New Spectroelectrochemical Insights into Manganese and Rhenium Bipyridine Complexes as Catalysts for the Electrochemical Reduction of Carbon Dioxide
This study aimed to demonstrate the behavior of different complexes using IR spectroelectrochemistry (SEC), a technique that combines IR spectroscopy with electrochemistry. Four different Mn and Re catalysts for electrochemical CO2 reduction were studied in dry acetonitrile. In the case of Mn(apbpy)...
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| Published in: | Molecules (Basel, Switzerland) Vol. 28; no. 22; p. 7535 |
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| Abstract | This study aimed to demonstrate the behavior of different complexes using IR spectroelectrochemistry (SEC), a technique that combines IR spectroscopy with electrochemistry. Four different Mn and Re catalysts for electrochemical CO2 reduction were studied in dry acetonitrile. In the case of Mn(apbpy)(CO)3Br (apbpy = 4(4-aminophenyl)-2,2′-bipyridine), SEC suggested that a very slow catalytic reduction of CO2 also occurs in acetonitrile in the absence of proton donors, but at rather negative potentials. In contrast, the corresponding Re(apbpy)(CO)3Br clearly demonstrated slow catalytic conversion at the first reduction potential. Switching to saturated CO2 solutions in a mixture of acetonitrile and 5% water as a proton donor, the SEC of Mn(apbpy)(CO)3Br displayed a faster catalytic behavior. |
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| AbstractList | This study aimed to demonstrate the behavior of different complexes using IR spectroelectrochemistry (SEC), a technique that combines IR spectroscopy with electrochemistry. Four different Mn and Re catalysts for electrochemical CO2 reduction were studied in dry acetonitrile. In the case of Mn(apbpy)(CO)3Br (apbpy = 4(4-aminophenyl)-2,2'-bipyridine), SEC suggested that a very slow catalytic reduction of CO2 also occurs in acetonitrile in the absence of proton donors, but at rather negative potentials. In contrast, the corresponding Re(apbpy)(CO)3Br clearly demonstrated slow catalytic conversion at the first reduction potential. Switching to saturated CO2 solutions in a mixture of acetonitrile and 5% water as a proton donor, the SEC of Mn(apbpy)(CO)3Br displayed a faster catalytic behavior.This study aimed to demonstrate the behavior of different complexes using IR spectroelectrochemistry (SEC), a technique that combines IR spectroscopy with electrochemistry. Four different Mn and Re catalysts for electrochemical CO2 reduction were studied in dry acetonitrile. In the case of Mn(apbpy)(CO)3Br (apbpy = 4(4-aminophenyl)-2,2'-bipyridine), SEC suggested that a very slow catalytic reduction of CO2 also occurs in acetonitrile in the absence of proton donors, but at rather negative potentials. In contrast, the corresponding Re(apbpy)(CO)3Br clearly demonstrated slow catalytic conversion at the first reduction potential. Switching to saturated CO2 solutions in a mixture of acetonitrile and 5% water as a proton donor, the SEC of Mn(apbpy)(CO)3Br displayed a faster catalytic behavior. This study aimed to demonstrate the behavior of different complexes using IR spectroelectrochemistry (SEC), a technique that combines IR spectroscopy with electrochemistry. Four different Mn and Re catalysts for electrochemical CO2 reduction were studied in dry acetonitrile. In the case of Mn(apbpy)(CO)3Br (apbpy = 4(4-aminophenyl)-2,2'-bipyridine), SEC suggested that a very slow catalytic reduction of CO2 also occurs in acetonitrile in the absence of proton donors, but at rather negative potentials. In contrast, the corresponding Re(apbpy)(CO)3Br clearly demonstrated slow catalytic conversion at the first reduction potential. Switching to saturated CO2 solutions in a mixture of acetonitrile and 5% water as a proton donor, the SEC of Mn(apbpy)(CO)3Br displayed a faster catalytic behavior. This study aimed to demonstrate the behavior of different complexes using IR spectroelectrochemistry (SEC), a technique that combines IR spectroscopy with electrochemistry. Four different Mn and Re catalysts for electrochemical CO[sub.2] reduction were studied in dry acetonitrile. In the case of Mn(apbpy)(CO)[sub.3]Br (apbpy = 4(4-aminophenyl)-2,2′-bipyridine), SEC suggested that a very slow catalytic reduction of CO[sub.2] also occurs in acetonitrile in the absence of proton donors, but at rather negative potentials. In contrast, the corresponding Re(apbpy)(CO)[sub.3]Br clearly demonstrated slow catalytic conversion at the first reduction potential. Switching to saturated CO[sub.2] solutions in a mixture of acetonitrile and 5% water as a proton donor, the SEC of Mn(apbpy)(CO)[sub.3]Br displayed a faster catalytic behavior. |
| Audience | Academic |
| Author | Fiedler, Jan Nervi, Carlo Rotundo, Laura Sokolova, Romana Gobetto, Roberto Reviglio, Chiara Barbero, Alice |
| Author_xml | – sequence: 1 givenname: Alice orcidid: 0000-0001-9617-1733 surname: Barbero fullname: Barbero, Alice – sequence: 2 givenname: Laura surname: Rotundo fullname: Rotundo, Laura – sequence: 3 givenname: Chiara orcidid: 0009-0003-3368-1076 surname: Reviglio fullname: Reviglio, Chiara – sequence: 4 givenname: Roberto orcidid: 0000-0002-2431-8051 surname: Gobetto fullname: Gobetto, Roberto – sequence: 5 givenname: Romana orcidid: 0000-0003-1705-7401 surname: Sokolova fullname: Sokolova, Romana – sequence: 6 givenname: Jan surname: Fiedler fullname: Fiedler, Jan – sequence: 7 givenname: Carlo orcidid: 0000-0002-3712-7369 surname: Nervi fullname: Nervi, Carlo |
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| SubjectTerms | BASIC BIOLOGICAL SCIENCES biochemistry & molecular biology Carbon dioxide carbon dioxide reduction Catalysts chemistry CO2 Electrons Energy Experiments INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY Ligands manganese Photovoltaic cells rhenium spectroelectrochemistry Voltammetry |
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| Title | New Spectroelectrochemical Insights into Manganese and Rhenium Bipyridine Complexes as Catalysts for the Electrochemical Reduction of Carbon Dioxide |
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| Volume | 28 |
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