Massive Anisotropic Thermal Expansion and Thermo-Responsive Breathing in Metal-Organic Frameworks Modulated by Linker Functionalization

Functionalized metal–organic frameworks (fu‐MOFs) of general formula [Zn2(fu‐L)2dabco]n show unprecedentedly large uniaxial positive and negative thermal expansion (fu‐L = alkoxy functionalized 1,4‐benzenedicarboxylate, dabco = 1,4‐diazabicyclo[2.2.2]octane). The magnitude of the volumetric thermal...

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Bibliographic Details
Published in:	Advanced functional materials Vol. 23; no. 48; pp. 5990 - 5996
Main Authors:	Henke, Sebastian, Schneemann, Andreas, Fischer, Roland A.
Format:	Journal Article
Language:	English
Published:	Weinheim WILEY-VCH Verlag 23.12.2013 WILEY‐VCH Verlag
Subjects:	Anisotropy Combinatorial analysis Crystal structure Flexibility Liquids Metal-organic frameworks Porosity porous materials porous-coordination polymers Solid solutions stimuli-responsive materials Thermal expansion
ISSN:	1616-301X, 1616-3028
Online Access:	Get full text
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