Gram-scale production of graphene based on solvothermal synthesis and sonication

Carbon nanostructures have emerged as likely candidates for a wide range of applications, driving research into novel synthetic techniques to produce nanotubes, graphene and other carbon-based materials. Single sheets of pristine graphene have been isolated from bulk graphite in small amounts by mic...

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Veröffentlicht in:Nature nanotechnology Jg. 4; H. 1; S. 30 - 33
Hauptverfasser: Choucair, Mohammad, Thordarson, Pall, Stride, John A.
Format: Journal Article
Sprache:Englisch
Veröffentlicht: London Nature Publishing Group UK 01.01.2009
Nature Publishing Group
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ISSN:1748-3387, 1748-3395, 1748-3395
Online-Zugang:Volltext
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Zusammenfassung:Carbon nanostructures have emerged as likely candidates for a wide range of applications, driving research into novel synthetic techniques to produce nanotubes, graphene and other carbon-based materials. Single sheets of pristine graphene have been isolated from bulk graphite in small amounts by micromechanical cleavage 1 , and larger amounts of chemically modified graphene sheets have been produced by a number of approaches 2 , 3 , 4 , 5 , 6 , 7 . Both of these techniques make use of highly oriented pyrolitic graphite as a starting material and involve labour-intensive preparations. Here, we report the direct chemical synthesis of carbon nanosheets in gram-scale quantities in a bottom-up approach based on the common laboratory reagents ethanol and sodium, which are reacted to give an intermediate solid that is then pyrolized, yielding a fused array of graphene sheets that are dispersed by mild sonication. The ability to produce bulk graphene samples from non-graphitic precursors with a scalable, low-cost approach should take us a step closer to real-world applications of graphene. Most techniques for producing graphene use graphite as a starting material and are labour-intensive. The direct chemical synthesis of carbon nanosheets in gram-scale quantities from the common laboratory reagents ethanol and sodium has now been demonstrated. The ability to produce bulk graphene samples from non-graphitic precursors with a scalable, low-cost approach should take us a step closer to real-world applications of graphene.
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ISSN:1748-3387
1748-3395
1748-3395
DOI:10.1038/nnano.2008.365