Ultrafast X-ray imaging of the light-induced phase transition in VO2

Using light to control transient phases in quantum materials is an emerging route to engineer new properties and functionality, with both thermal and non-thermal phases observed out of equilibrium. Transient phases are expected to be heterogeneous, either through photo-generated domain growth or by...

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Vydané v:Nature physics Ročník 19; číslo 2; s. 215 - 220
Hlavní autori: Johnson, Allan S, Perez-Salinas, Daniel, Siddiqui, Khalid M, Kim, Sungwon, Choi, Sungwook, Volckaert, Klara, Majchrzak, Paulina E, Ulstrup, Søren, Agarwal, Naman, Hallman, Kent, Haglund, Richard F, Günther, Christian M, Pfau, Bastian, Eisebitt, Stefan, Backes, Dirk, Maccherozzi, Francesco, Fitzpatrick, Ann, Dhesi, Sarnjeet S, Gargiani, Pierluigi, Valvidares, Manuel, Artrith, Nongnuch, de Groot, Frank, Choi, Hyeongi, Jang, Dogeun, Katoch, Abhishek, Kwon, Soonnam, Park, Sang Han, Kim, Hyunjung, Wall, Simon E
Médium: Journal Article
Jazyk:English
Vydavateľské údaje: London Nature Publishing Group 01.02.2023
Predmet:
Heterogeneity
Metal-insulator transition
Phase transitions
Phases
Vanadium
Vanadium dioxide
Vanadium oxides
X ray imagery
ISSN:1745-2473, 1745-2481
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Abstract Using light to control transient phases in quantum materials is an emerging route to engineer new properties and functionality, with both thermal and non-thermal phases observed out of equilibrium. Transient phases are expected to be heterogeneous, either through photo-generated domain growth or by generating topological defects, and this impacts the dynamics of the system. However, this nanoscale heterogeneity has not been directly observed. Here we use time- and spectrally resolved coherent X-ray imaging to track the prototypical light-induced insulator-to-metal phase transition in vanadium dioxide on the nanoscale with femtosecond time resolution. We show that the early-time dynamics are independent of the initial spatial heterogeneity and observe a 200 fs switch to the metallic phase. A heterogeneous response emerges only after hundreds of picoseconds. Through spectroscopic imaging, we reveal that the transient metallic phase is a highly orthorhombically strained rutile metallic phase, an interpretation that is in contrast to those based on spatially averaged probes. Our results demonstrate the critical importance of spatially and spectrally resolved measurements for understanding and interpreting the transient phases of quantum materials.The intermediate states in photo-excited phase transitions are expected to be inhomogeneous. However, ultrafast X-ray imaging shows the early part of the metal–insulator transition in VO2 is homogeneous but then becomes heterogeneous.
AbstractList Using light to control transient phases in quantum materials is an emerging route to engineer new properties and functionality, with both thermal and non-thermal phases observed out of equilibrium. Transient phases are expected to be heterogeneous, either through photo-generated domain growth or by generating topological defects, and this impacts the dynamics of the system. However, this nanoscale heterogeneity has not been directly observed. Here we use time- and spectrally resolved coherent X-ray imaging to track the prototypical light-induced insulator-to-metal phase transition in vanadium dioxide on the nanoscale with femtosecond time resolution. We show that the early-time dynamics are independent of the initial spatial heterogeneity and observe a 200 fs switch to the metallic phase. A heterogeneous response emerges only after hundreds of picoseconds. Through spectroscopic imaging, we reveal that the transient metallic phase is a highly orthorhombically strained rutile metallic phase, an interpretation that is in contrast to those based on spatially averaged probes. Our results demonstrate the critical importance of spatially and spectrally resolved measurements for understanding and interpreting the transient phases of quantum materials.The intermediate states in photo-excited phase transitions are expected to be inhomogeneous. However, ultrafast X-ray imaging shows the early part of the metal–insulator transition in VO2 is homogeneous but then becomes heterogeneous.
Author Maccherozzi, Francesco
Johnson, Allan S
Choi, Hyeongi
de Groot, Frank
Eisebitt, Stefan
Perez-Salinas, Daniel
Jang, Dogeun
Dhesi, Sarnjeet S
Günther, Christian M
Kwon, Soonnam
Choi, Sungwook
Siddiqui, Khalid M
Fitzpatrick, Ann
Volckaert, Klara
Valvidares, Manuel
Pfau, Bastian
Wall, Simon E
Ulstrup, Søren
Kim, Sungwon
Hallman, Kent
Kim, Hyunjung
Majchrzak, Paulina E
Agarwal, Naman
Artrith, Nongnuch
Backes, Dirk
Gargiani, Pierluigi
Park, Sang Han
Haglund, Richard F
Katoch, Abhishek
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Snippet Using light to control transient phases in quantum materials is an emerging route to engineer new properties and functionality, with both thermal and...
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SubjectTerms Heterogeneity
Metal-insulator transition
Phase transitions
Phases
Vanadium
Vanadium dioxide
Vanadium oxides
X ray imagery
Title Ultrafast X-ray imaging of the light-induced phase transition in VO2
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