'Green' composites prepared from polyfurfuryl alcohol and cork residues: Thermal and mechanical properties

Polyfurfuryl alcohol (PFA) is a biobased thermoset like matrix with high thermal performances and cork powder or cork granules are side stream product from cork stoppers’ production. They were processed together via compression molding. Structural investigations were made by means of FT-IR and therm...

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Vydané v:	Composites science and technology Ročník 124; s. 105473
Hlavní autori:	Menager, Charlotte, Guigo, Nathanael, Wu, Xuan, Vincent, Luc, Sbirrazzuoli, Nicolas
Médium:	Journal Article
Jazyk:	English
Vydavateľské údaje:	Elsevier Ltd 01.09.2019 Elsevier
Predmet:	A. Thermosetting resin absorption adhesion alcohols B. Thermal properties B. Thermomechanical Chemical Sciences composite materials compression molding Cork cork stoppers E. Compression moulding Fourier transform infrared spectroscopy granules Material chemistry modulus of elasticity temperature tensile strength thermal degradation thermogravimetry A. Thermosetting resin E. Compression moulding B. Thermomechanical B. Thermal properties Cork
ISSN:	1359-835X, 0266-3538, 1878-5840
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Abstract	Polyfurfuryl alcohol (PFA) is a biobased thermoset like matrix with high thermal performances and cork powder or cork granules are side stream product from cork stoppers’ production. They were processed together via compression molding. Structural investigations were made by means of FT-IR and thermo-mechanical measurements were performed using tensile tests, thermogravimetric analyses (TGA) and dynamic mechanical analyses (DMA). The fracture surface morphology controlled by scanning electronic microscopy (SEM) shows that cork cells are well filled by PFA and that homogeneous composites can be formed. The addition of PFA allows increasing sharply the elastic modulus and the tensile strength which attest for good adhesion between PFA and cork. The thermal degradation of cork/PFA composites is shifted to higher temperature (±20 °C) which indicates that PFA helps to prevent the cork decomposition. Finally PFA reduce significantly the absorption of water in composites.
AbstractList	Polyfurfuryl alcohol (PFA) is a biobased thermoset like matrix with high thermal performances and cork powder or cork granules are side stream product from cork stoppers’ production . They were processed together via compression molding. Structural investigations were made by means of FT-IR and thermo-mechanical measurements were performed using tensile tests, thermogravimetric analyses (TGA) and dynamic mechanical analyses (DMA). The fracture surface morphology controlled by scanning electronic microscopy (SEM) shows that cork cells are well filled by PFA and that homogeneous composites can be formed. The addition of PFA allows increasing sharply the elastic modulus and the tensile strength which attest for good adhesion between PFA and cork. The thermal degradation of cork/PFA composites is shifted to higher temperature (> +20 °C) which indicates that PFA helps to prevent the cork decomposition. Finally PFA reduce significantly the absorption of water in composites. Polyfurfuryl alcohol (PFA) is a biobased thermoset like matrix with high thermal performances and cork powder or cork granules are side stream product from cork stoppers’ production. They were processed together via compression molding. Structural investigations were made by means of FT-IR and thermo-mechanical measurements were performed using tensile tests, thermogravimetric analyses (TGA) and dynamic mechanical analyses (DMA). The fracture surface morphology controlled by scanning electronic microscopy (SEM) shows that cork cells are well filled by PFA and that homogeneous composites can be formed. The addition of PFA allows increasing sharply the elastic modulus and the tensile strength which attest for good adhesion between PFA and cork. The thermal degradation of cork/PFA composites is shifted to higher temperature (±20 °C) which indicates that PFA helps to prevent the cork decomposition. Finally PFA reduce significantly the absorption of water in composites.
ArticleNumber	105473
Author	Vincent, Luc Sbirrazzuoli, Nicolas Menager, Charlotte Guigo, Nathanael Wu, Xuan
Author_xml	– sequence: 1 givenname: Charlotte surname: Menager fullname: Menager, Charlotte – sequence: 2 givenname: Nathanael surname: Guigo fullname: Guigo, Nathanael email: nathanael.guigo@unice.fr – sequence: 3 givenname: Xuan surname: Wu fullname: Wu, Xuan – sequence: 4 givenname: Luc surname: Vincent fullname: Vincent, Luc – sequence: 5 givenname: Nicolas surname: Sbirrazzuoli fullname: Sbirrazzuoli, Nicolas
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Keywords	A. Thermosetting resin E. Compression moulding B. Thermomechanical B. Thermal properties Cork
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Snippet	Polyfurfuryl alcohol (PFA) is a biobased thermoset like matrix with high thermal performances and cork powder or cork granules are side stream product from...
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SubjectTerms	A. Thermosetting resin absorption adhesion alcohols B. Thermal properties B. Thermomechanical Chemical Sciences composite materials compression molding Cork cork stoppers E. Compression moulding Fourier transform infrared spectroscopy granules Material chemistry modulus of elasticity temperature tensile strength thermal degradation thermogravimetry
Title	'Green' composites prepared from polyfurfuryl alcohol and cork residues: Thermal and mechanical properties
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