Br] complexes publication-title: Chem. Eur. J. doi: 10.1002/chem.201605546 – volume: 47 start-page: 15206 year: 2018 ident: ref_8 article-title: Spectroelectrochemical investigations of nickel cyclam indicate different reaction mechanisms for electrocatalytic CO2 and H+ reduction publication-title: Dalton Trans. doi: 10.1039/C8DT02873G – volume: 33 start-page: 1624 year: 2004 ident: ref_7 article-title: Synthesis of an electron pooling ligand based on triruthenium clusters and electrochemical reduction of CO2 by its zinc(II)complex publication-title: Chem. Lett. doi: 10.1246/cl.2004.1624 – volume: 416 start-page: 129050 year: 2021 ident: ref_12 article-title: Turning manganese into gold: Efficient electrochemical CO2 reduction by a fac-Mn (apbpy)(CO)3Br complex in a gas–liquid interface flow cell publication-title: Chem. Eng. J. doi: 10.1016/j.cej.2021.129050 – volume: 15 start-page: 3374 year: 1996 ident: ref_10 article-title: Electrocatalytic Reduction of CO2 Using the Complexes [Re (bpy)(CO)3L] n (n=+ 1, L= P (OEt)3, CH3CN; n= 0, L= Cl-, Otf-; bpy= 2,2‘-Bipyridine; Otf-= CF3SO3) as Catalyst Precursors: Infrared Spectroelectrochemical Investigation publication-title: Organometallics doi: 10.1021/om960044+ – volume: 18 start-page: 3219 year: 2017 ident: ref_15 article-title: Electrochemical CO2 reduction at glassy carbon electrodes functionalized by MnI and ReI organometallic complexes publication-title: ChemPhysChem doi: 10.1002/cphc.201700739 – volume: 142 start-page: 4265 year: 2020 ident: ref_22 article-title: Ligand-controlled product selectivity in electrochemical carbon dioxide reduction using manganese bipyridine catalysts publication-title: J. Am. Chem. Soc. doi: 10.1021/jacs.9b11806 – volume: 42 start-page: 2908 year: 2003 ident: ref_30 article-title: Electron Donor–Acceptor Dyads Based on Ruthenium (II) Bipyridine and Terpyridine Complexes Bound to Naphthalenediimide publication-title: Inorg. Chem. doi: 10.1021/ic020420k – volume: 28 start-page: 541 year: 2012 ident: ref_5 article-title: FTIR Spectroelectrochemistry Study on the Reduction of CO2 at a Gold Electrode Interface publication-title: Chin. J. Inorg. Chem. – volume: 143 start-page: 20491 year: 2021 ident: ref_20 article-title: Promoting selective generation of formic acid from CO2 using Mn (bpy)(CO)3Br as electrocatalyst and triethylamine/isopropanol as additives publication-title: J. Am. Chem. Soc. doi: 10.1021/jacs.1c10805 – volume: 8 start-page: 1057 year: 2006 ident: ref_38 article-title: Accurate Coulomb-fitting basis sets for H to Rn publication-title: Phys. Chem. Chem. Phys. doi: 10.1039/b515623h – volume: 12 start-page: 9023 year: 2022 ident: ref_3 article-title: An overview of solar-driven photoelectrochemical CO2 conversion to chemical fuels publication-title: ACS Catal. doi: 10.1021/acscatal.2c01667 – volume: 2015 start-page: 296 year: 2015 ident: ref_18 article-title: Photo-and Electrocatalytic Reduction of CO2 by [Re (CO)3{α,α′-Diimine-(4-piperidinyl-1,8-naphthalimide)}Cl] Complexes publication-title: Eur. J. Inorg. Chem. doi: 10.1002/ejic.201402912 – volume: 33 start-page: 4550 year: 2014 ident: ref_27 article-title: Developing a Mechanistic Understanding of Molecular Electrocatalysts for CO2 Reduction using Infrared Spectroelectrochemistry publication-title: Organometallics doi: 10.1021/om500044a – volume: 61 start-page: 1342 year: 1996 ident: ref_6 article-title: Infrared Spectroelectrochemical Investigation of Carbon Dioxide Reduction Mediated by the Anion [Ru (SnPh3)(Co)2(iPr-DAB)]-(iPr-DAB= N,N′-Diisopropyl-1,4-diaza-1,3-butadiene) publication-title: Coll. Czech. Chem. Comm. doi: 10.1135/cccc19961342 – volume: 12 start-page: 1706 year: 2022 ident: ref_9 article-title: Role of Bimetallic Interactions in the Enhancement of Catalytic CO2 Reduction by a Macrocyclic Cobalt Catalyst publication-title: ACS Catal. doi: 10.1021/acscatal.1c05043 – volume: 35 start-page: 7704 year: 1996 ident: ref_29 article-title: Electrochemical and IR spectroelectrochemical studies of the electrocatalytic reduction of carbon dioxide by [Ir2(dimen)4]2+ (dimen = 1,8-Diisocyanomenthane) publication-title: Inorg. Chem. doi: 10.1021/ic9512385 – ident: ref_33 – volume: 55 start-page: 117 year: 1981 ident: ref_34 article-title: Electrostatic interaction of a solute with a continuum. A direct utilizaion of AB initio molecular potentials for the prevision of solvent effects publication-title: J. Chem. Phys. – volume: 8 start-page: 2108 year: 2021 ident: ref_23 article-title: Mechanistic Elucidation of Dimer Formation and Strategies for Its Suppression in Electrochemical Reduction of Fac-Mn (bpy)(CO)3Br publication-title: ChemElectroChem doi: 10.1002/celc.202100279 – volume: 7 start-page: 417 year: 2019 ident: ref_16 article-title: Electronic effects of substituents on fac-M (bpy-R)(CO)3(M = Mn, Re) complexes for homogeneous CO2 electroreduction publication-title: Front. Chem. doi: 10.3389/fchem.2019.00417 – volume: 32 start-page: 1456 year: 2011 ident: ref_40 article-title: Effect of the damping function in dispersion corrected density functional theory publication-title: J. Comput. Chem. doi: 10.1002/jcc.21759 – volume: 37 start-page: 785 year: 1988 ident: ref_37 article-title: Development of the Colle-Salvetti correlation-energy formula into a functional of the electron density publication-title: Phys. Rev. B Condens. Matter doi: 10.1103/PhysRevB.37.785 – volume: 136 start-page: 5460 year: 2014 ident: ref_26 article-title: Manganese catalysts with bulky bipyridine ligands for the electrocatalytic reduction of carbon dioxide: Eliminating dimerization and altering catalysis publication-title: J. Am. Chem. Soc. doi: 10.1021/ja501252f – volume: 98 start-page: 5648 year: 1993 ident: ref_36 article-title: Density-functional thermochemistry. I. The effect of the exchange-only gradient correction publication-title: J. Chem. Phys. doi: 10.1063/1.464913 – volume: 55 start-page: 775 year: 2019 ident: ref_13 article-title: Electrochemical CO2 reduction in water at carbon cloth electrodes functionalized with a fac-Mn (apbpy)(CO)3 Br complex publication-title: Chem. Commun. doi: 10.1039/C8CC08385A – volume: 114 start-page: 1709 year: 2014 ident: ref_2 article-title: Catalysis for the Valorization of Exhaust Carbon: From CO2 to Chemicals, Materials, and Fuels. Technological Use of CO2 publication-title: Chem. Rev. doi: 10.1021/cr4002758 – volume: 39 start-page: 1480 year: 2020 ident: ref_24 article-title: Evaluation of the electrocatalytic reduction of carbon dioxide using rhenium and ruthenium bipyridine catalysts bearing pendant amines in the secondary coordination sphere publication-title: Organometallics doi: 10.1021/acs.organomet.9b00815 – volume: 5 start-page: 1894 year: 2014 ident: ref_28 article-title: Reduction by M (bpy-R)(CO)4 (M = Mo, W; R = H, tBu) complexes. Electrochemical, spectroscopic, and computational studies and comparison with group 7 catalysts publication-title: Chem. Sci. doi: 10.1039/C3SC53470G – volume: 38 start-page: 1351 year: 2019 ident: ref_14 article-title: Electrochemical and photochemical reduction of CO2 catalyzed by Re(I)complexes carrying local proton sources publication-title: Organometallics doi: 10.1021/acs.organomet.8b00588 – volume: 317 start-page: 179 year: 1991 ident: ref_31 article-title: Simple construction of an infrared optically transparent thin-layer electrochemical cell: Applications to the redox reactions of ferrocene, Mn2(CO)10 and Mn(CO)3(3,5-di-t-butyl-catecholate)− publication-title: J. Electroanal. Chem. Interfacial Electrochem. doi: 10.1016/0022-0728(91)85012-E – volume: 31 start-page: 100509 year: 2021 ident: ref_1 article-title: Electrochemical CO2 reduction with earth-abundant metal catalysts publication-title: Curr. Opin. Green Sust. Chem. – volume: 117 start-page: 43 year: 2002 ident: ref_35 article-title: New developments in the polarizable continuum model for quantum mechanical and classical calculations on molecules in solution publication-title: J. Chem. Phys. doi: 10.1063/1.1480445 – volume: 50 start-page: 9903 year: 2011 ident: ref_17 article-title: [Mn (bipyridyl)(CO)3Br]: An abundant metal carbonyl complex as efficient electrocatalyst for CO2 reduction publication-title: Angew. Chem. Int. Ed. doi: 10.1002/anie.201103616 – volume: 38 start-page: 3373 year: 2009 ident: ref_32 article-title: Spectroelectrochemistry: The best of two worlds publication-title: Chem. Soc. Rev. doi: 10.1039/b504286k – volume: 14 start-page: 1115 year: 1995 ident: ref_25 article-title: Spectroelectrochemical (IR, UV/Vis) Determination of the Reduction Pathways for a Series of [Re(CO)3(.alpha.-diimine)L′]0/+ (L′ = Halide, OTf-, THF, MeCN, n-PrCN, PPh3, P(OMe)3) Complexes publication-title: Organometallics doi: 10.1021/om00003a013 |
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| SubjectTerms | BASIC BIOLOGICAL SCIENCES biochemistry & molecular biology Carbon dioxide carbon dioxide reduction Catalysts chemistry CO2 Electrons Energy Experiments INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY Ligands manganese Photovoltaic cells rhenium spectroelectrochemistry Voltammetry |
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| Title | New Spectroelectrochemical Insights into Manganese and Rhenium Bipyridine Complexes as Catalysts for the Electrochemical Reduction of Carbon Dioxide |
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